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2901.

The dissociation constants for acetic acid and HCN at 25∘C are 1.5×10−5 and 4.5×10−10, respectively. The equilibrium constant for the equilibrium, CN−+CH3COOH⇌HCN+CH3COO− would be?

Answer»

The dissociation constants for acetic acid and HCN at 25C are 1.5×105 and 4.5×1010, respectively. The equilibrium constant for the equilibrium, CN+CH3COOHHCN+CH3COO would be?

2902.

find the compound ratio of:3a:2b,2m:n and 4x:3y

Answer» find the compound ratio of:3a:2b,2m:n and 4x:3y
2903.

Column - IColumn - IIi.[Ni(CO)4]Planar octahedral, diamagneticii.[Fe(NO)(H2O)5]2+Planar, paramagneticiii.[Co(NO2)6]3−Octahedral, diamagneticiv.[Cu(NH3)4]2+Planar octahedral, paramagneticOctahedral, paramagnetic

Answer» Column - IColumn - IIi.[Ni(CO)4]Planar octahedral, diamagneticii.[Fe(NO)(H2O)5]2+Planar, paramagneticiii.[Co(NO2)6]3Octahedral, diamagneticiv.[Cu(NH3)4]2+Planar octahedral, paramagneticOctahedral, paramagnetic
2904.

Calculatethe number of kJ of heat necessary to raise the temperatureof 60.0 g of aluminium from 35°C to 55°C. Molar heat capacityof Al is 24 J mol–1K–1.

Answer»

Calculate
the number of kJ of heat necessary to raise the temperature

of 60.0 g of aluminium from 35°C to 55°C. Molar heat capacity
of Al is 24 J mol
–1
K–1.

2905.

At the same temperature and pressure, which of the following gas has the highest kinetic energy :

Answer»

At the same temperature and pressure, which of the following gas has the highest kinetic energy :


2906.

7. Molality of 100 g of 20% (w/w) of aqueous common solution is approximately

Answer» 7. Molality of 100 g of 20% (w/w) of aqueous common solution is approximately
2907.

Write the structural formulae of all the isomers of hexane.

Answer» Write the structural formulae of all the isomers of hexane.
2908.

WHY RATE CONSTANT(K) IS INDEPENDENT OF INITIAL CONCENTRATION OF REACTENT?

Answer» WHY RATE CONSTANT(K) IS INDEPENDENT OF INITIAL CONCENTRATION OF REACTENT?
2909.

Glycerineflows steadily through a horizontal tube of length 1.5 m and radius1.0 cm. If the amount of glycerine collected per second at one end is4.0 × 10–3kg s–1,what is the pressure difference between the two ends of the tube?(Density of glycerine = 1.3 × 103kg m–3and viscosity of glycerine = 0.83 Pa s). [You may also like to checkif the assumption of laminar flow in the tube is correct].

Answer»

Glycerine
flows steadily through a horizontal tube of length 1.5 m and radius
1.0 cm. If the amount of glycerine collected per second at one end is
4.0 × 10–3
kg s–1,
what is the pressure difference between the two ends of the tube?
(Density of glycerine = 1.3 × 103
kg m–3
and viscosity of glycerine = 0.83 Pa s). [You may also like to check
if the assumption of laminar flow in the tube is correct].

2910.

assertion: cis-1,3-dihydroxycyclohexane exists in boat conformationreason: in the boat form there will not be hydrogen bonding between the 2 hydroxyl groups

Answer» assertion: cis-1,3-dihydroxycyclohexane exists in boat conformation
reason: in the boat form there will not be hydrogen bonding between the 2 hydroxyl groups
2911.

Sodium ethoxide is allowed to react with {1 -(chloromethy) oxirane. The major product is expected to be

Answer» Sodium ethoxide is allowed to react with {1 -(chloromethy) oxirane. The major product is expected to be
2912.

Two liquids A and B mixed such that the adhesive forces between molecules are much larger than their respective cohesive forces. In such case, the solution will

Answer»

Two liquids A and B mixed such that the adhesive forces between molecules are much larger than their respective cohesive forces. In such case, the solution will


2913.

If the azimuthal quantum no. of a subenergy level is 4, then the maximum and minimum values of spin multiplicities are (1) 9,1 (2) 10,1 (3) 10,2 (4) 4,-4

Answer» If the azimuthal quantum no. of a subenergy level is 4, then the maximum and minimum values of spin multiplicities are (1) 9,1 (2) 10,1 (3) 10,2 (4) 4,-4
2914.

Among the following compounds, the one that is polar and has the central atom with sp2 hybridization is:

Answer»

Among the following compounds, the one that is polar and has the central atom with sp2 hybridization is:



2915.

Four diatomic species are listed below. Identify the correct order of increasing bond order:

Answer»

Four diatomic species are listed below. Identify the correct order of increasing bond order:

2916.

Q.5 The speed of an electron in in the second orbit of hydrogen atom

Answer» Q.5 The speed of an electron in in the second orbit of hydrogen atom
2917.

Which of the following molecules follows octet rule?

Answer»

Which of the following molecules follows octet rule?

2918.

What should be the reagent(s) and/or solvent to accomplish the following reaction?

Answer»

What should be the reagent(s) and/or solvent to accomplish the following reaction?


2919.

48 What happens when 2 equivalent HCl is added to 1-(2-Methylprop-1-enyl)cyclopent-1-ene ?

Answer» 48 What happens when 2 equivalent HCl is added to 1-(2-Methylprop-1-enyl)cyclopent-1-ene ?
2920.

A polyhydroxy compund P (Molar weight=92 gm/mol) when heated with oxalic acid at 110∘C, forms a carboxylic acid which is found in ant bodies. When the same compound P is heated with oxalic acid at or above 260∘C, a compound Q along with gas G which turns lime water milky and a liquid L which turns anhydrous CuSO4 blue are formed. What is vapour density of Q?

Answer» A polyhydroxy compund P (Molar weight=92 gm/mol) when heated with oxalic acid at 110C, forms a carboxylic acid which is found in ant bodies. When the same compound P is heated with oxalic acid at or above 260C, a compound Q along with gas G which turns lime water milky and a liquid L which turns anhydrous CuSO4 blue are formed. What is vapour density of Q?
2921.

In a mildly alkaline medium, thiosulphate ion is oxidized by KMnO4 to "A". The oxidation state of sulphur in "A" is:

Answer» In a mildly alkaline medium, thiosulphate ion is oxidized by KMnO4 to "A". The oxidation state of sulphur in "A" is:
2922.

State the comparison between reversible and irreversible reaction.

Answer» State the comparison between reversible and irreversible reaction.
2923.

Othophosphoric acidgentle heat−−−−−−→220∘CX. What is(are) correct about X?

Answer»

Othophosphoric acidgentle heat−−−−−220CX.

What is(are) correct about X?


2924.

What will happen if we add chloretone and acid with chlobenzene and heat it. Give the equation

Answer»

What will happen if we add chloretone and acid with chlobenzene and heat it. Give the equation

2925.

35. 40% N_2O_4 molecules dissociates into NO_2 in a sample of gas at 27 degree celcius and 760 torr. The density of the equilibrium mixture is ??

Answer» 35. 40% N_2O_4 molecules dissociates into NO_2 in a sample of gas at 27 degree celcius and 760 torr. The density of the equilibrium mixture is ??
2926.

8. The rate of a reaction (activation energy E1)increase twice as fast as the rate constant of a second reaction (activation energy E2). relationship between E1and E2 is?

Answer» 8. The rate of a reaction (activation energy E1)increase twice as fast as the rate constant of a second reaction (activation energy E2). relationship between E1and E2 is?
2927.

60.Charge q is uniformly distributed over a thin half ring of radius R .The electric field at the centre of the ring is

Answer» 60.Charge q is uniformly distributed over a thin half ring of radius R .The electric field at the centre of the ring is
2928.

Hydrazine (N2H4) can be produced according to the following reaction:ClNH2+2NH3→N2H4+NH4Cl. 1 kg of ClNH2 is reacted with excess NH3, find the actual number of molecules of N2H4 produced if the percentage yield of the given reaction is 76%.

Answer»

Hydrazine (N2H4) can be produced according to the following reaction:

ClNH2+2NH3N2H4+NH4Cl. 1 kg of ClNH2 is reacted with excess NH3, find the actual number of molecules of N2H4 produced if the percentage yield of the given reaction is 76%.


2929.

Why are copper Gold Silver sols called negatively charged sols?

Answer» Why are copper Gold Silver sols called negatively charged sols?
2930.

Carry out the following conversion1). Ethanoic anhydride to ethanol. 2).Ethyl propanoate to ethanol. 3) Ethyl propanoate to propanol. 4).Ethanol to propane nitrite

Answer»

Carry out the following conversion

1). Ethanoic anhydride to ethanol.

2).Ethyl propanoate to ethanol.

3) Ethyl propanoate to propanol.

4).Ethanol to propane nitrite

2931.

Question 26The name of the compound CH3−CH2−CHO(a) Propanal(b) Propanone(c) Ethanol(d) Ethanal

Answer» Question 26

The name of the compound CH3CH2CHO



(a) Propanal

(b) Propanone

(c) Ethanol

(d) Ethanal
2932.

e enthalpy of hydrogenation of cyclohexene is119.5 kJ mol-1. If resonance energy of benzene is-150.4 kJ mol-1, its enthalpy of hydrogenationwould be(1) -358.5 kJ mol-1(3) -208.1 kJ mol-1(2) -508.9 kJ mol-14) -269.9 kJ mol-1

Answer» e enthalpy of hydrogenation of cyclohexene is119.5 kJ mol-1. If resonance energy of benzene is-150.4 kJ mol-1, its enthalpy of hydrogenationwould be(1) -358.5 kJ mol-1(3) -208.1 kJ mol-1(2) -508.9 kJ mol-14) -269.9 kJ mol-1
2933.

3000 J of heat is given to a gas at a constant pressure of P =2×105 N/m2. If its volume increases by 10 litres during the process, find the change in internal energy of the gas. (in Joules)

Answer» 3000 J of heat is given to a gas at a constant pressure of
P =2×105 N/m2.
If its volume increases by 10 litres during the process, find the change in internal energy of the gas. (in Joules)
2934.

Choose the graph which correctly represents the reaction path when a negative catalyst is present.Graph for uncatalysed reaction:

Answer»

Choose the graph which correctly represents the reaction path when a negative catalyst is present.

Graph for uncatalysed reaction:


2935.

Which of the following salts will give highest pH in water?

Answer»

Which of the following salts will give highest pH in water?

2936.

Prepare n-erhylamine from grignard reagent in one step

Answer» Prepare n-erhylamine from grignard reagent in one step
2937.

Justify that the following reactions are redox reactions:(a) CuO(s) + H2(g) → Cu(s) + H2O(g)(b) Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)(c) 4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3 (s)(d) 2K(s) + F2(g) → 2K+F– (s)(e) 4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)

Answer»

Justify that the following reactions are redox reactions:


(a) CuO(s) + H2(g) → Cu(s) + H2O(g)


(b) Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)


(c) 4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3 (s)


(d) 2K(s) + F2(g) → 2K+F– (s)


(e) 4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)

2938.

doeas cross conjugation increase or decrease stability of a compound?

Answer» doeas cross conjugation increase or decrease stability of a compound?
2939.

The amount of urea to be dissolved in 500 cc of water (Kf=1.86∘C kg mol−1) to produce a depression of 0.186∘C in the freezing point is:( Molar mass of urea = 60 g/mol)

Answer»

The amount of urea to be dissolved in 500 cc of water (Kf=1.86C kg mol1) to produce a depression of 0.186C in the freezing point is:

( Molar mass of urea = 60 g/mol)

2940.

What is the difference between acid catalyzed deuteration and base catalyzed deuteration?

Answer» What is the difference between acid catalyzed deuteration and base catalyzed deuteration?
2941.

38. Why does solubility of NaCl remains unchanged when temperature is increased

Answer» 38. Why does solubility of NaCl remains unchanged when temperature is increased
2942.

The major product(s) obtained in the following reaction is/are:

Answer»

The major product(s) obtained in the following reaction is/are:




2943.

31. what is lattice enthalpy ?

Answer» 31. what is lattice enthalpy ?
2944.

ChI3 forms { } with Ag

Answer» ChI3 forms { } with Ag
2945.

200 mL of 0.1 M H2SO4 is added to 300 mL of 0.1 M NaOH solution. Find the normality of the ions in excess (H+ or OH−) in the resultant solution.

Answer» 200 mL of 0.1 M H2SO4 is added to 300 mL of 0.1 M NaOH solution. Find the normality of the ions in excess (H+ or OH) in the resultant solution.
2946.

What is the IUPAC name of the simplest bicyclo compound?

Answer»

What is the IUPAC name of the simplest bicyclo compound?



2947.

The Preamble consists of how many basic features?

Answer»

The Preamble consists of how many basic features?


2948.

Find the area bounded by curves

Answer»

Find the area bounded by curves

2949.

86. What is oxidation number oc manganese in KMnO4

Answer» 86. What is oxidation number oc manganese in KMnO4
2950.

The ratio of the electronegativity values in Muliken scale to the Pauling scale is :

Answer»

The ratio of the electronegativity values in Muliken scale to the Pauling scale is :