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1.

The correct order for acid strength of compounds `CH-=CH,CH_(3)-C-=CH and CH_(2)=CH_(2)` is as follows:A. `CH-=CH gt CH_(2)=CH_(2)gtCH_(3)-C-=CH`B. `HC-=CHgtCH_(3)-C-=CHgtCH_(2)=CH_(2)`C. `CH_(3)-C-=CHgtCH_(2)=CH_(2)gtHC-=CH`D. `CH_(3)-C-=CHgtCH-=CHgtCH_(2)=CH_(2)`.

Answer» Correct Answer - A::B
2.

In the following compounds The order of acidity is-A. IIIgtIVgtIgtIIB. IgtIVgtIIIgtIIC. IIgtIgtIIIgtIVD. IVgtIIIgtIgtII

Answer» Correct Answer - D
3.

Arrange the following c ompounds in order of decreasing acidity: A. IIgtIVgtIgtIIIB. IgtIIgtIIIgtIVC. IIIgtIgtIIgtIVD. IVgtIIIgtIgtII

Answer» Correct Answer - C
4.

Arrange the given phenol in their decreasing order of acidity: (I). `C_(6)H_(5)-OH` . Select the correct answer from the given code:A. IVgtIIIgtIgtIIB. IVgtIIgtIIIgtIC. IVgtIIIgtIIgtID. IVgtIgtIIIgtII

Answer» Correct Answer - C
5.

Statement-1: For the given two compounds-I is more acidic than compounds-II ltBrgt and Statement-2: Due to presence of `-CH_(3)` group at ortho positions to `-NO_(2)` the plane of `-NO_(2)` deviates, w.r.t plane of ring.A. Statement-1 I true, statement-2 is true, statement-2 is a correct explanation for statement-1B. Statement-1 is true, statement-2 is true, statement-2 is NOT a correct explanation for statement-1.C. Statement-1 is true, statement-2 is false.D. statement-1 is false, statement, statement-2 is true.

Answer» Correct Answer - D
6.

The carboxyl functional group `(-COOH)` is present in `:`A. picric acidB. barbituric acidC. ascorbic acidD. aspirin

Answer» Correct Answer - D
7.

Among the following acids, which has the lowest `pK_(a)` value?A. `CH_(3)CH_(2)COOH`B. `(CH_(3))_(2)CHCOOH`C. `HCOOH`D. `CH_(3)COOH`

Answer» Correct Answer - C
8.

Among the following compounds, the most acidic is:A. p-nitrophenolB. p-hydroxybenzoic acidC. o-hydroxybenzoic acidD. p-toluic acid

Answer» Correct Answer - C
9.

The conjugate base of hydraozic acid is:A. `HN_(3)^(-)`B. `N_(3)^(-)`C. `N_(2)^(-)`D. `N^(-3)`

Answer» Correct Answer - B
10.

Considerin the basic strength of amines in aqueous solution, which one has the smallest `pK_(b)` value?A. `(CH_(3))_(3)N`B. `C_(6)H_(5)NH_(2)`C. `(CH_(3))_(2)NH`D. `CH_(3)NH_(2)`

Answer» Correct Answer - C
11.

Which among the following compounds will not give effervescence with sodium bicarbonate ?A. Benzene sulphonic acidB. Benzoic acidC. o-NitrophenolD. 2,4,6-Trinitrophenol

Answer» Correct Answer - C
12.

The compound that does not liberate `CO_(2)`, on treatment with aqueous sodium bicarbonate isA. Benzoic acidB. Benzenesulphonic acidC. alicylic acidD. Carbolic acid (phenol)

Answer» Correct Answer - D
13.

The correct order of acidic strength of the following is:A. IIIgtIVgtIIgtIB. IVgtIIIgtIgtIIC. IIIgtIIgtIgtIVD. IIgtIIIgtIVgtI

Answer» Correct Answer - A
14.

Consider the following bases: (I) o-nitroaniline (II) m-nitroaniline (III) p-nitroaniline The decreasing order of basicity is:A. IIgtIIIgtIB. IIgtIgtIIIC. IgtIIgtIIID. IgtIIIgtII

Answer» Correct Answer - A
15.

The most basic compound among the following is-A. AcetanilideB. BenzylamineC. p-Nitro anilineD. Aniline

Answer» Correct Answer - B
16.

The correct order of increasing basicity of the given conjugate bases `(R=CH_(3))` isA. `RCOoverline(O) lt HC-=overline(C) lt overline(N)H_2 lt overline(R)`B. `RCOoverline(O) lt HC-=overline(C) lt overline(R) lt overline(N)H_(2)`C. `overline(R) lt HC-=overline(C) lt RCOoverline(C) lt overline(N)H_(2)`D. `RCOoverline(O) lt overline(N)H_(2) lt HC-=overline(C) lt overline(R)`.

Answer» Correct Answer - A
17.

In the following compounds: the order of basicity is as follows:A. IVgtIIIgtIIgtIB. IIgtIIIgtIgtIVC. IgtIIIgtIIgtIVD. IIIgtIgtIIgtIV

Answer» Correct Answer - C
18.

The increasing order of basicity of the following compounds is: A. `b lt a lt c lt d`B. `b lt a lt d lt c`C. `d lt b lt a lt c`D. `a lt b lt c lt d`

Answer» Correct Answer - B
19.

The order of basicity among the following compounds is .A. IIgtIgtIVgtIIIB. IVgtIIgtIIIgtIC. IgtIVgtIIIgtIID. IVgtIgtIIgtIII

Answer» Correct Answer - D
20.

The strongest acid is:A. HFB. `CH_(3)CO_(2)H`C. `HF+SbF_(5)`D. `H_(2)S`

Answer» Correct Answer - C
21.

Arrange acididy of given compounds in decreasing order (I). `CH_(3)-N-CH_(2)-OH` (II). `CH_(3)-NH-CH_(2)-CH_(2)-CH_(2)-OH` (III). `(CH_(3))_(3)overset(o+)(N)-CH_(2)-CH_(2)-OH`A. IIIgtIgtIIB. IIIgtIIgtIC. IgtIIgtIIID. IIgtIgtIII

Answer» Correct Answer - A
22.

The correct order of increasing basic nature of the bases `NH_(3),CH_(2)NH_(2) and (CH_(3))_(2)NH` is-A. `CH_(3)NH_(2) lt NH_(3)(CH_(3))_(2)NH`B. `(CH_(3))_(2)NHltNH_(3)ltCH_(3)NH_(2)`C. `NH_(3) lt CH_(3)NH_(2)lt(CH_(3))_(2)NH`D. `CH_(3)NH_(2)lt(CH_(3))_(2)NHltNH`

Answer» Correct Answer - C
23.

The increasing order of the pKa values of the following compounds is: A. `D lt A lt C lt B`B. `B lt C lt D lt A`C. `C lt B lt A lt D`D. `B lt C lt A lt D`.

Answer» Correct Answer - A::D
24.

Observe the following feasible reaction: Q. Identify the feasible reactionsA. B. C. D.

Answer» Correct Answer - A::D
25.

Observe the following feasible reaction: Q. Which of the following compound does not react with `NaHCO_(3)`.A. B. C. D.

Answer» Correct Answer - A
26.

Picric acid is:A. B. C. D.

Answer» Correct Answer - C
27.

identify the non-feasible reaction.A. `CH_(3)-C-=CH+NH_(2)^(-)hArrCH_(3)-C-=overset(underset(_)(* *))(C)+NH_(3)`B. `CH_(3)CH_(2)-OH+NaH hArrCH_(3)CH_(2)ON a+H_(2)`C. `CH_(3)-OH+NaOHhArrCH_(3)ON a+H_(2)O`D. `HC-=CH+NaOHhArrCH-=CN a+H_(2)O`

Answer» Correct Answer - D
28.

Select the number of compounds in which deprotonation gives aromatic anion:A. B. C. D.

Answer» Correct Answer - A::B::C::D
29.

The order of basicity of amines in gaseous state is-A. `3^(@) gt 2^(@) gt NH_(3) gt 1^(@)`B. `1^(@) gt 2^(@) gt 3^(@) gt NH_(3)`C. `NH_(3) gt 1^(@) gt 2^(@) gt 3^(@)`D. `3^(@) gt 2^(@) gt 1^(@) gt NH_(3)`.

Answer» Correct Answer - D
30.

Which of the following is most acidic:A. B. C. D.

Answer» Correct Answer - B
31.

The most important condition for resonanace to occur is that the invovled atoms in resonating structure must be coplanar or nearly coplanar for maximum delocalisation. If this condition does not fulfil, involved orbitals cannot be parallel to each other and as consequence delocalisation cannot occur. Bulky groups present on adjacent atoms inhibit the planarity of atoms involved in resonance. this pehnomenon is known as steric inhibition of resonance. Steric inhibition of resonance has profound effect on Q. Arrange the following in the decreasing order of basicity: .A. IgtIIgtIIIgtIVB. IVgtIIIgtIIgtIC. IIgtIgtIVgtIIID. IgtIVgtIIIgtII

Answer» Correct Answer - C
32.

The most important condition for resonanace to occur is that the invovled atoms in resonating structure must be coplanar or nearly coplanar for maximum delocalisation. If this condition does not fulfil, involved orbitals cannot be parallel to each other and as consequence delocalisation cannot occur. Bulky groups present on adjacent atoms inhibit the planarity of atoms involved in resonance. this pehnomenon is known as steric inhibition of resonance. Steric inhibition of resonance has profound effect on Q. Which of the following is most acidic:A. B. C. D.

Answer» Correct Answer - B