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301.

The pair in which both the complexes have the same magnetic moment (spin only value) is:

Answer»

The pair in which both the complexes have the same magnetic moment (spin only value) is:

302.

An example for a saturated fatty acid, present in nature is

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An example for a saturated fatty acid, present in nature is



303.

Which of these have inter-molecular hydrogen bond?

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Which of these have inter-molecular hydrogen bond?



304.

The electronic configuration of Ag atom is

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The electronic configuration of Ag atom is

305.

Which of the following is the strongest Bronsted acid?

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Which of the following is the strongest Bronsted acid?

306.

The first ionisation potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be

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The first ionisation potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be



307.

The enol from of acetone after treatment with D2O gives:

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The enol from of acetone after treatment with D2O gives:

308.

When mercury is heated with aqua regia then which compound is formed?

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When mercury is heated with aqua regia then which compound is formed?

309.

The raw material used in nylon-6 is

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The raw material used in nylon-6 is



310.

Redox reactions play a pivotal role in chemistry and biology. The values of standard redox potential (E⊖) of two half cell reactions decided which way the reaction is expected to proceed. A simple example is a Daniell cell in which zinc goes into solution and copper gets deposited. Given below are a set of half cell reactions (acidic medium) along with their E⊖ (V with respect to normal hydrogen electrode) values. Using this data, obtain correct explanations for the following questionI2+2e−→2I⊖; E⊖=0.54Cl2+2e−→2Cl⊖; E⊖=1.36Mn3++e−→Mn2+; E⊖=1.50Fe3++e−→Fe2+; E⊖=0.77O2+4H⨁+4e−→2H2O; E⊖=1.23While Fe3+ is stable, Mn3+ is not stable in acid solution because

Answer»



Redox reactions play a pivotal role in chemistry and biology. The values of standard redox potential (E) of two half cell reactions decided which way the reaction is expected to proceed. A simple example is a Daniell cell in which zinc goes into solution and copper gets deposited. Given below are a set of half cell reactions (acidic medium) along with their E (V with respect to normal hydrogen electrode) values. Using this data, obtain correct explanations for the following question

I2+2e2I; E=0.54

Cl2+2e2Cl; E=1.36

Mn3++eMn2+; E=1.50

Fe3++eFe2+; E=0.77

O2+4H+4e2H2O; E=1.23



While Fe3+ is stable, Mn3+ is not stable in acid solution because



311.

The empirical formula of a gaseous fluorocarbon is CF2. At a certian temperature and pressure, a 1 L volume hold 8.95 g of this fluorocarbon. Under the same conditions, 1 L volume holds only 1.70 g gaseous F2. Thus, fluorocarbon is_______.(F = 19)

Answer»

The empirical formula of a gaseous fluorocarbon is CF2. At a certian temperature and pressure, a 1 L volume hold 8.95 g of this fluorocarbon. Under the same conditions, 1 L volume holds only 1.70 g gaseous F2. Thus, fluorocarbon is_______.

(F = 19)

312.

If the E0cell for a given reaction has a negative value, which of the following gives the correct relationships for the values of ΔG0 and Keq ?

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If the E0cell for a given reaction has a negative value, which of the following gives the correct relationships for the values of ΔG0 and Keq ?

313.

Carbon forms a large number of compounds due to:

Answer»

Carbon forms a large number of compounds due to:



314.

0.622 g of a metal carbonate on heating gives 0.466 g of its oxide and some CO2. Calculate the equivalent weight of the metal.

Answer» 0.622 g of a metal carbonate on heating gives 0.466 g of its oxide and some CO2. Calculate the equivalent weight of the metal.
315.

Which of the reaction defines ΔH∘f

Answer» Which of the reaction defines ΔHf
316.

Two radioactive elements X and Y have decay constantsλ and 10λ respectively. If decay begins with the same number of atoms of them, the ratio of atoms of X to those of Y after time 19λ will be

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Two radioactive elements X and Y have decay constantsλ and 10λ respectively. If decay begins with the same number of atoms of them, the ratio of atoms of X to those of Y after time 19λ will be



317.

The ease of adsorption of the hydrated alkali metal ions on an ion-exchange resin follows the order:

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The ease of adsorption of the hydrated alkali metal ions on an ion-exchange resin follows the order:



318.

The IUPAC name of C6H5-CO-CH2-CH3

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The IUPAC name of C6H5-CO-CH2-CH3



319.

If the threshold wavelength (λ0) for ejection of electron from metal is 330 nm, then work function for the photoelectric emission is:(Planck's constant (h) = 6.6×10−34 J s)

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If the threshold wavelength (λ0) for ejection of electron from metal is 330 nm, then work function for the photoelectric emission is:

(Planck's constant (h) = 6.6×1034 J s)

320.

1 mole of an ideal gas is compressed isothermally and reversibly at 298 K from a pressure of 1 Pa. To do a work of 100J, to what final pressure should we compress it? (R = 8.314 J/K/mol)

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1 mole of an ideal gas is compressed isothermally and reversibly at 298 K from a pressure of 1 Pa. To do a work of 100J, to what final pressure should we compress it? (R = 8.314 J/K/mol)

321.

Which of the following is condensation reaction?

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Which of the following is condensation reaction?



322.

Which of the following phenols has the largest pKa value (i.e., least acidic)?

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Which of the following phenols has the largest pKa value (i.e., least acidic)?

323.

For 2SO2(g)+O2(g)→2SO3(g), ΔH is equal to:

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For 2SO2(g)+O2(g)2SO3(g), ΔH is equal to:

324.

Which of the following is the exact sawhorse projection representation for the following newman projection?

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Which of the following is the exact sawhorse projection representation for the following newman projection?




325.

We start with 2-cyclohexenone and subject it to (separate) reagents/reaction sequences A, B, C and D. Each of these correspondingly yields the products. From the options given, choose the correct ones that could be the reaction sequences

Answer»

We start with 2-cyclohexenone and subject it to (separate) reagents/reaction sequences A, B, C and D.

Each of these correspondingly yields the products.



From the options given, choose the correct ones that could be the reaction sequences



326.

Studies on the elevation in boiling point of Ca(NO3)2 gives its molar mass to be 131.2 g/mol. The degree of dissociation of Ca(NO3)2 is:

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Studies on the elevation in boiling point of Ca(NO3)2 gives its molar mass to be 131.2 g/mol. The degree of dissociation of Ca(NO3)2 is:

327.

Energy barrier between staggered and eclipsed conformation of ethane is?

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Energy barrier between staggered and eclipsed conformation of ethane is?



328.

Howmany space lattices are obtainable from the different crystal systems[MP PMT1996; MP PET/PMT 1998]

Answer»

How
many space lattices are obtainable from the different crystal systems

[MP PMT
1996; MP PET/PMT 1998]



329.

The order of reactivity of the following substrates in a nucleophilic addition reaction is:

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The order of reactivity of the following substrates in a nucleophilic addition reaction is:


330.

Which of the following is not correct about Molecular Orbital theory?

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Which of the following is not correct about Molecular Orbital theory?



331.

How many unbonded electrons are present on N in NO?

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How many unbonded electrons are present on N in NO?



332.

The compressibility factor of an ideal gas is equal to

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The compressibility factor of an ideal gas is equal to



333.

Which one of the following is not a surfactant

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Which one of the following is not a surfactant



334.

Predict the correct intermediate and product in the following reaction

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Predict the correct intermediate and product in the following reaction


335.

A golf ball has a mass of 40g and a speed of 45 ms−1. If the speed can be measured with an accuracy of 2%, calculate the uncertainty in the position.

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A golf ball has a mass of 40g and a speed of 45 ms1. If the speed can be measured with an accuracy of 2%, calculate the uncertainty in the position.



336.

Most commercial hydrochloric acid is prepared by heating NaCl with concentrated H2SO4. How much sulphuric acid containing 90.0% H2SO4by mass is needed for the production of 200 kg of conc. HCl containing 42.0% HCl by mass?

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Most commercial hydrochloric acid is prepared by heating NaCl with concentrated H2SO4. How much sulphuric acid containing 90.0% H2SO4by mass is needed for the production of 200 kg of conc. HCl containing 42.0% HCl by mass?



337.

Which of the following is not an example of cross-conjugation?

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Which of the following is not an example of cross-conjugation?

338.

Which type of phenomenon is used when coloured sugar solution is decolourized by charcoal?

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Which type of phenomenon is used when coloured sugar solution is decolourized by charcoal?



339.

Using Oxidation-number method, find the net ionic equation for the following reaction in basic medium: Mn(OH)2(s)+MnO−4(aq)→MnO2(s)

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Using Oxidation-number method, find the net ionic equation for the following reaction in basic medium:

Mn(OH)2(s)+MnO4(aq)MnO2(s)

340.

Which of the following statements is/are correct regarding A, B and C?

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Which of the following statements is/are correct regarding A, B and C?
341.

The correct order of bond angle of C−C−C in propane, propene and propyne are

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The correct order of bond angle of CCC in propane, propene and propyne are

342.

Which of the following is a correct statement?

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Which of the following is a correct statement?



343.

For the reaction : aA+bB→ Products, the rate law is given by Rate = k[A]m[B]n. On making the concentration of A two-fold and halving that of B, the ratio of the new rate to the earlier rate of the reaction would be:

Answer»

For the reaction : aA+bB Products, the rate law is given by Rate = k[A]m[B]n. On making the concentration of A two-fold and halving that of B, the ratio of the new rate to the earlier rate of the reaction would be:



344.

PbO2 is

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PbO2 is




345.

The sum of molar masses of the products A, B, C and D is

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The sum of molar masses of the products A, B, C and D is







346.

Select the appropriate option.

Answer»

Select the appropriate option.





347.

Which is the most common oxidation state of lanthanides and actinide series?

Answer» Which is the most common oxidation state of lanthanides and actinide series?
348.

Of the following, which compound is an acetal?

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Of the following, which compound is an acetal?

349.

The reaction of phenol with chloroform in presence of dilute sodium hydroxide finally introduces which one of the following functional groups?

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The reaction of phenol with chloroform in presence of dilute sodium hydroxide finally introduces which one of the following functional groups?

350.

In Sodium atom, the screening of 3s electron is due to:

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In Sodium atom, the screening of 3s electron is due to: