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20501.

When conc . Aqueous solution of potassium acetate is electrolysed we get

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METHANE
ethane
acetylene
ethylene

Answer :B
20502.

Which of the following cannot be used for converting aldehydes and ketones to alcohols?

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Finely divided nickel
Finely divided MAGNESIUM
`NaBH_(4)`
`LiAlH_(4)`.

ANSWER :B
20503.

Which galvanic cell can be obtained by following redox reaction ? (1)/(2)H_(2(g))+AgCl_((S)) hArr_((aq))^(+)+Cl_((aq))^(-)+Ag_((S))

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`Pt|H_(2(g))|KCl||AgCl_((S))|AG`
`Pt|H_(2(g))|HCL ||AgCl_((S))|Ag`
`Pt|H_(2(G))|HCl ||AgNO_(3)|Ag`
`Pt|AgCl_((g))|KCl||HCl|H_(2(g))|Pt`

Solution :`Pt|H_(2(g))|HCl ||AgCl_((S))|Ag`
20504.

Which of the following does not react with Fehling's solution

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BENZALDEHYDE
GIucose
ACETALDEHYDE
FORMIC acid

Answer :A
20505.

When the message between two neurons or that between neurons to muscles is complicated through certain chemicals. What are called such messengers ?

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CHEMICAL MESSENGERS
Internal messengers
Cell membrane
Cellular FLUID 

SOLUTION :Chemical messengers
20506.

Using IUPAC norms write the formulae for the following : Tetraamminechloridonitrito-N-platinum(IV)sulphate

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Solution :`[PT(NH_(3))_(4)CL(NO_(2))]SO_(4)`
Tetraamminechloridonitrito-N-platinum(IV)sulphate
20507.

Vitamin B_(12) contains:

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Fe(II)
CO(III)
ZN(II)
CA(II)

Answer :B
20508.

When 0.5 amp of current was passed for 200 seconds, 0.34 gm of copper was deposited , the electrochemical equivalent of copper will be

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34
3.4
0.034
0.0034

Solution :`W=Zit THEREFORE Z=(0.34)/(0.5xx200)`
20509.

Which one of the furnaces among the following can produce the highest temperature?

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MUFFLE FURNACE
blast furnace
REVERBERATORY furnace
ELECTRIC furnace

SOLUTION :electric furnace
20510.

Which of the following IUPAC names(s) is/are not correctly matched with its formula?

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Dichloridobis(ethane-1,2-diamine)cobalt(III) ion: `[CoCl_(2)(en)_(2)]^(+)`
Sodium (ethylenediaminetetraacetato)chromate(II): `Na_(2)[Cr(en)(CH_(3)COO)_(4)]`
Tris(bipyridyl)iron(II) ion: `[Fe(NH_(4)C_(5)-C_(5)H_(4)N)_(3)]^(2+)`
Ammineaquadibromidocopper(II): `[CU(NH_(3))(H_(2)O)Br_(2)]`

Solution :(A). `Na_(2)[Cr(edta)]` is te correct formula for given name.
20511.

Which of the folloiwng has highest thermal stability?

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`HClO_(3)`
`HBrO_(3)`
`HIO_(3)`
`HClO_(2)`

Answer :C
20512.

Which of the following contains both Ca and Mg ?

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GYPSUM
LIMESTONE
Dolomite
Chalk

Answer :C
20513.

When a strong acid, strong base or their salt are dissolved in water, they are completely ionized. If a strong acid is added to a strong base. H^(+) ions from the former combine with OH^(-) ions of the latter forming water. The formation of each water molecule liberates a certain quantity of energy and the reaction is exothermic. The heat liberated when one mole of water is formed by combining hydrochloric acid and sodium hydroxide is 13.7 kcal. The heat liberated when one mole of water is formed by combining sulphuric acid and sodium hydroxide is

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25.5 kcal
8.5 kcal
13.7 kcal
34 kcal

Solution :`H^(+)+OH^(-)rarrH_(2)O, DeltaH_("NEUTRALIZATION")=13.7 kcal`.
20514.

x = moles of KOH consumed is :

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1
2
3
4

Solution :(C ) BALANE the EQUATION.
20515.

What is Z in the following reaction? "Ethanol" overset(PBr_(3))to Xoverset("Alcoholic" KOH)to Y underset((ii)H_(2)O)overset((i)H_(2)SO_(4))to Z

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`CH_(3)CH_(2)OCH_(2)CH_(3)`<BR>`CH_(3)CH_(2)O-SO_(3)H`
`CH_(3)CH_(2)OH`
`CH_(2)=CH_(2)`

Solution :`underset("Ethanol")(CH_(3)CH_(2)OH) overset(PBr_(3))tounderset("ETHYL Bromide")(CH_(3)CH_(2)Br) underset(-KBr)overset("Alcoholic" KOH)to underset("Ethene")(CH_(2)=CH_(2)) underset((ii)H_(2)O)overset((i)H_(2)SO_(4))to underset("Ethanol")(CH_(3)CH_(2)OH)`
20516.

When a chromite ore (A) is fused with sodium carbonate in free excess of air and the product is dissolved in water, a yellow solution of compound (B) is obtained. After treatment of this yellow solution with sulphuric acid, Compound (C ) can be crystallised from the solution. When compound (C ) is treated with KCl, orange crystals of compound (D) crystallise out. Identify A to D and also explain the reactions.

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Solution :`A: FeCr_(2)O_(4), B: Na_(2)CrO_(4)`
`C: Na_(2) Cr_(2)O_(7), D: K_(2)Cr_(2)O_(7)`
`underset((A))(4FeCr_(2)O_(4)) + 8Na_(2)CO_(3) + 7O_(2) rarr underset((B))(8Na_(2)CrO_(4))`
`underset((B))(2Na_(2)CrO_(4)) + 2H^(+) rarr Na_(2)Cr_(2)O_(7) + H_(2)O + 2NA^(+)`
`underset((C ))(Na_(2)Cr_(2)O_(7)) + 2KCl rarr underset((D))(K_(2)Cr_(2)O_(7)) + 2NaCl`
20517.

The time required to coat a metal surface of 80 cm^2 with 5xx10^(-3) cm thick layer of silver (density 10.5 g cm^(-3) with th passageof 3A current through a silver nitrate solution is :

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115 sec
125 sec
135 sec
145 sec

Answer :B
20518.

The solubility product of a binary weak electrolyte is 4 xx 10^(-10) " at"298K. It's solubility in mol dm^(-3) at the same temperature is

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`8 xx 10^(-10)`
`16 xx 10^(-20)`
`4 xx 10^(-5)`
`2 xx 10^(-5)`

SOLUTION :For binary electrolyte the solubility and solubility product RELATION is `K_(SP) = S.S`.
`S= sqrt(K_(SP)) = sqrt(4 xx 10^(-10)) = 2.10^(-5) mol dm^(-3)`
20519.

Which of the following statements is trueA) Ma_3b_3 type of complex exhibits fac-mer isomerismB) Tetrahedral complexes do not exhibit optical isomerism C)[Co(en)_3]^(3+) shows optical isomerismD) [Pt(en)_2Cl_2] does not exhibit optical isomerism

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A,B,C are CORRECT
B, C, D are correct
A, C, D are correct
All are correct

Answer :A
20520.

Which of the following compound is formed when ethanol reacts with acetic acid in the presence of concentrated H_2 SO_4 .

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`CH_3 COOC_2H_5`
`C_2H_5OC_2H_5`
`CH_3 OCH_3`
`CH_3 CH_2 CHO`

ANSWER :A
20521.

Which metal is refined by Mond process?

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Titanium
Copper
NICKEL
Zinc

Solution :Nickel METAL is REFINED by MOND PROCESS.
20522.

Which one of the following will have the maximum dipole moment

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`CH_(3)F`<BR>`CH_(3)Cl`
`CH_(3)Br`
`CH_(3)I`

Solution :`CH_(3)Cl` has higher dipole MOMENT than `CH_(3)F` due to MUCH longer C-Cl bond than C-F bond length.
20523.

Which of the following reactions is not a disproportionation reactio ?

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`2NO_(2)+H_(2)O=HNO_(3)+HNO_(2)`
`Cl_(2)+H_(2)O=HCl+HClO`
`3K_(2)MnO_(4)+2H_(2)O=2KMnO_(4)+MnO_(2)+4KOH`
`2FeSO_(4)+2H_(2)O=Fe_(2)(OH)_(2)SO_(4)+H_(2)SO_(4)`

ANSWER :d
20524.

What is meant by corrosion ?

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SOLUTION :This REDOX process which CAUSES the DETERIORATION of metal is called corrosion.
20525.

What are amino acids ? Why are they so important ?

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Solution :Amino acids. These are organic compounds containing both an amino group and carboxylic group in their molecules . These are represented by the general formula:

The amino `(-NH_2)` group may be attached to any carbon atom other than that of carboxylic (-COOH) group. Accordingly, they are classified as `alpha-, beta-gamma-` etc. amino acid depending upon the position of amino group with respect to the carboxyl group. The carbon atom adjacent to the carboxyl group is designated as a carbon while the successive carbon atoms ALONG the carbon chain are `beta, gamma`-carbon atoms. Amino acids are referred to as `alpha, beta, gamma` depending upon whether the amino group is present on `alpha, beta, gamma` carbon atom RELATIVE to carboxyl group. Nearly all the NATURALLY occurring amino acids are `alpha`-amino acids i.e. containing amino group on the carbon atoms a to the carboxylic group. The general structure of `alpha`-amino acid is shown above. These amino acids are very important because these are the building blocks of proteins, which are very essential for us. The HUMAN body can synthesise 10 out of 20 amino acids found in proteins. Therefore, other must be supplied in our diet and these are called essential amino acids. Lack of essential amino acids in diet can cause diseases such as kwashiorkor.
20526.

When CuSO_(4) reacts with KI, the oxidation number of Cu changes by

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0
`-1`
1
2

Solution :`overset(+2)(Cu)SO_(4)+2 KI hArr K_(2)SO_(4)+CuI_(2)`
`2 CuI_(2) rarr overset(+1)(Cu)_(2)I_(2)+I_(2)`
20527.

Vappour pressure of water decreases from one atmosphere to one bar by dissolving glucose. (1 atm =1.01 bar) . Which statement (s) is (are) correct ? (P_("bar")=1 "atm")

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The solution contains approximately `1%` of glucose by moles
The solution is NEARLY `9%` w/w
The external pressure MUST be reduced by nearly `1%` to boil the solution
The prepared solution boils at `100^(@)C`

ANSWER :A::B::C
20528.

Which of the following contains P-O-P bond

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Hypophosphorus ACID
PHOSPHORUS acid
Pyrophosphoric acid
Orthophosphoric acid

SOLUTION :
20529.

Which group elements of first transition series has the highest paramagnetism in elemental form of +1 O.S, +2 O.S. and +3 O.S.(O.S.= Oxidation state) respectively ?

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Group 6, Group 7, Group 7, Group 8
Group7, Group 6, Group 5, Group 8
Group 8, Group 9, Group10, Group 11
Group 3, Group 4, Group 5, Group 6

Answer :A
20530.

Which of the following elements does not show allotropy?

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NITROGEN
BISMUTH
ANTIMONY
ARSENIC

ANSWER :A
20531.

Write the structure of monomers used for getting the following polymers: Glyptal

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SOLUTION :
20532.

Which of the following is most basic ?

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BENZYLAMINE
ANILINE
Acetamide
p-Nitroaniline.

Answer :A
20533.

The structural feature that distinguishes proline from other amino acids are

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It is a secondary amine
It is a PRIMARY amine
It is a TERTIARY amine
It exists as CYCLIC AMIDE

Solution :
20534.

There are some arrangements of atomic orbitals which are given below: Then calculate the value of "QtimesR-P'" where P, Q and R are no. of arrangements which give bonding molecular orbitals (positive overlap), antibonding molecular orbitals (negative overlap) and non-bonding molecular orbitals (zero overlap) respectively.

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Solution :(P)=(i), (iii), (Iv), (VII), (4)
(Q)=(ii), (V), (ix), (3)
(R)=(ii), (vii), (2)
then `QtimesR=3times2-4implies2`
20535.

Whichone of the followingis notmonosaccharide ?

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FRUCTOSE
RIBOSE
ERYTHROSE
MALTOSE

ANSWER :D
20536.

When phenol reacts with which one of the following reagents, a conjugate diketone will be formed ?

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`Na_2Cr_2O_7`
`CONC. HNO_3`
`ZN, DELTA `
`Na_2Cr_2O_7 + H_2SO_4`

ANSWER :D
20537.

Which gives blue colour to glass ?

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NiO
CoO
`FeSO_4`
CdS

Answer :B
20538.

Which is the correct IUPAC name for CH_(3)-underset(C_(2)H_(5))underset("|")("C")H-CH_(2)-Br ?

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1-Bromo-2-ethylpropane
1-Bromo-2-ethyl-2-methylethane
1-Bromo-2-methylbutane
2-Methyl-1-bromobutane

Solution :`CH_(3)-UNDERSET(underset(3)(C )H_(2)-underset(4)(C )H_(3))underset("|")(OVERSET("2")("C"))H-overset(1)(C )H_(2)-Br`
20539.

Which can be purified by sublimation ?

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`F_(2)`<BR>`Cl_(2)`
`Br_(2)`
`I_(2)`

ANSWER :D
20540.

What product is obtained when propionamide is heated with Br_(2) in alkali

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`CH_(3)CH_(2)COONa`
`CH_(3)CH_(2)CONHBr`
`CH_(3)CH_(2)NH_(2)`
`CH_(3)CH_(2)COOH`

ANSWER :C
20541.

Write the structure of the products in each case: (i) CH_(3)CH_(2)NH_(2) overset ((CH_(3)CO)_(2))(Delta) (ii)CH_(3)CONHC_(6)H_(5) overset(Br_(2)//Fe) to (iii) CH_(3)CH_(2)CN overset(H_(2)O/H)to

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SOLUTION :(i) `CH_(3)CH_(2)NHCOCH_(3), CH_(3)COOH`
(II)
(III) `CH_(3)CH_(2)COOH + NH_(4)^(+)`
20542.

Which of the following ion has highest ionic radius

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`Sc^(+3)`
`LA^(+3)`
`Ce^(+3)`
`LU^(+3)`

Answer :B
20543.

Which is not correct for N_2O ?

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It is CALLED laughing gas
It is nitrous oxide
It is not a linear molecule
It is least reactive of all the OXIDES of nitrogen

Answer :C
20544.

Which of the following compounds give alcohol on reaction with NaNO_(2) and HCI

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`C_(6)H_(5)CH_(2)NH_(2)`
`CH_(3)NHCH_(2)CH_(3)`
`CH_(3)CH_(2)CH_(2)NH_(2)`
`CH_(3)CH_(2)N(CH_(3))_(2)`

Solution :`1^(@)` amines gives the `"Rea"^(n)`
20545.

Which of the following could act as a propellant for rocket

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Liquid HYDROGEN + Liquid nitrogen
Liquid OXYGEN + Liquid argon
Liquid hydrogen + Liquid oxygen
Liquid nitrogen + Liquid oxygen

Solution :Liquid hydrogen + Liquid oxygen could ACT as a propellant of rocket.
20546.

Which statement is wrong?

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Haber's PROCESS of `NH_3` requires iron as catalyst.
Substances MADE by CHEMISTS to activate washing power
Hydrogenation of oils requires iron as catalyst
Oxidation of `SO_2` to `SO_3` requires `V_O_5`

Answer :C
20547.

What is meant by matrix?

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Solution :The IMPURITIES like SAND, mud and stone PRESENT in the ore are CALLED matrix or GANGUE.
20548.

The total number of isomers for the compound of the formula C_(4)H_(10)O is :

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SEVEN
Six
Three
Four

Answer :A
20549.

When acetylene reacts with arsenic trichloride in the presence of anhydous aluminium chloride, it produces

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LEWISITE
`BETA`-Chlorovinyl dichloroarisine
Nitrobenzene
Both (a) and (B)

ANSWER :D
20550.

Which of the following has highest Ka value ?

Answer»




ANSWER :D