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651.

A non C - C bond formation is not possible in :

Answer» A non C - C bond formation is not possible in :
652.

NiCl2+KCN(excess)→A(cyano complex)NiCl2+conc.HCl(excess)→B(Chloro complex)The hybridisation of A and B are:

Answer» NiCl2+KCN(excess)A(cyano complex)

NiCl2+conc.HCl(excess)B(Chloro complex)

The hybridisation of A and B are:
653.

A negatively charged suspension of clay in water will need for precipitation the minimum amount of

Answer»

A negatively charged suspension of clay in water will need for precipitation the minimum amount of



654.

Which one of the following transition metal ion shows magnetic moment 5.92 BM

Answer» Which one of the following transition metal ion shows magnetic moment 5.92 BM
655.

A vessel contains 100 litres of a liquid x. Heat is supplied to the liquid in such a fashion that, Heat given = change in enthalpy. The volume of the liquid increases by 2 litres. If the external pressure is one atm, and 202.6 Joules of heat were supplied then, [ U - total internal energy ]

Answer»

A vessel contains 100 litres of a liquid x. Heat is supplied to the liquid in such a fashion that, Heat given = change in enthalpy. The volume of the liquid increases by 2 litres. If the external pressure is one atm, and 202.6 Joules of heat were supplied then, [ U - total internal energy ]



656.

Match the following

Answer»

Match the following




657.

Aqueous solution of the following compound on electrolysis gives ethane

Answer»

Aqueous solution of the following compound on electrolysis gives ethane



658.

A hydrocarbon X adds on one mole of hydrogen to give another hydrocarbon and decolourised bromine water. X reacts with KMnO4 in presence of acid to give two moles of the same carboxylic acid. The structure of X is

Answer»

A hydrocarbon X adds on one mole of hydrogen to give another hydrocarbon and decolourised bromine water. X reacts with KMnO4 in presence of acid to give two moles of the same carboxylic acid. The structure of X is

659.

On hydrolysis with dil H2SO4, starch and cellulose give 'X' and 'Y'. Then 'X' and 'Y' are a pair of

Answer»

On hydrolysis with dil H2SO4, starch and cellulose give 'X' and 'Y'. Then 'X' and 'Y' are a pair of



660.

A conjugated alkadiene having molecular formula C12H22 on ozonolysis yields butanone, ethanedial and cyclohexanecarbaldehyde. Which of the following is the correct structural formula ofthe alkadiene.

Answer»

A conjugated alkadiene having molecular formula C12H22 on ozonolysis yields butanone, ethanedial and cyclohexanecarbaldehyde. Which of the following is the correct structural formula ofthe alkadiene.

661.

The activation energy for a reaction at the temperature TK was found to be 2.303 RTJmol−1. The ratio of the rate constant to Arrhenius factor is ___

Answer»

The activation energy for a reaction at the temperature TK was found to be 2.303 RTJmol1. The ratio of the rate constant to Arrhenius factor is ___

662.

which one of the given options would convert propylbenzene into (1-methoxypropyl)benzene:

Answer»

which one of the given options would convert propylbenzene into (1-methoxypropyl)benzene:



663.

Which of the following is not a double salt?

Answer» Which of the following is not a double salt?
664.

Which of the following compounds has the maximum molar conductivity?

Answer»

Which of the following compounds has the maximum molar conductivity?

665.

The enol form of acetone, after treatment with D2,O, gives

Answer» The enol form of acetone, after treatment with D2,O, gives


666.

Assuming that water vapour is an ideal gas, the internal energy change (∆U) when 1 mol of water is vapourised at 1 bar pressure and 100∘ C, (given : molar enthalpy of vapourisation of water at 1 bar and 373 K = 41 kJ mol−1 and R = 8.3 J mol−1 K−1 ) will be

Answer»

Assuming that water vapour is an ideal gas, the internal energy change (∆U) when 1 mol of water is vapourised at 1 bar pressure and 100 C, (given : molar enthalpy of vapourisation of water at 1 bar and 373 K = 41 kJ mol1 and R = 8.3 J mol1 K1 ) will be



667.

What is the molar solubility of Ag2CO3(Ksp=4×10−13) in 0.1 M Na2CO3 solution?

Answer»

What is the molar solubility of Ag2CO3(Ksp=4×1013) in 0.1 M Na2CO3 solution?

668.

The above P-V diagram represents the thermodynamic cycle of an engine, operating with an ideal monoatomic gas. The amount of heat, extracted from the source in a single cycle is:

Answer»

The above P-V diagram represents the thermodynamic cycle of an engine, operating with an ideal monoatomic gas. The amount of heat, extracted from the source in a single cycle is:


669.

Which of the following is not a process in the extraction of metals?

Answer»

Which of the following is not a process in the extraction of metals?



670.

For a first order reaction, A → P, the temperature (T) dependent rate constant (k) was found to follow the equation:log k=2000T+6.0the pre - exponential factor A and the activation energy Eα. respectively, are:

Answer»

For a first order reaction, A P, the temperature (T) dependent rate constant (k) was found to follow the equation:

log k=2000T+6.0

the pre - exponential factor A and the activation energy Eα. respectively, are:

671.

If the observed and the theoretical molecular mass of NaCl is found to be 31.80 and 58.50, then the percentage dissociation of NaCl is

Answer»

If the observed and the theoretical molecular mass of NaCl is found to be 31.80 and 58.50, then the percentage dissociation of NaCl is



672.

Mark out the incorrect pair of compounds and their shapes:

Answer»

Mark out the incorrect pair of compounds and their shapes:

673.

What would be the product when propene reacts with chlorine in presence of CCl4?

Answer»

What would be the product when propene reacts with chlorine in presence of CCl4?

674.

The ozonolysis products of an olefin are OHC−CHO and OHC−CH2−CH2−CHO, the olefin is:

Answer»

The ozonolysis products of an olefin are OHCCHO and OHCCH2CH2CHO, the olefin is:

675.

Calculate oxidation state of Ag in Ag[(S2O3)2]3− molecule

Answer»

Calculate oxidation state of Ag in Ag[(S2O3)2]3 molecule

676.

The ionic radii of isoelectronic species N3−, O2− and F− in oA are respectively:

Answer»

The ionic radii of isoelectronic species N3, O2 and F in oA are respectively:


677.

Reaction of phenol with dil. HNO3 gives [KCET 1993; RPMT 1997]

Answer»

Reaction of phenol with dil. HNO3 gives [KCET 1993; RPMT 1997]



678.

The ground state electronic configuration of nitrogen atom can be represented by

Answer»

The ground state electronic configuration of nitrogen atom can be represented by

679.

A cubical vessel has a side with 'I' cm lenth contained a gas at a pressure of 'p'. when the side of the vessel is made 12 cm, the pressure of gas becomes?

Answer»

A cubical vessel has a side with 'I' cm lenth contained a gas at a pressure of 'p'. when the side of the vessel is made 12 cm, the pressure of gas becomes?



680.

What compound is formed when copper sulphate solution reacts with an excess of KCN?

Answer»

What compound is formed when copper sulphate solution reacts with an excess of KCN?

681.

If the radius of the second Bohr orbit of hydrogen atom is r2, the radius of the third Bohr orbit will be

Answer»

If the radius of the second Bohr orbit of hydrogen atom is r2, the radius of the third Bohr orbit will be



682.

The correct order of total number of nodes of atomic orbitals is:

Answer»

The correct order of total number of nodes of atomic orbitals is:

683.

Aqueous sulphuric acid reacts with 2-methyl-1-butene to give predominantly

Answer» Aqueous sulphuric acid reacts with 2-methyl-1-butene to give predominantly
684.

Which of the following is an example for intra-molecular redox reaction?

Answer»

Which of the following is an example for intra-molecular redox reaction?

685.

Meso compounds do not show optical activity because they

Answer»

Meso compounds do not show optical activity because they



686.

Which are the starting materials for the preparation of

Answer»

Which are the starting materials for the preparation of



687.

10 L of a monoatomic ideal gas at 0oC and 5 atm is suddenly released to 1 atm pressure and the gas is expanded adiabatically against the constant pressure. Find the final volume (in L) of the gas.

Answer» 10 L of a monoatomic ideal gas at 0oC and 5 atm is suddenly released to 1 atm pressure and the gas is expanded adiabatically against the constant pressure. Find the final volume (in L) of the gas.
688.

C2H5Cl+NaDry ether−−−−−−→X+NaCl Number of possible structural and stereo isomers for mono chloro derivatives of 'X' are

Answer»

C2H5Cl+NaDry ether−−−−−X+NaCl Number of possible structural and stereo isomers for mono chloro derivatives of 'X' are



689.

The base found only in the nucleotide of RNA is

Answer»

The base found only in the nucleotide of RNA is


690.

The degrees of freedom of Oxygen gas molecule at normal temperature is:

Answer»

The degrees of freedom of Oxygen gas molecule at normal temperature is:

691.

A mixture of HCOOH and H2C2O4 is heated with concentrated H2SO4. The gas produced is collected and on treating with KOH solution, the volume of the gas decreases by 16th. The molar ratio of the two acids (HCOOH : H2C2O4) in the original mixture is:The corresponding reactions are:HCOOHH2SO4−−−−→H2O+CO H2C2O4H2SO4−−−−→H2O+CO2+COAssume that the water produced is in liquid state.

Answer»

A mixture of HCOOH and H2C2O4 is heated with concentrated H2SO4. The gas produced is collected and on treating with KOH solution, the volume of the gas decreases by 16th. The molar ratio of the two acids (HCOOH : H2C2O4) in the original mixture is:



The corresponding reactions are:

HCOOHH2SO4−−−H2O+CO

H2C2O4H2SO4−−−H2O+CO2+CO



Assume that the water produced is in liquid state.


692.

The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1:4. Their ratio of number of molecules is:

Answer»

The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1:4. Their ratio of number of molecules is:

693.

LiH+B2H6Ether−−−→A. A is as follows

Answer»

LiH+B2H6Ether−−A. A is as follows



694.

​​​​​​The decreasing order of pKa value of the following is: I. CH≡CHII. III.

Answer»

​​​​​​The decreasing order of pKa value of the following is:

I. CHCH

II.

III.

695.

Osmotic pressure is 0.0821 atm at a temperature of 300 K. Find concentration in mole/litre.

Answer»

Osmotic pressure is 0.0821 atm at a temperature of 300 K. Find concentration in mole/litre.



696.

An example of a psychiatric agent is

Answer»

An example of a psychiatric agent is



697.

Which of thefollowing is correct[DPMT 1997]

Answer»

Which of the
following is correct

[DPMT 1997]


698.

Identify the correct balanced redox reaction by using ion-electron method:BiO−3+Mn2+→Bi3++MnO−4+H2O

Answer»

Identify the correct balanced redox reaction by using ion-electron method:

BiO3+Mn2+Bi3++MnO4+H2O

699.

If NA is Avogadro’s number, then the number of valence electrons in 4.2 g of azide ions (N−3) are:

Answer»

If NA is Avogadro’s number, then the number of valence electrons in 4.2 g of azide ions (N3) are:

700.

A green ball weighs 75 g and comes travelling towards you at 400 cm/s. A photon of light emitted from green ball has a wavelength of 5×10−5 cm. Assuming that the error in the position of ball is the same as the wavelength of itself, calculate the error in the momentum of the green ball.

Answer»

A green ball weighs 75 g and comes travelling towards you at 400 cm/s. A photon of light emitted from green ball has a wavelength of 5×105 cm. Assuming that the error in the position of ball is the same as the wavelength of itself, calculate the error in the momentum of the green ball.