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51.

The unequal sharing of bonded pair of electronsbetween two atoms in a molecule gives rise to:

Answer»

The unequal sharing of bonded pair of electrons
between two atoms in a molecule gives rise to:


52.

The movement of electrons in which one of the structure is not shown correctly?

Answer»

The movement of electrons in which one of the structure is not shown correctly?


53.

Is work done in anticlockwise cycle is positive?

Answer» Is work done in anticlockwise cycle is positive?
54.

What is buckminsterfullerene?

Answer» What is buckminsterfullerene?
55.

the number of atoms of a radioactive subs†an ce of half life T at N not at t=0. the time necessary to decay from Nnot/2atoms to N not/10atoms ll b

Answer» the number of atoms of a radioactive subs†an ce of half life T at N not at t=0. the time necessary to decay from Nnot/2atoms to N not/10atoms ll b
56.

x+ay+a^2 z=0,x+by+y^2z=0,x+y^2z=0

Answer» x+ay+a^2 z=0,x+by+y^2z=0,x+y^2z=0
57.

7.5 ml of a gaseous hydrocarbon was burnt with 36 ml of oxygen .On cooling The volume was found to be 28.5 ml of which 15 ml was absorbed by KOH .find the molecular formula of the hydrocarbon

Answer» 7.5 ml of a gaseous hydrocarbon was burnt with 36 ml of oxygen .On cooling The volume was found to be 28.5 ml of which 15 ml was absorbed by KOH .find the molecular formula of the hydrocarbon
58.

The circumference of the first Bohr orbit in H atom is 3.322 × 10−10 m. What is the velocity of the electron of this orbit?

Answer»

The circumference of the first Bohr orbit in H atom is 3.322 × 1010 m. What is the velocity of the electron of this orbit?


59.

calculate number of moles of KMnO_{} which reacts with 2 N,1500 ml FeC_2O_4

Answer» calculate number of moles of KMnO_{} which reacts with 2 N,1500 ml FeC_2O_4
60.

Two moles of a gas at temperature T and volume V are heated to twice its volume at constant pressure . if Cp/Cv = y then what will be the increase of the internal energy of the gas ?

Answer» Two moles of a gas at temperature T and volume V are heated to twice its volume at constant pressure . if Cp/Cv = y then what will be the increase of the internal energy of the gas ?
61.

Electrode potential of hydrogen electrode is18mV then concentration of H+ is

Answer»

Electrode potential of hydrogen electrode is18mV then concentration of H+ is

62.

Which of the following is known as synthesis gas?

Answer»

Which of the following is known as synthesis gas?


63.

The mole fraction of ethanol in water is 0.40. Calculate its molality.

Answer»

The mole fraction of ethanol in water is 0.40. Calculate its molality.

64.

When vicinal dibromide is heated with KOH in ethanol followed by sodamide (200∘C), double dehydrohalogenation takes place giving alkyne. Which of the following fails to give alkyne according to this procedure?

Answer»

When vicinal dibromide is heated with KOH in ethanol followed by sodamide (200C), double dehydrohalogenation takes place giving alkyne. Which of the following fails to give alkyne according to this procedure?

65.

Calculate the volume of carbondioxide formed at STP and the weight or zinc oxide formed in grams , when 2 . 32 g of zinc carbonate decomposes with no further loss in weight ?

Answer» Calculate the volume of carbondioxide formed at STP and the weight or zinc oxide formed in grams , when 2 . 32 g of zinc carbonate decomposes with no further loss in weight ?
66.

10 L of a monoatomic ideal gas at 0 oC and 10 atm is suddenly released to 1 atm pressure and the gas is expanded adiabatically against the constant pressure. Find the final volume (L) of the gas.

Answer» 10 L of a monoatomic ideal gas at 0 oC and 10 atm is suddenly released to 1 atm pressure and the gas is expanded adiabatically against the constant pressure. Find the final volume (L) of the gas.
67.

nt4K2Cr2O7 -> 4K2CrO4 + 3O2 +X , in this reaction X isn nt(1) CrO3n nt(2) Cr2O7n nt(3) Cr2O3n nt(4) CrO5n

Answer» nt4K2Cr2O7 -> 4K2CrO4 + 3O2 +X , in this reaction X isn nt(1) CrO3n nt(2) Cr2O7n nt(3) Cr2O3n nt(4) CrO5n
68.

What is the difference between 1.Allyl Halides and Allylic Halides2.Benzyl Halides and Benzylic HalidesAnd which of the two in both the cases shows Sn1 and Sn2?

Answer» What is the difference between
1.Allyl Halides and Allylic Halides
2.Benzyl Halides and Benzylic Halides
And which of the two in both the cases shows Sn1 and Sn2?
69.

what is radius ratio of octahedral voids

Answer» what is radius ratio of octahedral voids
70.

Give condensed and bond line structural formulas and identify the functional group(s) present, if any, for: (a)2,2,4-Trimethylpentane (b)2-Hydroxy-1,2,3-propanetricarboxylic acid (c) Hexanedial

Answer»

Give condensed and bond line structural formulas and identify the functional group(s) present, if any, for:

(a)2,2,4-Trimethylpentane
(b)2-Hydroxy-1,2,3-propanetricarboxylic acid
(c) Hexanedial

71.

Thecorrect order of reactivity of groupin given compounds is:

Answer»

The
correct order of reactivity of group
in given compounds is:


72.

38. The vapour pressure of a solution having solid as solute and liquid as solvent is 1) directly proportional to mole fraction of solvent 2) inversely proportional to mole fraction of solvent 3) directly proportional to mole fraction of the solute 4) inversely proportional to mole fraction of the solute

Answer» 38. The vapour pressure of a solution having solid as solute and liquid as solvent is 1) directly proportional to mole fraction of solvent 2) inversely proportional to mole fraction of solvent 3) directly proportional to mole fraction of the solute 4) inversely proportional to mole fraction of the solute
73.

State the number of significant figures in the following: (a) 0.007 m2 (b) 2.64 × 1024 kg (c) 0.2370 g cm–3 (d) 6.320 J (e) 6.032 N m–2 (f) 0.0006032 m2

Answer»

State the number of
significant figures in the following:



(a) 0.007 m2



(b) 2.64 × 1024
kg



(c) 0.2370 g cm–3



(d) 6.320 J



(e) 6.032 N m–2



(f) 0.0006032 m2

74.

43 State the balance chemical equation what happens when excess NH4OH is added dropwise to an aqueous solution of CuSO4

Answer» 43 State the balance chemical equation what happens when excess NH4OH is added dropwise to an aqueous solution of CuSO4
75.

25 The number of H+ ions in 1 ml of a solution of ph=13 is

Answer» 25 The number of H+ ions in 1 ml of a solution of ph=13 is
76.

Read the following questions and answer as per the directions given below:Statement – I: The first ionization energy of Be is greater than that of B.Statement – II: 2p-orbital is lower in energy than 2s.

Answer»

Read the following questions and answer as per the directions given below:


Statement – I: The first ionization energy of Be is greater than that of B.


Statement – II: 2p-orbital is lower in energy than 2s.



77.

38. Number of isomeric forms (constitutional and stereo isomers) for (Rh(en)2(NO2)(SCN))+

Answer» 38. Number of isomeric forms (constitutional and stereo isomers) for (Rh(en)2(NO2)(SCN))+
78.

(CH3COO)2Pb+Ca(OH)2→A+(CH3COO)2Ca A+CaOCl2→B+CaCl2+H2O Identify A and B.

Answer»

(CH3COO)2Pb+Ca(OH)2A+(CH3COO)2Ca

A+CaOCl2B+CaCl2+H2O

Identify A and B.


79.

what is the maximum no of orbitals that can be identified with the following Qnos?n=3,l=1,m=0

Answer» what is the maximum no of orbitals that can be identified with the following Qnos?n=3,l=1,m=0
80.

A gas is heated in a duct as it flows over a resistance heater. Consider a 101 kw electric heating system. The gas enters the heating section of the duct at 100 kPa and 270C with a volume flow rate of 15m3/s. If heat is lost from the gas in the duct to the surroundings at a rate of 51 kW, the exit temperature of the gas is (Assume constant pressure, ideal gas, negligible change in kinetic and potential energies and constant specific heat; Cp=1kJ/kgK;R=0.5kJ/kgK)

Answer»

A gas is heated in a duct as it flows over a resistance heater. Consider a 101 kw electric heating system. The gas enters the heating section of the duct at 100 kPa and 270C with a volume flow rate of 15m3/s. If heat is lost from the gas in the duct to the surroundings at a rate of 51 kW, the exit temperature of the gas is (Assume constant pressure, ideal gas, negligible change in kinetic and potential energies and constant specific heat; Cp=1kJ/kgK;R=0.5kJ/kgK)

81.

What is the normality of a KMnO4 solution in which 15.8 g of KMnO4 is present in 250 mL solution and the solution is used as an oxidant, where MnO4− is reduced to Mn2+ ? (Given: molar mass of KMnO4=158 gmol−1 )

Answer»

What is the normality of a KMnO4 solution in which 15.8 g of KMnO4 is present in 250 mL solution and the solution is used as an oxidant, where MnO4 is reduced to Mn2+ ? (Given: molar mass of KMnO4=158 gmol1 )



82.

Why orbital angular momentum is neglected in the first series from sc to zn

Answer» Why orbital angular momentum is neglected in the first series from sc to zn
83.

The energies of orbitals ( 3s, 3p, 4s, 4p, 3d)of H-atom are in the order

Answer»

The energies of orbitals ( 3s, 3p, 4s, 4p, 3d)of H-atom are in the order

84.

Find the ratio of the difference in energy between the first and the second Bohr's orbit to that between the second and third Bohr's orbit of a hydrogen atom.

Answer»

Find the ratio of the difference in energy between the first and the second Bohr's orbit to that between the second and third Bohr's orbit of a hydrogen atom.

85.

Why boiling point and melting point show different trends? What is the criteria which makes melting point different from boiling point while comparison between elements? eg. Sb has more boiling point but less melting point than Bi?

Answer» Why boiling point and melting point show different trends? What is the criteria which makes melting point different from boiling point while comparison between elements? eg. Sb has more boiling point but less melting point than Bi?
86.

A fixed mass ‘m’ of a gas is subjected to transformation of states from K to L to M to N and back to K shown in figure.The pair of isochoric processes among the transformation of states is

Answer»

A fixed mass ‘m’ of a gas is subjected to transformation of states from K to L to M to N and back to K shown in figure.



The pair of isochoric processes among the transformation of states is



87.

Derivation for average life of a radionuclide

Answer» Derivation for average life of a radionuclide
88.

H2O+H3PO4+H3O++H2PO−4,pk1=2.15 H2O+H2PO−4+H3O++HPO2−4,pk2=7.20 pH of 0.01 M NaH2PO4 is:

Answer» H2O+H3PO4+H3O++H2PO4,pk1=2.15
H2O+H2PO4+H3O++HPO24,pk2=7.20
pH of 0.01 M NaH2PO4 is:
89.

The force between two alpha particles separated by a distance r is?

Answer» The force between two alpha particles separated by a distance r is?
90.

nt for a black body at temperature 727 degree centigrade , its rate of energy loss is 20 watt and temperature of surrounding is 277 degree centigrade. if temperature of black body is changed to 1227 degree centigrade then its rate of energy loss will ben

Answer» nt for a black body at temperature 727 degree centigrade , its rate of energy loss is 20 watt and temperature of surrounding is 277 degree centigrade. if temperature of black body is changed to 1227 degree centigrade then its rate of energy loss will ben
91.

Number of moles of nitrogen atom in 56 grams nitrogen gas

Answer»

Number of moles of nitrogen atom in 56 grams nitrogen gas

92.

Explain absolute configuration (R and S nomenclature)

Answer» Explain absolute configuration (R and S nomenclature)
93.

The number of electrons involved in the reduction of Cr2O2−7 in acidic solution to Cr3+ is

Answer»

The number of electrons involved in the reduction of Cr2O27 in acidic solution to Cr3+ is



94.

13. Enthalpy and entropy changes of a reversible reaction are 40.63 kJ mol–1 and 108.8 J K–1 mol–1 respectively. Predict the feasibility of the reaction at 27^° C.

Answer» 13. Enthalpy and entropy changes of a reversible reaction are 40.63 kJ mol–1 and 108.8 J K–1 mol–1 respectively. Predict the feasibility of the reaction at 27^° C.
95.

Is remembering periodic table necessary?? If it is then how should we learn it?? Periodwise i.e., atomic number wise or grogroup wise (more convenient)??

Answer» Is remembering periodic table necessary?? If it is then how should we learn it?? Periodwise i.e., atomic number wise or grogroup wise (more convenient)??
96.

Complete the following reactions H2(g)+MmO(s)Δ−→ CO(g)+H2(g)Δ−−−−→catalyst C3H8(g)+3H2O(g)Δ−−−−→catalyst Zn(s)+2NaOH(aq)heat−−→

Answer»

Complete the following reactions
H2(g)+MmO(s)Δ

CO(g)+H2(g)Δ−−−catalyst

C3H8(g)+3H2O(g)Δ−−−catalyst

Zn(s)+2NaOH(aq)heat

97.

An aqueous solution of NaCl on electrolysis gives H2,Cl2 and NaOH according to the equation 2Cl- aq + 2H2O =2OH- AQ + H2g +Cl2 g A direct current of 25ampere with a current efficiency of 62% is passed through 20l of NaCl solution (20% by weight) then, the time taken to produce 1kj of cl2 and the molarity of the solution wrt hydroxide ion is

Answer» An aqueous solution of NaCl on electrolysis gives H2,Cl2 and NaOH according to the equation 2Cl- aq + 2H2O =2OH- AQ + H2g +Cl2 g A direct current of 25ampere with a current efficiency of 62% is passed through 20l of NaCl solution (20% by weight) then, the time taken to produce 1kj of cl2 and the molarity of the solution wrt hydroxide ion is
98.

Explain why the following systems are not aromatic?(i)(ii)(iii)

Answer»

Explain why the following systems are not aromatic?


(i)



(ii)



(iii)


99.

Three different processes that can occur in an ideal monoatomic gas are shown in the P vs V diagram. The paths are labelled as A→B, A→C and A→D. The change in internal energies during these process are taken as EAB, EAC and EAD and the workdone as WAB,WAC and WAD. The correct relation between these parameters are

Answer»

Three different processes that can occur in an ideal monoatomic gas are shown in the P vs V diagram. The paths are labelled as AB, AC and AD. The change in internal energies during these process are taken as EAB, EAC and EAD and the workdone as WAB,WAC and WAD. The correct relation between these parameters are




100.

Calculate osmotic pressure of 3.42% w/V solution of cane sugar (sucrose) at 27∘C.Given:Molecular formula of sucrose is C12H22O11

Answer»

Calculate osmotic pressure of 3.42% w/V solution of cane sugar (sucrose) at 27C.

Given:

Molecular formula of sucrose is C12H22O11