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93801.

................. inhibits bacterial enzyme DNA gyrase.

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SOLUTION :FLUOROQUINOLONES
93802.

, Instant turbidity Identyfy X :

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`CH_(3)-overset(CH_(3))overset(|)(CH)-UNDERSET(OH)underset(|)(CH)-CH_(3)`
`CH_(3)-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-CH_(2)-CH_(3)`
`CH_(3)-overset(CH_(3))overset(|)(CH)-CH_(2)-CH_(2)-OH`
`CH_(3)-overset(OH)overset(|)(CH)-CH_(2)-CH_(2)-OH`

Solution :`3^(@)` alcohol GIVES INSTANT TURBIDITY with lucas reagent.
93803.

............... inhibits bacterial cell wall biosynthesis.

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SOLUTION :ANTIMICROBIALS
93804.

In aqueous solution, basic character of methylamines follows the order, 1°>2°>3°

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ANSWER :F
93805.

In anhydrous state, basic character of ethylamines follows the order , 3°>2°>1°

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ANSWER :T
93806.

In a buffer solution of weak acid and its salt, when the concentration of salt to acid is increased by 10 times, the pH of the solution,

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 INCREASES by one
decreases by one
decreases TEN FOLD
 increases ten fold.

SOLUTION :`pH_(1)=(1)/(log[H^(+)]^(+))`,`pH_(2)=(1)/(log[10H^(+)])`
`(pH_(1))/(pH_(2))=(1//log[H^(+)])/(1//log[10H^(+)])=(log10+log[H^(+)])/(log[H^(+)])`
=`(1+log[H^(+)])/(log[H^(+)])`
pH of the solution increases by one factor.
93807.

. Identify X,A,Y,Z.

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A-methoxymethane, X-ehtanol,Y-ethanoic ACID, Z-semicarbazide
A-ethanol, X-ethano,Y-but -z-enal, Z-semicarbazone.
A-ehtanol,X-Acetaldehyde, Y-Butanone, Z-Hydroazone
A-Methoxymethane, X-ethanoicacid, Y-acetate ION and Z-Hydrazine.

ANSWER :B
93808.

. Identify the reactant

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`H_(2)O`
HCHO
CO
`CH_(3)CHO`.

SOLUTION :Like `C_(6)H_(5)CHO,(CH_(3))_(3)"CC"HO` has m `alpha`-HYDROGEN which is a condition for this type of reaction (i.e., CANNIZZARO's reaction).
93809.

+I effect is shown by

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`-CH_(3)`<BR>`-Br`
`-CI`
`-NO_(2)`

Solution :`-Br, -CI, -NO_(2)` show (-I) EFFECT as all are electron attracting or withdrawing.
`+I` effect is shown by `-CH_(3)` group only.This is electron releasing or repelling group.
93810.

____ helps to maintain pH of blood between 7.26 to 7.42

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`CO_(2)`
`H_(2)CO_(3)`
`CO_(3)^(20-)`
`H_(2)CO_(3) or HCO_(3)^(-)`

Solution :`H_(2)CO_(3) or HCO_(3)^(-)` BUFFER system help to maintain PH of blood between 7.26 to 7.42
93811.

………….+HCl to NaCl + H_(2)O + CO_(2)

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`NaHCO_(3)`
NACL
`NaSO_(4)`
NaOH

Answer :A
93812.

"______" has thehighestelectricsconductivityat roommtemperature .

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CHROMIUM
COPPER
Silver
CADMIUM

Answer :C
93813.

............ has a half life 2.5 hours within the body.

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SOLUTION :PARACETAMOL
93814.

........... gases like H_(2), N_(2), O_(2)have low critical temperature and ........... slowly

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SOLUTION :PERMANENT , adsorbed
93815.

.......... gas is obtained on reaction of ammonium sulphate with caustic soda ?

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`H_(2)`
`Cl_(2)`
`O_(2)`
`NH_(3)`

Solution :`(NH_(4))_(2)SO_(4) + 2NAOH(aq) to 2NH_(3) + 2H_(2)O + Na_(2)SO_(4)`
93816.

_______ enzyme hydrolyses starch into maltose.

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pepsin
diastase
zymase
urease

Answer :B
93817.

………………… dye is formed when phenol couples with benzene diazonium chloride in an alkaline solution.

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SOLUTION :P-hydroxy AZO BENZENE (or) Red orange DYE
93818.

.................... donot become soft on heating but set to an infusible mass upon heating.

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SOLUTION :THERMOSETTING
93819.

................. do not form oxo cations.

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SOLUTION : LANTHANOIDS
93820.

_____ distinguishes between acetaldehyde and acetone.

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SOLUTION :Tollen.s REAGENT
93821.

……………….. Dilates blood vessels.

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ANSWER :HISTAMINE
93822.

-(d[H_2O_2])/(dt) represented

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rate of formation of `H_2O_2`
rate of decompotion of `H_2O_2`
order of reaction
none

Solution :CHANGE in conc. W.r.t. REACTANT is indicated by -ve SIGN.
93823.

........... destroys the activity of platinum in contact process

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SOLUTION :`AS_2O_3` CATALYST POISON
93824.

…………………..defect arises due to the missing of equal number of cations and anions from the crystal lattice.

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SOLUTION :SCHOTTKY
93825.

, 'D' is

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o-bromo benzoic ACID
phenyl acetic acid
p-bromo benoic acid
m-bromo benzoic acid

Solution :N-Bromo SUCCINIMIDE (NBS) HELPS in BENZYLIC bromination.
93826.

………………….. Crystal to act as a molecular sieve.

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ANSWER :ZEOLITE
93827.

-COOH is ________ directing group.

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ORTHO
meta
para
both ortho and para

Answer :B
93828.

-COOH is a /an ………….group but COO^- is a /an …………..group.

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ANSWER :DEACTIVATING ACTIVATING
93829.

(-COOH) group of a compound does not react with NaHSO_3 even though it has >C=O group because of:

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ACID CHARACTER
Resonance
Cyclic structure
The ATTACHED ORGANIC group.

Answer :B
93830.

-COOH group is obtained by acid hydrolysis of

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`-CHO`
`-C EQUIV N`
`-CH_(2)-OH`
`-overset(overset(O)(abs()))(C)-`

ANSWER :B
93831.

- COOH group of a compound does not react with NaHSO_(3) even though it has gt C = O group because of

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CYCLIC STRUCTURE
acidic character
linear structure
resonance

Answer :D
93832.

-COOH group can be converted to -NH_(2) group by :

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Claisen condensation
Schmidt reaction
Perkin 's reaction
Cannizzaro 's reaction.

Answer :B
93833.

.......... concentration phenol solution acts as disinfectants.

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`2 %` 
`1%` 
`0.2%` 
`0.1%`

SOLUTION :`1 %`
93834.

, Compounds (X) and (Y) can be differentiated by :

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`H_(3)O^(o+), NAOI`
`H_(3)O^(o+)`, then FEHLING test
`H_(3)O^(o+)`, then Na
Both (b) and (C)

Solution :
93835.

…………………….. Compounds are the important consituents of explosives, drugs, dyes, fuels, polymers, synthetic rubbers.

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ANSWER :NOTROGEN
93836.

……………. compound gives Hofmann bromamide reaction.

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ETHYL cyanide
Ethenoic acid
Ethenamide
Ethenamine

Answer :C
93837.

{:("Column A","Column B"),("A) Glass","1) Framework silica"),("B) Quartz","2) Malleable and ductile"),("C) Metallic crystal","3) Pseudo solid"):} The correct match is

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`{:(A,B,C),(1,3,2):}`
`{:(A,B,C),(3,1,2):}`
`{:(A,B,C),(2,1,3):}`
`{:(A,B,C),(1,2,3):}`

ANSWER :B
93838.

........... colloid is used as eye lotion.

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SOLUTION :ARGYROL
93839.

_____is/are used to obtain aromatic comopounds.

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Wood
Coal tar
Petroleum
Both B and C

Answer :Bituminus
93840.

-CN group is converted into- COOH group by ,

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HYDROLYSIS
OXIDATION
REDUCTION
ESTERIFICATION

ANSWER :A
93841.

+CH_(3)NH_(2)rarr Product: product is :

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NONE of these

Solution :
93842.

+CH_(3)MgBroverset(H_(3)O^(+))(to)P. Product P in the above reaction is ……………..

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ANSWER :B
93843.

, CH_(3)CH_(2)COOHIdentify X:

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`CH_(3)-CH_(2)-C-=C-CH_(2)-CH_(3)`
`CH_(3)-C-=CH_(2)-CH_(2)-CH_(3)`

SOLUTION :N//A
93844.

+CH_(3)-NH_(2)toP P is?

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SOLUTION :
93845.

{:(""CH_(3)),(""|),(CH_(3)-CH-CH-CH-CH_(2)-CH_(2)),(""| ""|),(""CH_(2)-Cl CH_(3)):} locants at parent carbon chain will be :-

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1
2
3
4

Answer :D
93846.

-CH_2OH group is obtained by reduction of

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R-CN
`R-NO_2`
R-CO-R
R-COOH

Answer :D
93847.

+CH_2N_2overset(UV)tomtoTotal no .of products.

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Solution :Some INITIALLY formed SINGLET carbene consume collides with inert gas molecule and changes to triplet.

TOTAL 3 stereoisomers (2 optically ACTIVE, 1 optically inactive)
93848.

(-CH_(2) - underset(CH_(3))underset(||)overset(CH_(3))overset(||)(C) - CH_(2) - underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-)_(n) is apolymer having monomer units

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ANSWER :A
93849.

(--CH_2-underset(CH_3)underset(|)overset(CH_3)overset(|)C-CH_2-underset(CH_3)underset(|)overset(CH_3)overset(|)C--)_n is a polymer having monomer units .............

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SOLUTION :ISOBUTYLENE , is the MONOMER .
93850.

(-- CH_2 - underset(CH_3)underset(|) overset(CH_3)overset(|)C-CH_2 - underset(CH_3)underset(|)overset(CH_3)overset(|)C--)_n is a polymer having monomer units.

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SOLUTION :The REPEATING strtuctural unit in the given POLYMER is `-CH_2 - underset(CH_3)underset(|) overset(CH_3)overset(|)C -`and HENCE the MONOMER is isobutylene,