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91451.

(A) Ammonia is least volatile among MH_(3) type hydrides of group VA elements. (R ) Molecules of ammonia are held together by strong electrostatic forces

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Both (A) and (R ) are TRUE and (R ) is the CORRECT explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

Answer :4
91452.

(A) Among 15^(th) group elements nitrogen has the least B.P where as Bi has the high B.P than N. (R ) Nitrogen is a non metal where as Bi is a metal

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Both (A) and (R ) are TRUE and (R ) is the CORRECT explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

ANSWER :2
91453.

(A) Ammonia can be dried over conc. H_(2)SO_(4) (R ) Conc. H_(2)SO_(4) has more affinity to waterthan to ammonia

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Both (A) and (R ) are true and (R ) is the correct EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

Answer :4
91454.

Aamineproduces yellowoilycompoundon reactionwithnitrousacid . It isprobably a

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Primaryamine
Secondaryamine
TERTIARYAMINE
Quarternarysalt

ANSWER :B
91455.

(A) Aluminium metal is used as a reducing agentin thermite welding (R) Al has a lower meltingpoint than Fe, Cr and Mn.

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Both (A) and (R) are TRUE and (R) is the CORRECT explanation of (A)
Both (A) and (R) are true and (R) is not the correct explanationof (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :B
91456.

A: Aluminium metal is used as a reducing agent for the extraction of metals R: Aluminium has great affinity for oxygen

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If both Assertion & Reason are true and the reason is the CORRECT EXPLANATION of the assertion, then mark (1).
If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)
If Assertion is true statement but Reason is false, then mark
 If both Assertion and Reason are false STATEMENTS, then mark (4)

Answer :A
91457.

(A) Aluminium metal can be extracted by the electrolysis of aqueous aluminium fluoride (R) The reduction potentialof standard aluminium electrode is positive

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct EXPLANATIONOF (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :D
91458.

(A) Alumina is leached from bauxite using caustic soda (R) Leaching is used when ore alone, but not gangue is soluble in a suitablesolvent.

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct EXPLANATIONOF (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :C
91459.

Find out the correct statement from the following: (a) Alum is potassium aluminium sulphate (b) Alum is extrated form colemanite ( c ) Anhydrous aluminium chloride a catalyst in Friedels crafts reactions. (d) It’s a Lewis acid

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ANSWER :B
91460.

(A) : PF_(5),PCl_(5) and PBr_(3) are known, the pentahalides of nitrogen have not been observed (R ) Phosphorous has lower electronegativity than nitrogen.

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Both (A) and (R ) are true and (R ) is the CORRECT explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

ANSWER :2
91461.

(A) Although fluorine is more electronegative than chlorine, yet p-fluorobenzoic acid is a weaker acid than p-chlorobenzoic acid. (R) Due to matching sizes of 2p orbitals of F and carbon, F has a stronger +R effect than Cl.

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Both (A) and (R) are true and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :A
91462.

(A) Although fluorine is more electronega-tiye than oxygen, but the ability of oxygen to stabilise the higher oxidation states with d- block metal is more. (R) Oxygen has ability to form multiple bonds to metals

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is FALSE
Both (A) and (R) are false

Solution :Both (A) and (R) are true and (R) is the correct explanation of (A)
91463.

(A) alpha-Hydrogen atoms in aldehdes and ketones are acidic. (R) The anion left after the removal of alpha-hydrogen from carbonly compounds is stabilized by the electron withdrawing carbonyl group.

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Both (A) and (R) are TRUE and (R) is the CORRECT explanation of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) is false

Answer :C
91464.

(A) All types of magnetic solids become paramagnetic at elevated temperatures. (R) Magnetic solids on heating attains randomisation of spins

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Both (A) and (R) are true and (R) is the CORRECT explanation of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :A
91465.

A : All the oxides of boron family with the general formula M_(2) O_(3) are basic . R : From B_(2) O_(3) to Tl_(2) O_(3) basic character decreases .

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If both Assertion & REASON are true and the reason is the correct explanation of the assertion , then mark (1)
If both Assertion & Reason are true but the reason is not the correct explanation of the assertion , then mark (2)
If Assertion is true statement but Reason is false , then mark (3)
If both Assertion and Reason are false STATEMENTS , then mark (4)

Answer :D
91466.

(A) All the noble gases have ns^2 np^6 electronic configuration in their outermost shell(R) In noble gases all the energy levels are completely filled.

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Both (A) and (R) are TRUE and (R) is the correct explanation of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :D
91467.

(A) All the hydrogen atoms in but-2-ene lie in one plane. (R) All the carbon atoms in it are sp^(2)-hybridized.

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ANSWER :D
91468.

(A): All square planar complexes can exhibit geometrical isomerism (R): In square planar complexes metal generally assumes dsp^2 hybrid state.

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Both A & R are true, R is the CORRECT explanation of A
Both A & R are true, R is not correct explanation of A
A is true, R is false
A is false, R is true

Answer :D
91469.

(A) All noble gases occur in atmosphere(R) Among noble gases 'R' is radioactive element

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Both (A) and (R) are true and (R) is the correct explanation of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :B
91470.

(A): All noble gases are monoatomic (R): Noble gas atom is stable and does not dimerise or polymerise

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Both (A) and (R) are true and (R) is the correct EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :A
91471.

(A) All instantaneous reactions are spontaneous (R ) Spontaneous recations get completed in a fraction of minute

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Both (A) and (R ) are true and (R ) is the CORRECT explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

Answer :C
91472.

(A): All hormones are proteins (R): All hormone receptors are proteins

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Both A & R are true, R is the CORRECT EXPLANATION of A
Both A & R are true, R is not correct explanation of A . 
A is true, R is false
A is false, R is true

Answer :D
91473.

(A) All Ionic reactions are Instantaneous (R ) Ionic reactions do not involve bond rearrangements

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Both (A) and (R ) are TRUE and (R ) is the correct EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

Answer :A
91474.

(A): All DNA and RNA molecules contain adenine, guanine and cytosine base molecules (R): Adenine, guanine and cytosine molecules are examples of the same base type

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Both A & R are true, R is the CORRECT EXPLANATION of A
Both A & R are true, R is not correct explanation of A
A is true, R is false
A is false, R is true

Answer :C
91475.

A : All crystals of same substance possess the same elements of symmetry.R : The size of crystal of same substance may vary depending upon the conditions of crystallisation.

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If both Assertion & REASON are true and the reason is the CORRECT explanation of the assertion then mark (1)
If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)
If Assertion is true statement but Reason is false then mark (3)
If both Assertion and Reason are false statements, then mark (4)

ANSWER :B
91476.

(A) All covalent solids are non conductors(R) Graphite is a ionic solid

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Both (A) and (R) are true and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :D
91477.

A: All Cr-o bond length in K_(2)Cr_(2)O_(7) are equalR: Both the Cr are present in dsp^(2) hybrid state

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If both Assertion & REASON are true and the reason is the CORRECT explanation of the assertion, then mark (1)
If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)
If Assertion is true statement but Reason is false, then mark (3)
If both Assertion and Reason are false statements, then mark (4)

Answer :D
91478.

(A) All compounds having C=C bond exhibit geometrical isomerism. (R) Rotation about C=C bond is restricted.

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ANSWER :D
91479.

(A) All collisions lead to chemical reaction (R ) All molecules bring about effective collisions

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Both (A) and (R ) are TRUE and (R ) is the correct explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

Answer :D
91480.

(A): Alkyl halides on reaction with KCN, the major product is nitrile, but with AgCN, the major product is isonitrile. (R): Mainly KCN is more ionic, but AgCN is more covalent than KCN.

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Both A & R are true, R is the correct EXPLANATION of A
Both A & R are true, R is not correct explanation of A
A is true, R is false
A is false, R is true

Answer :A
91481.

A alkene that provides only Butanone -2 on ozonolysis is

Answer»

3, 4-dimethylhex-3-ene
2,3-dimethylhex-2-ene
3-methylhex-3-ene
2,3-dimethylpent-2-ene

Answer :A
91482.

(A) Alkanes containing more than three carbons exhibit chain isomerism. (R) All the carbon atoms in alkanes are sp^(3)-hybridized.

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ANSWER :C
91483.

(A) Alkaline hydrolysis of ethyl acetate follows first order kinetic (R ) Rate= K [ester] for saponification reactions

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Both (A) and (R ) are true and (R ) is the CORRECT EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is false
Both (A) and (R ) are false

Answer :D
91484.

(A) Alkanes can have an infinite number of conformations. (R) In configurational isomerism, the isomers are distinct individual substances.

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ANSWER :B
91485.

(A) Aldehydes on reaction with hydroyxl amine to form aldoximes. (R) Aldoximes exhibit geometrical isomerism.

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Both (A) and (R) are TRUE and (R) is the correct explanation of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) is false

Answer :B
91486.

(A) Aldol condensation of acetone can be catalysed both by acid (or) base. (R) beta-Hydroxyaldehyde readily undergo acid-catalysed dehydration.

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) is false

Answer :B
91487.

(A) Aldehydes are reduced to alkanes in the presence of Zn/Hg and Conc. HCl. (R) In Wolff-Kishner reduction reagent used is NH_(2)NH_(2) and KOH in glycol.

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Both (A) and (R) are true and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) is false

Answer :B
91488.

(A) Aldehydes & ketones on shaking with a saturated solution of NaHSO_(3) gives solid derivative of sodium bisulphite compounds. (R) Carbonyl compounds on heating with NaCN gives cyanohydrins.

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) is false

Answer :B
91489.

(A): Alcohols on dehydration can produce ether as well as alkene under different conditions. (R): Dehydration of alcohol takes place with conc. H_(2)SO_(4) or Al_(2)O_(3).

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Both A & Rare true, R is the CORRECT explanation of A
Both A & Rare true, R is not correct explanation of A
A is true, R is FALSE
A is false, R is true

Answer :B
91490.

(A) Alcohols can act as nucleophiles(R) Alcohols form salts with alkali metals

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Both (A) and (R) are true and (R) is the CORRECT explanation of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is FALSE
Both (A) and (R) are false

Answer :B
91491.

(A) Alcohols can be dried over anhydrous CaCl_(2) (R ) Anhydrous CaCl_(2) absorbs moisture of aqueous ethyl alcohol.

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If both (A) and (R ) are CORRECT and (R ) is correct EXPLANATION of (A ).
If both (A ) and (R ) are correct but (R ) is not correct explanation of (A ).
If (A) is correct but (R ) is INCORRECT
If (A) is incorrect but (R ) is correct.

ANSWER :D
91492.

(A) Alcohols are acidic in nature but donot react with NaOH solution(R) Alkoxide is stronger base than hydroxide ion

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Both (A) and (R) are true and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :A
91493.

(A) Alcohols act as Bronsted - Lowry bases.(R) In alcohols the lone pair of electrons on oxygen forms dative bond by accepting a proton

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is false
Both (A) and (R) are false

Answer :A
91494.

What is addition polymerization? Give one example for a copolymer.

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Solution :POLYMERIZATION during which large NUMBER of same (or) DIFFERENT monomers contains one or more double BONDS add together to give a polymer is called addition polymerization.
Example for co polymer is Buna-s
It is addition polymerization in which the polymer is made up of large number of two different monomer UNITS
Eg :- Buna-s it is prepared by the co-polymersiation of 1,3 - butadiene and styrene
91495.

(A): Alcoholic fermentation involves conversion of sugar into ethanol by the action of yeast. (R): Fermentation involves the liberation of CO_(2) gas.

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Both A & RARE TRUE, R is the CORRECT EXPLANATION of A
Both A & Rare true, R is not correct explanation of A
A is true, R is false
A is false, R is true

Answer :B
91496.

(a) Al_(2)O_(3) is treated with Co(NO_(3))_(2) (b) Ammonium alum is heated (c) Metastannic acid is heated (d) SnCls is treated with Sn (e) Nitrous oxide (N_(2)O) is treated with sodamide.

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SOLUTION :(a) ` 2Co(NO_(3))_(2) RARR 2CoO 4NO_(2) +O_(2)`
CoO + `Al_(2)O_(3) rarr CoAl_(2)O_(4)`
(B) ` (NH_(4))SO_(4)Al(SO_(4))_(3) .24H_(2)O rarr (NH_(4))HSO_(4) + Al_(2)(SO_(4))_(3) + 24H_(2)O`
(C) ` H_(2)Sn_(5)O_(4)4H_(2)O rarr 5SnO_(2) + 5H_(2)O`
(d) `SnCl_(4) + Sn rarr 2SnCl_(2)`
` N_(2)O + NaNH_(2) rarr NaN_(3) + NH_(3) + NaOH` sodium azide is formed.
91497.

A : Al forms [AIF_6]^(3-) but B does not form [BF_6]^(3-) R : B does not react with fluorine.

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a
B
c
d

Solution :B does not have VACANT d-orbitals (sub-SHELL) as its VALENCE shell.
91498.

A: AI_(2)(CH_(3))_(6) is a dimeric compound and has Similar structure to diborane. R: AI_(2)(CH_(3))_(6) in a sigma bonded complex

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 If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1
 If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2). 
) If Assertion is true STATEMENT but Reason is false, then mark (3).
 If both Assertion and Reason are false statements, then mark (4)

Answer :B
91499.

(a) Adsorption of a gas on the surface of solid is generally accompanied by a decrease in entropy. Still it is a spontaneous process. Explain. (b) How does an increase in temperature affect both physical as well as chemical adsorption?

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SOLUTION : (a) ACCORDING to the equation `DELTAG=DeltaH_T DeltaS `
For a process to be spontaneous, `DeltaG` should be negative.` DELTAH` of adsorption is always negative. For a gas, `DeltaS` is also negative. Thus, in an adsorption process, which is spontaneous, a combination of these two factors always makes `DeltaG` negative.
(b) On increasing the temperature desorption occurs in case of physical adsorption. CHEMICAL adsorption first increases and then decreases with increase in temperature.
91500.

(A) Adsorption is endothermic (R ) Adsorption process is accormpanied by increase in randomness

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Both (A) and (R ) are true and (R ) is the correct EXPLANATION of (A)
Both (A)and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

ANSWER :D