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6101.

What is the amount of PCl_5 (in mole) need to be aded to one litre vesselat 250^Oc in order to obtain a concentration of 0.1 moles of Cl2​ ?Kc​for PCl5​ ⟺PCl3​ +Cl2​is 0.0414 mol/litre

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0.3415
0.0341
3.415
0.3415

Answer :A
6102.

The specific conductivity of N/10 KCl solution at 20^(@)C is 0.0212 ohm^(-1) cm^(-1) and the resistance of the cell containing this solution at 20^(@)C is 55 ohm. The cell constant is :

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`"(a) 3.324 CM"^(-1)`
`"(B) 1.166 cm"^(-1)`
`"(c) 2.372 cm"^(-1)`
`"(d) 3.682 cm"^(-1)`

Solution :`K=Cxx1/A`
`1/A=Kxx1/C=KxxR`=0.0212 X 55 =`1.166 cm^(-1)`
6103.

When calcium formate is distilled with calcium acetate , the product is :

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ACETIC acid
Acetaldehyde
acetone
ethane.

Solution :
6104.

When the hybiridization state of the carbon atom changes as follows: sp^(3) to sp^(2) to so, the angle between thehybridized orbitals.

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decreases gradually
decreases considerably
is not AFFECTED
INCEASES PROGRESSIVELY.

SOLUTION :
6105.

Tin (IV) chloride is

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a covalent COMPUND
a voatile liquid at room temperature
a covalent compound
TETRAHEDRAL in shape

Solution :All OPTION are correct.
6106.

Which is used as a preservative for biological specimens ?

Answer»

Formalin
Formic acid
LIQUID `NH_(3)`
`ACETIC acid

SOLUTION :Formalin used as a preservative for biogical specimens.
6107.

Which of the following pairs of compounds are enantiomers

Answer»




SOLUTION :STRUCTURES are not MIRROR of each other which are NON superimposableso they are ENANTIOMERS.
6108.

Write the chemical tests to distinguish between Acetaldehyde and formaldehyde.

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Solution :ADD fehling's solution to each of them separately. Acetaldehyde will give yellow PRECIPITATE of iodoform where benzaldehyde will not REACT.
6109.

What is the role of SiO_(2) in the extration of copper?

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SOLUTION :The copper ore is heated in a REVERBERATORY furnace after mixing with SILICA. IRON oxide forms a slag of `FeSiO_(3)" with "SiO_(2)`
`{:(FeO + SiO_(2) to FeSiO_(3)), ("Slag"):}`
The slag is removed and copper matte is then charged into the silica line converter.
6110.

The solubility of an aqueous solution of Mg(OH)_(2) be x then its K_(sp) is ………………………

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`4x^(3)`
`108X^(5)`
`27x^(4)`
9x

Solution :`Mg(OH)_(2) harr underset(x)(Mg)^(2+)+ underset((2X)^(2))(2OH)^(-)`
`K_(SP) = 4x^(3)`
6111.

Thermal stabilities of the halogen fluorides are

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 `BrF_(3)gtCIF_(3)`
 `CIF_(3)gtBIF_(3)`
 `CIF_(3)=BIF_(3)`
NONE of the above

Answer :B
6112.

Which of the following statements is / are correct

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In GAS phase the basic strength order among the three types of AMINES is `3^(0)gt2^(0)gt1^(0)`.
Among the isomeric amines BOILING points order is `3^(0)gt2^(0)gt1^(0)`
Alcohols are more water soluble than amines (of comparable molecular weight)
The C-N bond in Aromatic amines is shorter than that of in aliphatic amincs

Solution :Gas phase
Amines Basicity :- `3^(@)gt 2^(@)gt1^(@)`
Amines B.Pt :- `1^(@)gt 2^(@)gt 3^(@)` no of H-bonds
ALCHOLS form STRONG H-bond with water than amines
Due to resonance aromatic amines have lass C-N bond bength
6113.

Which of the following does not determine the translational kinetic energy of an ideal gas ?

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Temperature
Amount of the gas
Number of MOLES of gas
Pressure of the gas

Answer :D
6114.

Which of the following process is for purification of metals?

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LEACHING 
WASHING 
Liquidation 
FROATH floatation 

Answer :C
6115.

What modification can you suggest for Hardy-Schulze law?

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Answer :According to Hardy-Schulze law, ions carrying, charge opposite to that on colloidal particles CAUSE COAGULATION of the sol. This is because of NEUTRALISATION of charge on colloidal particles.
The law can be modified to add the following. If oppositely CHARGED sols are mixed in suitable proportions to neutralise the CHARGES of each other, coagulation of both sols takes place.
6116.

What is the coordination number of B_(2)0_(3) ?

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4
6
8
3

Answer :D
6117.

Write the structure of the following species :

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SOLUTION :
6118.

Which of the following contain S - O linkage

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`H_2S_2O_7`
`H_2S_2O_8`
`H_2S_2O_6`
`H_2S_2O_5`

ANSWER :A
6119.

Which of the following reactions takes place when a mixture of concentrated HNO_3 and H_2SO_4 reacts on benzene at 350 K

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SULPHONATION
NITRATION
Hydrogenation
Dehydration

Solution :
6120.

Which is not a green house gas ?

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`CO_2`
`CH_4`
`N_2O`
NONE of these

Answer :C
6121.

Which of the following diazonium salt is most stable?

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p-Nitrobenzenediazonium chloride
2,4-Dinitrobenzenediazonium chloride
2,4,6-Trinitrobenzenediazonium chloride
p-Methoxybenzenediazonium chloride.

Solution :ELECTRON DONATING groups increase the STABILITY of diazonium cations by dispersing the +ve CHARGE on the N-atom.
6122.

Which of the following maintains constant sugar level in blood ?

Answer»

Gibberlins
Insulin
Glucogen
Estrone

Answer :B
6123.

What are local anaesthetics? Give example. Mention its uses.

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Solution :(i) Local anaesthetics cause LOSS of sensation in the area in which it is applied without LOSING consciousness. They block pain perception that is transmitted VIA peripheral nerve fibre to the brain. e.g., procaine, lidocaine.
(ii) They are often used during MINOR SURGICAL procedures.
6124.

Vegetable oils are

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THERMAL insulator
an ABSORBER of minerals
catalyst
Enzymes

Answer :A
6125.

Which of the following characteristics apply both to ethene and ethyne -

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Form white PRECIPITATE with `AgNO_(3)` solution
Explode when mixed with chlorine
Decolourise Baeyer’s reagent giving BROWN precipitate
Rapidly absorbed by COLD conc. `H_(2)SO_(4)`

Answer :C
6126.

The volumes of gases H_(2), CH_(4), CO_(2) and NH_(3), adsorbed by 1 g charocal at 298 K are in the order .

Answer»

`H_(2) GT CH_(4) gt CO_(2) gt NH_(3)`
`CH_(4) gt CO_(2) gt NH_(3) gt H_(2)`
`CO_(2)gtCO_(2) gtH_(2) gt CH_(4)`
`NH_(3) gt CO_(2) gt CH_(4) gt H_(2)`

Solution :Greater the critical temperature of a gas, greater is the ADSORPTION. Critical temperatures of the given GASES are as follows: `NH_(3) (406 K), CO_(2) (304 K), CH_(4) (190 K) and H_(2) (33 K)`. Thus adsorption decreases from `NH_(3)` to `H_(2)` in this order.
6127.

Which is not the disproportionation reaction?

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`3H_(3)PO_(2) to 3H_(3)PO_(3)+PH_(3)`
`HCHO+OH^(-) to HCOO^(-)+CH_(3)OH`
`NH_(4)NO_(3)toN_(2)O+2H_(2)O`
`Cl_(2)+6OH^(-)to5Cl^(-)+ClO_(3)^(-)+3H_(2)O`

ANSWER :C
6128.

The reducing power of divalent species decreases in the order :

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`GegtSngtPb`
`SngtGegtPb`
`PbgtSngtGe`
NONE of these

Answer :A
6129.

What role does the molecular interaction play in solution containing chloroform and acetone ?

Answer»

SOLUTION :H-bonding formed, results in negative DEVIATION from Raoult’s LAW.
6130.

Using the data (all values and in kcal/mol at 25^(@) C) given below: DeltaH_(l)^(@) CO_(2)(g) = -94.05 DeltaH_(t)^(@) CO(g) = -26.41 DeltaH_(l)^(@)H_(2)O(l) = -68.32 DeltaH_(l)^(@)H_(2)O(g) = -57.79 DeltaH_("combustion")^(@) (C_(6)H_(16)) = -1302.7 Mean molar heat capacities C_(p) (cal/mol) at 25^(@) C. CO(g) = 6.97 H_(2)O(g) = 5.92 CO_(2)(g) = 8.96 Calculate the no. of moles of CO and CO_(2) produced, when 0.1 mol of C_(8)H_(18) at 25^(@) C is completely burned at constant pressure in some oxygen gas at 25^(@) C yielding as products gaseous H_(2)O, CO and CO_(2) at 300^(@) C, the process yielded 90.20 kcal of heat to the surroundings.

Answer»

Solution :`C_(8)H_(18) + 25/2 O_(2)(g) to 8CO_(2)(g) + 9H_(2)O(L)`
`DeltaH^(@) = 8DeltaH_(l)^(@) CO_(2)(g) + 9DeltaH_(l)^(@) H_(2)O(l) -DeltaH_(l)^(@)(C_(8)H_(18))`
`DeltaH_(l)^(@)(C_(6)H_(18)) = -64.6` kcal
REACTIONS under consideration re
`C_(8)H_(18) + 25/2 O_(2)(g) to 8CO_(2)(g) + 9H_(2)O(g).DeltaH_(2)`
`DeltaH_(1) = 8(-94.05) + 9(-57.79) -(-64.6) = -1207.9` kcal/mol.
`DeltaH_(2) =8(-26.41) + 9(-57.79) -(-64.6) = -666.8` k cal/mol
Let moles of CO PRODUCED =X
`therefore` moles of `CO_(2)` produced = `0.8 -x`
`(666.8 x)/8 + (0.8 -x)/8 1207.9 = 120.79-67.64`x.
Heat utilized (in kcal):
`90.20 + 275 [x(6.97) + (0.8 -x)8.96 + (0.9)(5.92)] xx 10^(-3)`
`=93.64 - 0.547`
Heat utilized = Heat generated
`120.79 - 67.64 x = 93.64 - 0.547`x
`x=0.405` mol CO
`0.8-x =0.395` mol `CO_(2)`
6131.

What type of analgetics are chiefly used for the relief of pains of terminal cancer ?

Answer»

SOLUTION :Narcotic analgesics like MORPHINE and its homologues in medicinal DOSES are used for the RELIEF of pains of terminal CANCER.
6132.

Which polymer is not obtained by addition polymerization ?

Answer»

POLYSTYRENE
NYLON
Polypropene
PVC

Solution :Nylon
6133.

Write the formula of the following coordination compound Mercury(I) tetrathiocyanatocobaltate (III).

Answer»

SOLUTION :`HG[CO(SCN)_4]`.
6134.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggested about the structure of RNA ?

Answer»

Solution :Since DNA has double stranded STRUCTURE with specific base pairing, there is some relationship between the BASES. For EXAMPLE, the number of moles of adeninewill be EQUAL to THYMINE and the number of moles of guanine will be equal to cytosine
6135.

Which of the following sulphateisinsolublein H_(2)O

Answer»

`CuSO_(4)`
`PbSO_(4)`
`CdSO_(4)`
`Bi(SO_(4))_(3)`

ANSWER :b
6136.

Which of the following cannot be hydrolysed

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A SALT of weak ACID and strong BASE
A salt of strong acid and weak base
A salt of weak acid and weak base
A salt of strong acid and strong base

Solution :A salt of strong acid and strong base cannot be hydrolysed. In this case the equilibrium cannot SHIFTED towards the backward.
6137.

Which of the following is correct order of acid strength among I(CO_2), II(SiO_2), III(SO_3), IV(N_2O_5)

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`II ltI LT IV lt III`
`I lt II lt III lt IV`
`III ltII lt IV lt I`
`IIlt IIIlt II lt I`

Solution :Correct ORDER of ACIDIC strength:
`SiO_2 ltCO_2 lt N_2O_5lt SO_3`.
6138.

What are lyophilic and lyophobic sols? Give one example of each type. Why are hydrophobic sols easily coagulated?

Answer»

Solution :Lyophilic SOLS: Colloidal sols directly formed by mixing SUBSTANCES LIKE gums, GELATIN, starch, rubber, etc. with a SUITABLE liquid (The dispersion medium) are lyophilic sols. An important characteristic of these sols is that if the dispersion medium is separated from the dispersed phase (say by evaporation) the sol can be reconstituted by simply remixing with the dispersion medium. That is why these sols are also called reversible sols. These sols are quite stable and cannot be easily coagulated.
Lyophobic sols: These colloidal sols can only be prepared by some special methods. These sols are readily precipitated on the addition of small amount of electrolytes, by heating or by shaking and hence are not stable.
Hydrophobic sols are water hating. They are formed by indirect method. These sols are irreversible sols. These sols are readily precipitated by the addition of small amount of electrolytes, by heating or by shaking and hence are not stable.
6139.

Which of the following is produced during condensation polymerization ?

Answer»

WATER
Alcohol
Ammonia
All of these

SOLUTION :All of these
6140.

Which of the following statements is not correct regarding the adsorption of a gas on the surface of a solid?

Answer»

On increasing temperature, adsorption INCREASES CONTINUOUSLY.
Enthalpy and entropy change is negative
Adsorption is more for some specific substances.
It is a reversible reaction

Solution :Adsorption is the ability of a substance to concentrate or hold gases, LIQUIDS or dissolved substances upon its surface. Solids adsorb greater amounts of substances at LOWER temperature. In general, adsorption decreases with increase in temperature.
6141.

Transition metals in which vacent spaces are occupied by small atoms such as hydrogen, carbon etc. arecalled "….................."

Answer»


ANSWER :INTERSTITIAL COMPOUNDS
6142.

Which of the following statements are true about the addition polymerization?

Answer»

Addition POLYMERIZATION occurs between molecules containing double or triple bond.
It takes place in the presence of organic peroxides.
It proceeds via ionic MECHANISM in the presence of organic peroxides.
Polythene and polystyrene are addition polymers.

Solution :Addition reactions (electrophilic or FREE RADICAL) are common for the alkenes and alkynes which are initiated by ions or free radical INITIATORS `(R_2O_2)`
6143.

Which of the following polymer is not synthesized from acidic monomer ?

Answer»

NYLON - 6, 6
Dacron
Bakelite
TEFLON

ANSWER :D
6144.

Which of the following is incorrect with respect to property indicated ?

Answer»

`E.N:FgtClgtBr`
`E.A:ClgtBrltF`
OXIDISING power : `F_(2)gtCl_(2)gtBr_(2)`
Bond ENERGY : `F_(2)gtCl_(2)gtBr_(2)`.

Answer :D
6145.

The wrong statement is

Answer»

heat of NEUTRALISATION is ALWAYS negative
resonance energy is always negative
heat of ATOMISATION is always positive
heat of combustion is always negative

Answer :D
6146.

Which of the following is an example of freon ?

Answer»

`BrCH_2CH_2Cl`
`"CC"l_2F_2`
`"CC"l_2Br_2`
`ICH_2CH_2F`

ANSWER :B
6147.

The value of van der Waals constant 'a' is makimum for

Answer»

Helium
Nitrogen
`CH_(4)`
`NH_(3)`

ANSWER :D
6148.

What is the product of this sequence of reactions ?

Answer»




ANSWER :B
6149.

Why are all aqueous solution of the cobaltous salts pink?

Answer»

Solution :All AQUEOUS solution of cobaltous salts are pink due to the formatiion of `[CO(H_(2)O)_(6)]^(2+)` ions.
6150.

The synthetic polymer which resembles natural rubber is

Answer»

NEOPRENE
PMMA
GLYPTAL
Nylon

Answer :A