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1.

Mention the uses of formaldehyde.

Answer»

1. 40% aqueous solution of formaldehyde is called formalin. It is used for preserving biological specimens. 

2. Formalin has hardening effect, hence it is used for tanning. 

3. Formalin is used in the production of thermo setting plastic known as bakelite, which is obtained by heating phenol with formalin.

2.

Which aldehyde does not give aldimine with etheral ammonia solution?(a) CH3CHO(b) CH3CH2CHO(C) HCHO

Answer»

Answer is (C) HCHO

3.

Identify the product formed when acetaldehyde reacts with ammonia?(a) CH3 - CH = NH(b) CH3 - CH2 - NH2(d) CH3 - NH2

Answer»

(a) CH3 - CH = NH

4.

Which one of the following is used as, an urinary antiseptic? (a) Urotropine (b) Urea formaldehyde (c) Formalin (d) Aldimm

Answer»

(a) Urotropine

5.

Which one of the following is called Mesityl oxide?

Answer»

(c) (CH3)2C = CHCOCH3

6.

Which one of the following is the formula of Succinic acid? (a) HOOC – CH2 – COOH (b) HOOC – (CH2)2 – COOH (c) HOOC – (CH2)4 – COOH (d) HOOC – (CH)3 – COOH

Answer»

(b) HOOC – (CH2)2 – COOH 

7.

The IUPAC name of is .......(a) Glyceraldehyde (b) Acrolein (c) 2, 3 – dihydroxy propanal (d) Butanal

Answer»

(c) 2, 3 – dihydroxy propanal

8.

Match the column I and II using the code given below the column.column Icolumn IIA. BenzophenoneB. AcetophenoneC. Phenyl methanalD. Propanone4. C6H5 - CHOABCDa1234b3142c4321d2413

Answer»

(b)  3 1 4 2

9.

Fill in the blanks1. ……. is used to convert acetic acid to ethane at 473 K.2. ……. reaction is generally used for the preparation of esters of higher alcohol from that of a lower alcohol. 3. Formic acid is used in medicine for treatment of ………4. The conversion of acetamide to methylamine by the action of caustic alkali and Bromine is known as ………5. ……. is used as food preservative. 6. ……. is used in the detection and estimation of – OH, – NH2 , groups in organic compounds.7. ……. is used in the preparation of artificial fruit essences.8. The conversion of Benzene to Benzaldehyde by the action of carbon monoxide and HCl is known as ……9. The product formed when formaldehyde condensed with acetone is …….10. Benzaldehyde condenses with acetaldehyde to form ………

Answer»

1. HI + Red P

2. Transesterification

3. Gout

4. Hoff mann’s degradation

5. Sodium benzoate

6. Acetyl chloride

7. Ethyl acetate

8. Gattermann – koch reaction

9. 4 – hydroxy – butane – 2 – one

10. Cinnamaldehyde

10.

O3 reacts with CH2 = CH2 to form ozonide. On hydrolysis it forms ……(a) Ethylene oxide(b)  HCHO(c) CH3 CHO

Answer»

O3 reacts with CH2 = CH2 to form ozonide. On hydrolysis it forms HCHO

11.

Reduction of > C = O to – CH2 can be carried out with .....(a) Ni (b) Na/C2H5OH (c) NH2 – NH2 + C2HONa(d) LiAIH4

Answer»

(c) NH2 – NH2 + C2HONa

12.

The IUPAC name of crotanaldehyde CH3 – CH = CH – CHO is ………(a) Prop – 2 – enal (b) But – 2 – enal (c) Ethenal (d) Phenyl methanal

Answer»

(b) But – 2 – enal

13.

The IUPAC name of HOOC – (CH2)4 – COOH is ……… (a) Adipic acid (b) Butane dioic acid(c) Hexane diolc acid (d) Glutaric acid

Answer»

(c) Hexane diolc acid

14.

Tdentifý the product “C” in the sequence of the reaction(a) CH3CH2NH2 (b) CH3CH2OH (c) CH2 = CH2 (d) CH3CHO

Answer»

(c) CH2 = CH2 

15.

In which of the following reactions new carbon – carbon bond is not formed? (a) Aldol condensation (b) Friedel craft reaction (c) Kolbe’s reaction (d) Wolf kishner reduction

Answer»

(d) Wolf kishner reduction

16.

Which one of the following is the hybridised state of C atoms in carbonyl carbon?(a) sp (b) sp3d (c) sp3 (d) sp2

Answer»

sp2 is the hybridised state of C atoms in carbonyl carbon.

17.

What are the uses of acetic acid?

Answer»

Acetic acid is used in:

1. as table vinegar

 2. for coagulating rubber latex

3. for manufacture of cellulose acetate and poly vinylacetate

18.

Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their ………(a) more extensive association of carboxylic acid via van der Waals force of attraction (b) formation of carboxylate ion (c) formation of intramolecular H – bonding (d) formation of intermolecular H – bonding

Answer»

(d) formation of intermolecular H – bonding

19.

Which one of the following is used as a catalyst in Knoevenagal reaction?(a) Pyrimidine(b) Pyridine (c) PCC (d) CdCl2

Answer»

(b)  Pyridine

20.

What is the colour change take place when Fehling’s solution is added to an aldehyde? (a) Red to blue (b) Blue to red (c) Red to green (d) Green to blue

Answer»

(b) Blue to red

21.

Which one of the following is the formula of Schiff’ s base’?(a) C6H5 – NH NH2 (b) C6H5 CH = N – C6H5 (b) Perkin’s reaction (d) Aldol condensation

Answer»

(b) C6H5 CH = N – C6H5 

22.

Which one of the following is used in silvering of mirrors? (a) Paraldehyde (b) Benzaldehyde (c) Acetone (d) Acetaldehyde

Answer»

(d) Acetaldehyde

23.

Which one of the following is used for preserving biological specimens?(a) Urotropine (b) Formalin (c) Schiff’s base (d) Benzoin

Answer»

Formalin is used for preserving biological specimens

24.

Match the column I and II using the code given below the column.column Icolumn IIA. CH3 - CH = CH - CH3 + O3 → ?1. 2HCHO2. CH3CHO + HCHOC. CH2 = CH2 + O3 → ?3. 2CH3CHOD. CH3 - CH = CH2 O3 → ?4. CH3CHO + CH3COCH3ABCDa1234b4321c3412d2143

Answer»

(c)  3 4 1 2

25.

The JUPAC name of is ......(a) Benzene carboxylic acid (b) Benzoic acid (c) 2 – phenyl ethanoic acid (d) 2 – phenyl acetic acid

Answer»

(c) 2 – phenyl ethanoic acid

26.

Fill in the blanks.1. RDX is also called ……. or ………2. With ammonia, benzaldehyde form a complex condensation product called ……3. The oxidation of unsymmetrical ketone is governed by ……….4. The reducing agent used in Clemmensen reduction is ……5. The reducing agent used in woif-kishner reduction is ……6. Symmetric diols are called ………7. Aldehydes which do not have ……… undergo disproportionation reaction (or) cannizaro reaction.8. The reagent used in the conversion of Benzaldehyde to Benoin is ……9. In Knoevenagal reaction …………. act as the basic catalyst.10. The formula of Benzal aniline (or) Schiffs base is ………

Answer»

1. Cyclonite(or)cyclotrimethylene trinitramine

2. Hydrobenzamide

3. Popott’s rule 

4. Zn + Hg / conc.HCl

5. NH2 – NH2 + C2H5ONa

6. Pinacol

7. a – hydrogen atom

8. Alcoholic KCN

9. Pyridine

10. C6H5CH = N – C6H5

27.

What are the reagents required to prepare Benzal aniline (or) Schiff’s base?(a) Benzyl amine + Ammonia (b) Benzal amine + Ammonia(c) Benzaldehyde + Aniline(d) Phenol + Aniline

Answer»

(c) Benzaldehyde + Aniline

28.

Which one of the following is formed when phenol is heated with formalin? (a) Bakelite (b) PVC (c) Polyurethane (d) Polyester

Answer»

Bakelite is formed when phenol is heated with formalin.

29.

Which one of the following is used as a hypnotic? (a) Acetaldehyde (b) Formalin (c) Paraldehyde (d) Formaldehyde

Answer»

(c) Paraldehyde

30.

Match the column I and II using the code given below the column.column Icolumn II1. 2C6H5COCH3 + 2CaCO32. HCHO + CaCO33. 2CH3CHO + 2CaCO34. CH3COCH3 + CaCO3ABCDa2341b1234c3412d4123

Answer»

(a)  2 3 4 1

31.

Acetone and acetaldehyde are differentiated by ……..(a) NaOH + I2 (b) Ag(NH3)+2 (Tollens’s reagent) (c) I2 (d) NaOH + NH3

Answer»

(b) Ag(NH3)2+ (Tollens’s reagent)

32.

Consider the following statements:(i) Formaldehyde is a gas at room temperature and acetaldehyde is a volatile liquid. (ii) The oxidation of symmetrical ketones is governed by Popoti’s rule. (iii) Aliphatic aldehyde react with primary amines in the presence of base gives Schiff’s base. Which of the above statement is/are not correct? (a) (i) only (b) (ii) only (c) (ii) & (iii) (d) (i) & (ii)

Answer»

(c)  (ii) & (iii)

33.

Identify the reagents X and Y are ………(a) X = MgCl2 Y = CH3CH = CH2(b) X = CH3MgCI Y = C6H5COCH3 (c) X = CH3MgCI Y = (CH3)3C – OH(d) X = C6H5 MgCI Y = (CH3)3C – OH

Answer»

(c) X = CH3MgCI Y = (CH3)3C – OH

34.

RDX is otherwise named as ………(a) Cyclonite (b) Cyclohexane (c) 1, 4 – dione (d) Cyclohexanol

Answer»

(a) Cyclonite

35.

What is Vinegar? How will you get glacial acetic acid?

Answer»

1. Vinegar is 6 to 8% solution of acetic acid in water. 

2. Pure acetic acid is called glacial acetic acid. Because it forms ice like crystal when cooled. 

When aqueous acetic acid is cooled at 289.5 K, acetic acid solidifies and forms ice like crystals, where as water remains in liquid state and removed by filtration. This process is repeated to obtain glacial acetic acid.

36.

Match the column I and II using the code given below the column.column Icolumn IIA. Stephen's reactionB. Rosenmund reductionC. Gattermann Koch reactionD. Friedel crafts BenzoylationABCDa1234b4321c2143d3412

Answer»

(d)  3 4 1 2

37.

Consider the following statements. (i) Terminal olefins gives Formaldehyde as one of the product (ii) Oxidation of alcohols using pcc yield carboxylic acids (iii) Catalytic dehydrogenation of alcohols give either aldehyde or ketone.Which of the above statement is/are not correct? (a) (ii) only (b) (i) & (iii) (c) (ii) & (iii) (d) (ii) only

Answer»

(a) (ii) only

38.

Which one of the following is used in the preparation of Artificial fruit essences? (a) Ethanoic acid (b) Acetamide (c) Ethyl acetate (d) Acetic anhydride

Answer»

(c) Ethyl acetate

39.

Which one of the following is formed when acetic acid is heated with phosphorous pentoxide?(a) CH3COCH3 (b) CH3CONH2 (c) CH4 (d) (CH3CO)2O

Answer»

(d)  (CH3CO)2O

40.

The reaction of acetic acid with Cl2 and red phosphorous is named as …… (a) Kolbe’s reaction (b) Reimer – Tiemann reaction (c) HeII – volhard – zelinsky reaction (d) Knoevenagal reaction

Answer»

(c) HeII – volhard – zelinsky reaction

41.

Match the column I and II using the code given below the column.column I column IIA. HCHO + NH3B. CH3CHO + NH32. (CH2)6N4C. 2CH3COCH3 + NH33. CH3CH = NHD. 2C6H5CHO + NH3ABCDa2314b4231c3142d1423

Answer»

(a)  2 3 1 4

42.

Aldehyde turns pink with ……… (a) Benedict solution (b) Schiff ‘s base (c) Fehiing solution (d) Tollen’s reagent

Answer»

(b) Schiff ‘s base

43.

Which of the following is used in the preparation of benzhydrol drop?(a) Benzaldehyde (b) Benzophenone (c) Acetophenone (d) Benzoin

Answer»

(b) Benzophenone

44.

The IUPAC name of Acrolein is (a) Prop – 2 – enal (b) Propanal (c) Ethenal (d) 1 – butanal

Answer»

(a) Prop – 2 – enal

45.

Why acid anhydride are preferred to acyl chloride for carrying out acylation reactions?

Answer»

Acid anhydride are preferred to acyl chloride for carrying out acylation reactions. Because 

1. Easily available 

2. Cheap 

3. Easy to prepare 

4. Easily undergo acylation without irritating odours

46.

Which one of the following is formed when ethanoic acid is treated with HI and Red phosphorous? (a) Ethane (b) Ethene(c) Ethyne (d) Methane

Answer»

Ethane is treated with HI and Red phosphorous

47.

Match the column I and II using the code given below the column.column I column IIA. Cinnmaldehyde1. Rosenmunds reductionB. Cinnamic acid2. Friedel crafts reactionC. Acetaldehyde3. Perkin's reactionD. Benzophenone4. Claisen schmidt condensationABCDa4312b1234c2143d3421

Answer»

(a)  4 3 1 2

48.

Indicate the uses of Benzoic acid.

Answer»

Benzoic acid is used in :

1. as food preservative either in the pure form or in the form of sodium benzoate 

2. in medicine as an urinary antiseptic 

3. for manufacture of dyes

49.

What is the name of the reaction when benzaldehyde changes into Benzyl alcohol?(a) Friedel – crafts reaction(b) Kolbe’s reaction(c) Cannizaro reaction (d) Wurtz reaction

Answer»

(c) Cannizaro reaction

50.

Which one of the following aldehyde is derived from vitamin B, function as a co – enzyme?(a) Pyridoxal (b) Formaldehyde (c) Ethanal (d) Propanal

Answer»

(a) Pyridoxal