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401.

Which of the following isoelectronic ions have lowest ionization energy?

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Which of the following isoelectronic ions have lowest ionization energy?

402.

Which of the following is a natural polymer?

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Which of the following is a natural polymer?



403.

Please give the product of the reactions below:

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Please give the product of the reactions below:




404.

What is the correct order of increasing second ionisation energies for the elements Be, B, C, N and F?

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What is the correct order of increasing second ionisation energies for the elements Be, B, C, N and F?

405.

Which of the following cannot work as oxidising agent?

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Which of the following cannot work as oxidising agent?



406.

In terms of thermal stability of the alkali metal hydrides, which one is the most stable?

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In terms of thermal stability of the alkali metal hydrides, which one is the most stable?



407.

Which of the following is correct order of stability?

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Which of the following is correct order of stability?



408.

What is normality of a solution?

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What is normality of a solution?



409.

The emf of the cell Zn|Zn2+(0.1M) || Fe2+|Fe(0.01M) is 0.2905 V. Equilibrium constant for the cell reaction is

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The emf of the cell Zn|Zn2+(0.1M) || Fe2+|Fe(0.01M) is 0.2905 V. Equilibrium constant for the cell reaction is

410.

Select the correct order of molecular velocities.

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Select the correct order of molecular velocities.



411.

4 g of argon (Atomic mass = 40) in a bulb at a temperature of T K has a pressure P atm. When the bulb was placed in a hot bath at a temperature 50∘C more that the first one, 0.8 g of the gas had to be removed to get the original pressure. T is equal to:

Answer» 4 g of argon (Atomic mass = 40) in a bulb at a temperature of T K has a pressure P atm. When the bulb was placed in a hot bath at a temperature 50C more that the first one, 0.8 g of the gas had to be removed to get the original pressure. T is equal to:
412.

A mixture of three amines A, B and C is treated with Benzene sulphonyl chloride and filtered.' B' is obtained in the filterate. The mixture containing A and C is treated with KOH so that' A' becomes soluble while 'C' does not. Now A, B and C are

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A mixture of three amines A, B and C is treated with Benzene sulphonyl chloride and filtered.' B' is obtained in the filterate. The mixture containing A and C is treated with KOH so that' A' becomes soluble while 'C' does not. Now A, B and C are



413.

Treatment of benzene with CO/HCl in the presence of anhydrous AlCl3/CuCl followed by reaction with Ac2O/NaOAc gives compound X as the major product. Compound X upon reaction with Br2/Na2CO3, followed by heating at 473 K with moist KOH furnishes Y as the major product. Reaction of X with H2/Pd−C,followed by H3PO4 treatment gives Z as the major product.The compound Y is:

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Treatment of benzene with CO/HCl in the presence of anhydrous AlCl3/CuCl followed by reaction with Ac2O/NaOAc gives compound X as the major product. Compound X upon reaction with Br2/Na2CO3, followed by heating at 473 K with moist KOH furnishes Y as the major product. Reaction of X with H2/PdC,followed by H3PO4 treatment gives Z as the major product.

The compound Y is:

414.

The power of halides of boron to act as Lewis acids decreases in the order:

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The power of halides of boron to act as Lewis acids decreases in the order:



415.

Phosgene is the common name for[DPMT 1983; CPMT 1993; MP PMT 1994; Kurukshetra CEE 1998; RPMT 2000, 02]

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Phosgene is the common name for


[DPMT 1983; CPMT 1993; MP PMT 1994;


Kurukshetra CEE 1998; RPMT 2000, 02]



416.

Calculate the pH of an aqueous solution of 1.0 M ammonium formate assuming complete dissociation. (pKa of formic acid = 3.8 and pKb of ammonia = 4.8)

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Calculate the pH of an aqueous solution of 1.0 M ammonium formate assuming complete dissociation. (pKa of formic acid = 3.8 and pKb of ammonia = 4.8)



417.

3 g of a salt of molecular mass 30 is dissolved in 250 g of water. The molality of the solution is:

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3 g of a salt of molecular mass 30 is dissolved in 250 g of water. The molality of the solution is:



418.

The reaction, 3ClO−(aq)⟶ClO−3(aq)+2Cl−(aq) is an example of:

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The reaction, 3ClO(aq)ClO3(aq)+2Cl(aq) is an example of:



419.

Nitrogen tetra oxide (N2O4) decomposes as N2O4(g)→2NO2(g). If the pressure of (N2O4) falls from 0.50 atm to 0.32 atm is 30 minutes, the rate of appearance of NO2(g) is

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Nitrogen tetra oxide (N2O4) decomposes as N2O4(g)2NO2(g). If the pressure of (N2O4) falls from 0.50 atm to 0.32 atm is 30 minutes, the rate of appearance of NO2(g) is

420.

The X -X bond length is 1 ∘A and Y - Y bond length is 1.54 ∘A. If electronegativities of 'X' and 'Y' are 3.0 and 2.0 respectively, the X - Y bond length is likely to be

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The X -X bond length is 1 A and Y - Y bond length is 1.54 A. If electronegativities of 'X' and 'Y' are 3.0 and 2.0 respectively, the X - Y bond length is likely to be

421.

Identify the final products from the following:

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Identify the final products from the following:
422.

When Ethyl magnesium bromide is treated with heavy water, the expected compound will be

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When Ethyl magnesium bromide is treated with heavy water, the expected compound will be



423.

Normality of 2M sulphuric acid is

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Normality of 2M sulphuric acid is

424.

On bombarding 7N14 with α -particles, the nuclei of the product formed after the release of a proton will be or In nuclear reaction 7N14+2He4→zXA+1H1, the term zXA represents

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On bombarding 7N14 with α -particles, the nuclei of the product formed after the release of a proton will be or In nuclear reaction 7N14+2He4zXA+1H1, the term zXA represents

425.

When one mole of monoatomic ideal gas at temperature T undergoes adiabatic change reversibly, change in volume is from 1 L to 2L, the final temperature in Kelvin would be

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When one mole of monoatomic ideal gas at temperature T undergoes adiabatic change reversibly, change in volume is from 1 L to 2L, the final temperature in Kelvin would be

426.

Which of the following is not correct?Organometallics can play an ever expanding role in the production of

Answer» Which of the following is not correct?

Organometallics can play an ever expanding role in the production of

427.

IUPAC nomenclature of

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IUPAC nomenclature of



428.

An electrochemical cell has two half cell reactions as,Y3++3e−→Y: E=0.22VZ→Z3++3e−: E=2.27VCalculate the Ecell.

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An electrochemical cell has two half cell reactions as,

Y3++3eY: E=0.22V

ZZ3++3e: E=2.27V

Calculate the Ecell.

429.

Which of the following compound is aromatic?

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Which of the following compound is aromatic?

430.

If a gas at 5 atm and 373 K expands against a constant external pressure of 1 atm from a volume of 2 litres to 10 litres, the amount of work done is:(Given: 1L.atm=101.3 J)

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If a gas at 5 atm and 373 K expands against a constant external pressure of 1 atm from a volume of 2 litres to 10 litres, the amount of work done is:

(Given: 1L.atm=101.3 J)

431.

If the radius ratio is between 0.414 - 0.732, what will be the type of void present? What will be the coordination number?

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If the radius ratio is between 0.414 - 0.732, what will be the type of void present? What will be the coordination number?



432.

At 250C and 1 atmospheric pressure, the partial pressures in equilibrium mixture of gaseous N2O4 and NO2 are 0.7 and 0.3 atm respectively. Calculate the partial pressure of the N2O4 gas when it is in equilibrium 25oC and the total pressure of 10 atm

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At 250C and 1 atmospheric pressure, the partial pressures in equilibrium mixture of gaseous N2O4 and NO2 are 0.7 and 0.3 atm respectively. Calculate the partial pressure of the N2O4 gas when it is in equilibrium 25oC and the total pressure of 10 atm

433.

The kind of delocalization involving sigma bond orbitals is called:

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The kind of delocalization involving sigma bond orbitals is called:



434.

The following diagram represents

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The following diagram represents




435.

The correct increasing order of energy between 8s and 8p orbital are

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The correct increasing order of energy between 8s and 8p orbital are

436.

Which of the following solutions has the maximum pH value?

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Which of the following solutions has the maximum pH value?



437.

Standard molar enthalpy of formation of CO2 is equal to

Answer» Standard molar enthalpy of formation of CO2 is equal to
438.

The species that contains 24 protons, 26 neutrons and 22 electrons would be represented by the symbol:

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The species that contains 24 protons, 26 neutrons and 22 electrons would be represented by the symbol:

439.

The kinetic theory of gases perdicts that total kinetic energy of a gaseous assembly depends on

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The kinetic theory of gases perdicts that total kinetic energy of a gaseous assembly depends on




440.

In an exothermic reaction A→B, the activation energy of reverse reaction is twice that of forward reaction. If enthalpy of the reaction is -80 kJ mol−1, the activation energy of the reverse reaction is :

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In an exothermic reaction AB, the activation energy of reverse reaction is twice that of forward reaction. If enthalpy of the reaction is -80 kJ mol1, the activation energy of the reverse reaction is :



441.

Which of the statements is wrong among the following?

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Which of the statements is wrong among the following?



442.

The number of moles of oxygen in one litre of air containing 21% oxygen by volume, under standard conditions are:

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The number of moles of oxygen in one litre of air containing 21% oxygen by volume, under standard conditions are:

443.

Of the given options, choose the combination that contains metals whose ores are most appropriate for roasting. In other words, Sulphide ores are common for which kind of metals?

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Of the given options, choose the combination that contains metals whose ores are most appropriate for roasting. In other words, Sulphide ores are common for which kind of metals?



444.

For the chemical equilibrium, CaCO3(s) ⇌ CaO(s) + CO2(g),ΔH.,can be determined from which one of the following plots

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For the chemical equilibrium, CaCO3(s) CaO(s) + CO2(g),ΔH.,can be determined from which one of the following plots



445.

The solubility product of Mg(OH)2 at 25∘C is 1.4 × 10−11. The solubility of Mg(OH)2 in gm per litre is:

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The solubility product of Mg(OH)2 at 25C is 1.4 × 1011. The solubility of Mg(OH)2 in gm per litre is:



446.

What will be the solubility of Cd(CN)2 in 0.05 M NaCN solution if the Ksp is 1.0×10−8 mol3 L−3?Cd(CN)2⇌Cd2++2CN−NaCN→Na++CN−

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What will be the solubility of Cd(CN)2 in 0.05 M NaCN solution if the Ksp is 1.0×108 mol3 L3?

Cd(CN)2Cd2++2CNNaCNNa++CN

447.

The order of the oxidation state of the phosphorous atom in H3PO2,H3PO4,H3PO3, and H4P2O6 is

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The order of the oxidation state of the phosphorous atom in H3PO2,H3PO4,H3PO3, and H4P2O6 is

448.

Which of the following elements is industrially produced for uranium enrichment?

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Which of the following elements is industrially produced for uranium enrichment?



449.

Consider the composite system shown in the figure which is held at 300 K. Assuming ideal gas behavior, calculate the total pressure if the barriers separating the compartments are removed. Assume that the volume of the barriers is negligible. (Given: R = 0.082 atm L−1mol−1k−1 ­­)

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Consider the composite system shown in the figure which is held at 300 K. Assuming ideal gas behavior, calculate the total pressure if the barriers separating the compartments are removed. Assume that the volume of the barriers is negligible. (Given: R = 0.082 atm L1mol1k1 ­­)




450.

Among the following which one is linear?

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Among the following which one is linear?