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7801.

The half life of a  first order reaction is 200 sec. calculate the rate constant of the reaction.

Answer»

Half life, t½ = 0.693 / k  

= 0.693 / 200 s-1  

= 3.47 ×10-3s (approximately)

7802.

Define the following terms in relation to crystalline solids:(i) Unit cell(ii) Coordination numberGive one example in each case.

Answer»

(i) Unit cell: A unit cell is the smallest portion of a crystal lattice which, when repeated in different direction, generates the entire lattice.

(ii) Coordination number: The number of nearest neighbours of any constituent particle in a packing is called its coordination number. The coordination number of an atom in the bcc structure is 8.

i) Unit Cell:- Smallest element of a crystal lattice which on repetition gives the entire crystal lattice.  Eg - cubic unit cell

ii) Coordination Number  :- The number of neighbour atoms attached to a central atom         Eg - In hcp the C.N is 6 (three dimensional)

7803.

(a) Give one main difference between lyophillic and lyophobic colloids(b) What is observed when(i) A beam of light is passed through a colloidal solution.(ii) Electric current is passed through a colloid solution

Answer»

(a) Lyophillic colloids-(i) They have strong forces of attraction between the dispersed phase and dispersion medium. (ii) They are reversible in nature Lyobolic colloids (i) They have work force of attraction between the dispersed phase and dispersion medium (ii) They are irreversible in nature. (Any one difference)

(b) (i) Due to the scattering of light by colloidal particles, the path of light becomes visible. The effect is called Tyndall effect. The illuminated path of the beam of light is called Tyndall cone. (ii) The colloidal particles get precipitated at one of the electrodes, having charge opposite to the charge they have.

7804.

Account for the following :(a) Aniline does not undergo Friedel Crafts alkylation(b) Although-NH2 group is an ortho and para-directing group, nitration of aniline gives alongwith ortho and para-derivatives meta-derivative also.

Answer»

(a) During Friedel Craft's alkylation, aluminium chloride acts as a catalyst, as well as a Lewis acid, if forms salt with– NH2 group of aniline, so that–NH2 group acquires a positive charge, and acts as a deactivating group, so aniline does not undergo FCA. 

(b) During nitration in strongly acidic medium aniline is protonated to form anilinium ion, which is a meta directing group, so along with o & pisomers, meta isomers is also obtained.

7805.

Predict, giving reasons, the order of basicity of the following compounds in (i)gaseous phase and (ii) in aqueous solutions(CH3)3N, (CH3)2(NH), CH3NH2, NH3

Answer»

In gaseous phase, basic character of amines increases with increases in number of electron releasing groups, due to + I effect, so trend of basic character is 3° > 2° > 1°.

But in aqueous phase, salvation of ammonium cation occurs by water molecules, greater the size of ion, lesser will be the salvation, and lesser will be the stability of ion, so on combining + I effect and salvation effect, in aqueous phase trend changes to 2° > 3° > 1°.

7806.

Explain giving reason(a) The enthalpies of atomization of the transition metals are high(b) Transition metals in their many compounds act as good catalyst

Answer» (a) Due to strong inter particle force

(b) Due to variable oxidation state
7807.

Write the principle of the following (a) Hydraulic washing (b) Chromatography  (c) Froth – floatation process 

Answer»

(a) Principle of hydraulic washing – This separation is based on the difference in the specific gravities of the gangue particles and the ore particles. The powdered ore is agitated with water or washed with a running water. The heavy ore particles settle down while the lighter particles of sand, clay etc. are washed away. 

(b) Chromatography : - It is based on selective distribution of the various constituents of a mixture between two phases. A stationary phase and a moving phase. The stationary phase can be either solid (such as alumina, silicagel) or tightly bound liquid on a solid support. The moving phase may be liquid or a gas. 

 (c) Froth – floatation process. This process is based on the fact that metallic sulphide ore particles are preferentially wetted by oil where as silicate gangue particles are preferentially wetted by water. So sulphide ore particles rise to the surface in the form of froth while gangue particles sink to the bottom. 

7808.

Give reasons for the following : (a) Transition metals have high enthalpies of atomization. (b) Manganese has lower melting point even though it has a higher number of unpaired electrons for bonding.  (c) Ce4+ is a strong oxidizing agent. 

Answer»

(a) Transition elements have a large number of valence electrons and high effective nuclear charge. Due to this they form very strong metallic bonds. As a result of this the enthalpy of atomization of transition metals is high. 

(b) Complex structure of metal crystal is responsible for this abnormal behaviour of manganese. 

(c) Ce4+(4f 0 ) in + 4 oxidation state tend to revert to the more stable oxidation state of + 3 by gain of an electron so it behaves as strong oxidising agent. 

7809.

Describe Ausable's reaction after finding Max in his room.

Answer»

When Ausable found Max in his room waiting for the report, Ausable moved to an armchair and sat down heavily. He was displeased because this was the second time that somebody had intruded his room thrugh balcony. He decided that he would complain the management about that balcony. 

7810.

Sales are equal to: a) Cost of goods sold + gross profit b) Cost of goods sold - gross profit c) Gross profit- Cost of goods sold d) None of the above 

Answer»

Sales are equal to Cost of goods sold + gross profit

7811.

The practice of appending notes regarding contingent liabilities in accounting statements is in pursuance to: a) Convention of consistency b) Money measurement concept c) Convention of conservatism d) Convention of disclosure

Answer»

d) Convention of disclosure 

7812.

Accountant should follow the same principles of accounting continuously is as per which accounting convention a) Convention of conservatism b) Convention of full disclosure c) Convention of consistency d) None of these

Answer»

c) Convention of consistency

7813.

The convention of disclosure implies that all material information should be a) Disclosed in the account b) Disclosed in the accounts which is required to owner c) Not disclosed d) None of these

Answer»

a) Disclosed in the account

7814.

The system of recording based on dual aspect concept is called: a) Double account system b) Double entry system c) Single entry system d) All the above

Answer»

b) Double entry system 

7815.

Accounting principles are generally based upon: a) Practicability b) Subjectivity c) Convenience in recording d) None of the above

Answer»

a) Practicability

7816.

Accounting principles are ………which are adopted by the accountant universally while recording accounting transaction. a) Rules of action or conduct b) Which u can change as per accountant c) Which keep changing every year d) None of these

Answer»

Accounting principles are Rules of action or conduct which are adopted by the accountant universally while recording accounting transaction. 

7817.

Management Accounting provides invaluable services to management in performing a) All management function b) Interpret financial data c) Controlling function d) None of these

Answer»

All management function

7818.

Accounting principles are generally based on a) Practicability b) Subjectivity c) Convenience in recording d) None of these

Answer»

Accounting principles are generally based on Practicability

7819.

Book keeping is mainly concerned with a) Recording of financial data relating to business operation b) Designing the systems in recording classifying,summarizing the recorded data c) Interpreting the data for internal and external users

Answer»

a) Recording of financial data relating to business operation

7820.

When time of Withdrawals are not mentioned interest on drawing is charged.(a) 6 1/2 For 6 1/2 month(b)  For 6 month(c)  For 5 month(d)  For 12 month

Answer»

Withdrawals are not mentioned interest on drawing is charged for 6 month.

7821.

Current Account is(a) Personal Account(b) Real Account(c) Nominal Account(d) None of these

Answer»

Current Account is Personal Account.

7822.

The current assets include.(a) Long term investment(b)  Short term investment(c)  Furniture(d)  Preliminary Expense

Answer»

The current assets include Short term investment.

7823.

Income and expenditure accounts records are ....

Answer»

An income and expenditure account is a records are showing debits and credits for an organization within a particular time period.

7824.

Income and expenditure accounts records are ....

Answer»

An income and expenditure account is a records are showing debits and credits for an organization within a particular time period.

7825.

Given below are few transgenic crops approved by US food and drug administration along with the improved character. Name the genes A to F introduced for the improved character.CropGeneImproved characterCanolaAHybrid production CornBInsect resistance CottonCInsect resistancePapayaDVirus resistancePotato EInsect and virus control SoyabeanFWeed Control

Answer»
CropGene Improved character
Canola(A) Thioesterase EPSP synthase/ Any relevant geneHybrid production 
Corn(B) Bt cry I Ac /any other Insect resistance 
Cotton(C)  Acetolactate synthase Nitrilase EPSP synthase Bt CryIA(c)Insect resistance
Papaya(D)  Coat protein/ Any relevant geneVirus resistance
Potato (E)  Bt CryIIIA and coat protein/ Any relevant geneInsect and Virus control
Soyabean (F)  EPSP synthase/ Any relevant geneWeed control 
7826.

What is a pilot plant? Why is it necessary to validate a process in a pilot plant before commercial scale production in a bioprocess industry?

Answer»

Pilot plant: Mini version of the commercial plant.

Direct production of microbes on a large or commercial scale has the risk of not only large investments, but also producing products, which may not be of appropriate quality so that there are problems in their commercialization.

7827.

Name the cells of immune system that are affected by HIV?

Answer» Helper T-cells.
7828.

How does the metagenomics approach help to identify novel genes present in the environment? Explain the process.

Answer»

The collective DNA(from various environmental niche) is subjected to restriction digestion using restriction endonucleases and the fragments are cloned into suitable vectors.

The clones are then screened for presence of a variety of molecules. The clones expressing novel molecules or molecules with improved characteristics are used for large-scale production by fermentation techniques.

7829.

Amniocentesis for sex determination is banned in our country. Is this ban necessary? Comment.

Answer»

Yes. Amnicoentesis (alongwith sonography) is being misused to determine the sex of the foetus. Due to small family norm, along with religion and social practices, every family wants a male child. The female foetus is destroyed. This has resulted in decline in female population to less than 50 per 100 males in certain areas. Such an imbalance in sex ratio is bound to create social problems for the future generations. Therefore, the test has been banned.

7830.

Explain giving two reasons why pollen grains can be best preserved as fossils.

Answer»

(i) Pollens are produced in large numbers. 

(ii) The sporopollenin in exine protects the pollen from harsh conditions.

7831.

Explain what is meant by biofortification.

Answer»

Biofortification is a crop breeding programme that is aimed at increasing nutritional quality of the crop like high vitamin content, more minerals, complete proteins and healthier fats, e.g., lysine and tryptophan rich Maize, vitamin A enriched Carrot.

7832.

Explain the following giving reasons: (i) Pollen grains are well preserved as fossils. (ii) Pollen tablets are in use by people these days

Answer»

(i) Pollen grains have thick outer exine which is composed of sporopollenin. Sporopollenin can withstand high temperatures and strong acids and alkalis. Therefore, they are well preserved as fossils. 

(ii) Pollen tablets are used by people because pollens are rich in nutrients.

7833.

A human female experiences two major changes, menarche and menopause during her life. Mention the significance of both the events.

Answer»

(a) Menarche : It is the first menstruation that occurs in the life of a young girl. Menarche is indication of the attainment of sexual maturity and beginning of fertile period. 

(b) Menopause : It is the cessation of menstruation in the life of a women that marks the end of fertile period due to nonrelease of ova.

7834.

Why is the process of fertilisation in angiosperms termed as double fertilisation? Explain.

Answer»

On reaching synergid, pollen tube releases the two male gametes into cytoplasm of synergid. One of the male gamete fuses with egg nucleus to form a diploid zygote. This is called syngamy. Other male gamete fuses with polar nuclei at the centre to produce a triploid primary endosperm nucleus (PEN). This is termed as triple fusion. As syngamy and triple fusion take place simultaneously in the embryo sac, it is termed as double fertilisation. 

7835.

In the given figure of embryo sac label the parts (1), (2),(3) and (4)

Answer» 1. Antipodals,

2. Polar nuclei,

3. Central cell,

4. Egg cell
7836.

Name any five hybrid varieties of crop plants which have been developed in India.

Answer»

(i) Cauliflower varieties – Pusa shubhra and Pusa Snowball K-1

(ii) Brassica varieties – Pusa Swarnim(karan rai)

(iii) Wheat varieties – Himgiri

(iv) Rice varieties – Jaya and Ratana

(v) Chilli varieties – Pusa Sadabahar.

7837.

Expand is CAM.

Answer» Crassulacean Acid Metabolism.
7838.

What is contact inhibition? How does this phenomenon operate in cancer cells? 

Answer»

Contact Inhibition is the property by which contact with other cells inhibits their uncontrolled growth.

This phenomenon is absent in cancer cells.

7839.

What is Biological evolution based on Darwinism.

Answer»

According to Darwin, only fittest individual which shows adaptiability can undergo natural selection process end can produce large number of projeny. According to him, adaptiability which has genetic basis makes individual fit. Such individual are selected by nature and produce large number of projeny

7840.

For which variety of Indian Rice, the patent was filed by U.S.A. company?

Answer»

Indian Basmati Rice was crossed with a semidwarf variety and was claimed to be new scented variety for which patent was filed by a U.S.A. company.

7841.

What is GEAC? What are its objectives?

Answer»

GEAC : Genetic engineering Approval Committee.

Objectives :

(i) Examine the validity of GM research.

(ii) Inspect the safety of use of GMOs.

7842.

Explain any two merits and two limitations of a partnership firm. Is it compulsory to get partnership firm registered? What are the consequences of non registration?

Answer»

Merits : 

(a) Ease of formation and closure: A partnership firm can be formed easily with an agreement between two or more persons to carry some lawful business. There is no compulsion of registration. 

(b) Balanced decision making: Different partners having expertise in different areas of functions can take balanced decisions with the consent of all other partners. There is lesser burden of work. 

(c) More funds: Since the capital is contributed by many partners, it is possible to accumulate more funds for business. 

(d) Sharing of risks: since the risks involved in the business is shared by all the partners, the stress and burden of running the business gets reduced on individual partners. 

(e) Secrecy: it is generally not required to publish its accounts, hence, it can maintain confidentiality of its business operations.

Limitations of partnership 

(a) Unlimited liability: The liability of the partners is joint and several. They are liable to pay the liabilities of the firm in case the business funds are not sufficient to repay its debts. 

(b) Limited Resources: capital investment by partners is low as there is a restriction on the number of partners. The firm cannot expand beyond a certain size. 

(c) Possibility of conflicts: Since the decision making is shared by partners, any difference of opinion may result in disputes, Moreover, the decision of the partnership is binding on all partners. 

(d) Lack of continuity: A partnership may come to an end on the death, retirement, insolvency or lunacy of any one partner. However, the remaining partners may enter into fresh agreement to continue the business. 

(e) Lack of public confidence: Since a partnership is not required by law to publish its accounts, any member of the public finds it difficult to ascertain the true financial status of the firm.

Registration of a partnership firm is not obligatory. It is optional. However, an unregistered firm suffers from serious disabilities. 

Consequences of Non-registration of a firm 

(a) A partner of an unregistered firm cannot file suit against the firm or any other partner 

(b) An unregistered firm cannot file a suit against any third party for the recovery of claims. 

(c) An unregistered firm cannot file suit against any partner. Thus, the Indian Partnership Act, 1932 has effectively ensured the registration of firms without making it compulsory. The third parties, however, can file a suit against the unregistered firm for their claims.

7843.

Differentiate between 

Answer»

The instructions enclosed in the forever block keep on executing till the time the project is running or the Stop button is not pressed. The instructions enclosed in the repeat block execute for the given number of times.

7844.

Differentiate between 

Answer»

The instruction blocks enclosed inside the if …block are executed only if the condition is true. Nothing happens if the condition is false. In case of if..then…else block, the instruction blocks enclosed inside the if are executed if the condition is true. If the condition is false, then the instruction blocks enclosed inside the else part are executed. 

7845.

What will be the final position of the cat (Scratch mascot) after running the following script?

Answer»

 Centre of the stage.

7846.

Which one among the following represents a permanent fastener?(a) Nut(b) Rivet(c) Screw(d) Bolt

Answer»

Rivet represents a permanent fastener.

7847.

What happens when the sprite does not touch the edge of the stage? 

Answer»

 It changes its costume and displays the caller box with message “Safe’ for one second.

7848.

What happens when the sprite does not touch the edge of the stage? above, what happens when the sprite touches the edges. 

Answer»
  • Displays the caller box saying “Touched..” 
  • Turns on the left by 30 degrees 
  • Increases its size by 20 points 
  • Bounces back
7849.

In isometric projection, the four centre method is used to construct(a) an ellipse(b) an involute(c) a parabola(d) a hyperbola

Answer»

(a) an ellipse

7850.

Name the tab and category of blocks that should be selected to do the following: (i) Ask the user’s name(ii) Add a variable to store points of the game

Answer»

(i) Scripts tab/ Sensing category of blocks

(ii) scripts tab / Data category of block