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7501.

Differentiate the following:03omega

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7502.

QUE S T2.Why should a magnesium ribbon boWrito ihbe cleaned before burning in air?chemical reactions.

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7503.

5.How is plaster of Paris chemically different from gypsum? How can they be interconverted? Writetwo uses of plaster of Paris.

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Gypsum chemical formula is CaSO4.2H2O whereas on the other hand chemical formula for the plaster of Paris is CaSO4.1/2H2O.

On heating, the gypsum at 373 K plaster of Paris is formed which is mostly used by the doctors for the treatment like fractures, sprain, etc. this is due to the properties of plaster of paris which is paitentent gets faster relief from the pain.

7504.

S R RO R Wस)-निम्न-अश्विकियाओं को. पर्ण कीजिए |H20(i) CeHsOH +Br, > B{0H(if) CeHsOH + (CHy)N, _ "7

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(1) C6H5OH + 3Br2 --H2O--> C6H2Br3OH + 3HBr

(2) 12(CH2)6N4 + 16H3BO3 + 27H2O + 9C6H5OH -----> 16(NH4)3BO3 + 18C6H4(OH)CHO

7505.

in solid the sound travel first

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Solids have a higher density and the speed of sound depends on the density of the medium.

7506.

6) Expansion of a perfect gas into vacuum is related with(1) ΔΗ(2) q 0(3)W=0(4) All of these

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When an Ideal gas is expanded into vacuum, it does no work. (W =0) Hence, no change in the internal energy and thus in the temperature of the gas.This means the q = 0, change in internal energy and enthalpy are also zero.Hence, Option (4) is correct.

7507.

a)54. The molecular formula of the third member of the homologous series of ketones is(d) CH12O(a) C4HgO(b) C3H,O(c) CsH1oO

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7508.

If the speed of light in a medium is1.5 x 10^8 m/s, what is the absoluterefractive index of the medium?

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absolute refractive index is (speed of light in vacuum)/speed in medium= 3*10^8/1.5×10^8= 2

7509.

The third member of the family of alkenyneshas the molecular formula(1) CH(3) CH(2) CH(4) C,H

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C H 3 8

CH2=CH-CH2-C≡C-CH3

option 3

7510.

42.If the amount of dissociation is 0.5, the value ofK for the reaction NO, NO+NO, will be(1) equal to the pressure of the system.(2)of the pressure of the system.3Cocoof the pressure of the system.(4) 5 times of the pressure of the system.

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2 option is the correct one. the value of Kp for the reaction is 2/8 of pressure

2nd optoin is correct answer

2nd option is correct as value of kp is always 2/8 of pressure of the systen

option 2 is correct answer.

7511.

4Y16The values of Kp, and Kp, for the reactionsX YZ(1) andA 2Bare in ratio of 9:1. If degree of dissociation of Xand A be equal, then total pressure at equilibrium(1) and (2) are in the ratio

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7512.

SECTIONCa.Name two acids that are usually present in rain water.

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The main chemicals in air pollution that create acid rain are sulphur dioxide (SO2) and nitrogen (NOx). Acid rain usually forms high in the clouds where sulphur dioxide and nitrogen oxides react with water, oxygen, and oxidants. this mixture forms a mild solution of sulphuric acid and nitric acid.

Therefore, Sulphuric acid and Nitric acid are usually present in rain water.

sulphuric dioxide and nitrogen oxides

sulper dioxide, nitrogen dioxide

Nitrous acid and Sulphurous acid

7513.

A certain charge Q is divided at first into two parts,(q) and (Q-q). Later on the charges are placed at acertain distance. If the force of interaction betweenthe two charges is maximum then-

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let parts are sepereted at a distance of d

so repulsion force F= k q(Q-q)/d2

here Q and d are constant so for maximum force differentiate the force w.r.t q

dF/dq = k/d2[Q -2q]

for maximum force dF/dq=0

Q-2q=0

Q/q =2

7514.

59.Calculate the partial pressure of carbon monoxide fromthe following data:CaCO,(s) ㅡ스→ Cao (s) + CO2 ↑,K78 x 102CO2(g) + C (s)--→ 2 CO (g), Kp-2(b) 0.4(d) 4(a) 0.2

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7515.

For the reaction : 2HI (g)29+ 12(9): thedegree of dissociation (a) of HI (g) is related toequilibrium constant Kp by the expression1+2K1+2 Kp22K2yKp(D) 1+2Kp

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7516.

For the reaction CO(g)+Cl2 (g)---------->COCI,(g)the Kp/Kc is equal to(A) √RT(B) RT(C) 1.0(D) 1/RT

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the value of Kp/kc = (RT)^{∆n} here , ∆n = 1-2 =-1 ( 1 mole of gas in product side - 2 mole at reactant side.) so Kp/kc = (RT)^{-1} therefore Kp/Kc = 1/RT option D.

7517.

a. Classify the acids according totheir basicity and give one exampleof each type.

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According to basicity Acid can be divided into 3 types:1) Monobasic : Examples HCL ( Hydrochloric Acid)2) Dibasic : Examples H2SO4 (Sulphuric Acid)3) Tribasic : Examples H3PO4 (Phosphoric Acid)

7518.

Write down the causative orgapism of the following diseases.a. Tuberculosisb. Measlesc. Elephantiasise. Athletiรง footf. Chdlera

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a. . Mycobacterium tuberculosis

b. Measles virus

c. Wuchereria bancrofti,Brugia malayi,B. timori

d. Plasmodium falciparum

e. Trichophyton, Epidermophyton, and Microsporum

f. Vibrio cholerae

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7519.

1.N2O4(g)2NO2(g); Kp and Kc are related as(2) KpK(3) K, ET2(RT)(4) KpKc(RT)

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option 4 is the answer.

7520.

We can classify acids and bases having no H orOH- ions. This is the statement of the scientist(1) Lewis(2) Bronsted and Lowry(3) Arhenius(4) Sorensen

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A Lewis acid is therefore any substance, such as the H+ion, that can accept a pair ofnonbondingelectrons. Inotherwords, a Lewis acid is an electron-pair acceptor.hence Lewis ..option a is the answer

7521.

Write down the causative orgapiśm of the following diseases.a. Tuberculosisb. Measlesc. Elephantiasisaria-e. Athletic footf. Chdlera

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a. Mycobacterium tuberculosis

b. Measles virus

c. Wuchereria bancrofti,Brugia malayi,B. timori

d. Plasmodium falciparum

e. Trichophyton, Epidermophyton, and Microsporum

f. Vibrio cholerae

7522.

3. An element has its electronconfiguration as 2,8,2. Now answerthe following questions.What is the atomic number of thiselement?What is the group of this element?To which period does this elementbelong?a.b.c.

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A. The atomic number is 12b. The valency of it is +2. It can donate electrons.c. Be because they both have same number of valence electron in their outermost orbit. Hence both are metals can donate electrons. And both lie in same group that is group 2 so they have same physical and chemical properties.

7523.

What are Lewis bases?libria

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ALewis baseis any substance, such as the OH-ion, that can donate a pair of nonbonding electrons. ALewis baseis therefore an electron-pair donor. One advantage of theLewistheory is the way it complements the model of oxidation-reduction reactions.

A Lewis's base has a substance such sa OH ions

a Lewis base give a OH ion

A Lewis acid is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct.

ALewis baseis any substance, such as the OH-ion, that can donate a pair of nonbonding electrons. ALewis baseis therefore an electron-pair donor. One advantage of theLewistheory is the way it complements the model of oxidation-reduction reactions.

Lewis base is given OH

a Lewis base give a OH ion

7524.

Explain positive resonance effect ( + R effect).

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Positive Resonance Effect-Positive resonance effect occurs when the groups release electrons to the other molecules by the process of delocalization. The groups are usually denoted by +R or +M. In this process, the molecular electron density increases. For example- -OH, -SH, -OR,-SR.

7525.

dnaw the lewis structuse tost the ioninaw the lewis stHuctuste fou the ionicompounds by the follosins paits otelement

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7526.

2) What are intermolecular forces ?3) H is a Lewis base. Give reason.

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3)Lewis base is a substance that can donate an electrone pair.Those species having a lonepair always forms Lewis base so H-is a Lewis base as it possess a lone pair and can donate it.

2)Intermolecular forces are the forces which mediate interaction between molecules, including forces of attraction or repulsion which act between molecules and other types of neighboring particles, e.g., atoms or ions. ... Ion-induced dipole forces. Ion-dipole forces. Hydrogen bonding.

7527.

Write Lewis symbols for the formation offollowing atoms and ions S and S2-, Al and Alb*, H2

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7528.

. Draw the Lewis structure of CO and CO

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7529.

Lewis dot structure ofH2SO3

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This is the H2SO3 Lewis structure:sulfurous acid. The key to understanding this Lewis structure is recognizing these two H's in front attached to a polyatomic ion. That makes it an acid. And theseOxygenshere, theHydrogenswill attach to the outside of theOxygens.

7530.

Write the Lewis dot structure of comolecule.

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7531.

Question.26 Write the electron dot structure of ethane molecule (C2H6)

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7532.

What will be the formula and electron dot structuredi cycfopentane?

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7533.

In the aqueous solution of sulphuric acid themole fraction of water is 0.85. The molality ofthe solution is(A) 8.9 m(C) 9.8 m(B) 0.19 m(D) 15 m

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The relationship between mole fraction and molality is given as

m=1000 X xB/(1-XB)X Molecular weoght of solvent

The tricky part in this question is observing which is solute and solvent.

Mole fraction of water is 0.85 which means it is not the solute but it is the SOLVENT.

We know that mole fraction of solute+mole fraction of solvent=1

Therefore, xB=0.15

Substitute it in given equation,

1000(0.15)/(0.85)(18)

Which is equal to 9.8

7534.

Q1. Define the following terms:(a) client (b) server

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The term "client software" is used to refer to the software that acts as the interface between the client computer and the server.

In computing, aserveris a computer program or a device that provides functionality for other programs or devices, called "clients."

7535.

1. Define the following terms.(a) Atom(b) Atomicity

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a) Anatomis a fundamental constituent of a matter. Anatomitself is made up of three kinds of particles called subatomic particles: protons, neutrons, and electrons.

b)Atomicity is the total number of atoms present in one molecule of an element, compound or a substance.

For example oxygen O2 exists as diatomic means 2 atoms of oxygen are present.

7536.

What is conformation? Explain the conformation in ethane.

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Ans :- Inchemistry, conformational isomerism is a form of stereoisomerism in which the isomers can be interconverted exclusively by rotations about formally single bonds (refer to figure on single bond rotation). Such isomers are generally referred to as conformational isomers or conformers and, specifically, as rotamers.

The lowest energyconformation of ethane, shown in the figure above, is called the 'staggered'conformation, in which all of the C-H bonds on the front carbon are positioned at dihedral angles of 60°relative to the C-H bonds on the back carbon. Another 60°rotation returns the molecule to a second eclipsedconformation.

7537.

cercises2.1 Define the term solution. How many types of solutions are formed? Write briefly2.2 Give an example of a solid solution in which the solute is a gas.2.3 Define the following terms:about each type with an example.(0 Mole fraction (ii) Molality (ii) Molarity (iv)Mass percentage.Concentrated nitric acid used in laboratory work is 68% nitric acid by mass inaqueous solution. What should be the molarity of such a sample of the acid ifthe density of the solution is 1.504 g mL1?2.4

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7538.

5. The hybridization of iodine in iodosobenzene is:2(a) sp(c) sp3(b) sp(d) sp d

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Iodine (I) is bonded to sp^2 hybridised carbon.

Bonded electron group =3Non-Bonded electron group =1

Difference =3-1=2

hence, I is sp^2 hybridised

7539.

overlapIn C2H, (ethane), the C-C sigma (o) bond is formed by(4) sp3 -sp(2) sp(3) s - s

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option 4 is correct answer

7540.

Q1. Define Absolute Zero.

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Absolute zero is the lowest possible temperature where nothing could be colder and no heat energy remains in a substance

7541.

Q1. What are canal rays?

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7542.

define aqueous solution

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An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending to the relevant chemical formula. For example, a solution of table salt, or sodium chloride, in water would be represented as Na+ + Cl−.

it is a solution in which solute and solvent are present

7543.

Copper (D had d10 configuration, while Copper (I1) has do configuration.Still Copper (II) is more stable in aqueous solution than CopperWhy?(b)

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7544.

briefly explain what is copper co-enzyme?

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Copper cofactoris a non-proteinchemical compoundormetallic ionthat is required for anenzyme's activity. Cofactors can be considered "helper molecules" that assist inbiochemicaltransformations. The rates at which these happen are characterized byenzyme kinetics.

13 L 4 A 7 = 41 or 14 A 3 L 12 = 54 rahe yo 12 L 3 A 9 =

7545.

lodine molecule dissociates into atoms after absorbing light of 4500A. If onequantum of radiation is absorbed by each molecule, calculate the kinetic energyof iodine atoms. [BE of 12 240 kJ mol IIT 1995/ [Ans. 2.165 x 10-20 JI

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7546.

14) Find the equation of circle passing through thepoints (1, -2) and (4,-3) and whose centre lies onthe line 3x +2y 7.

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equation of circle with(1,−2)(1,−2)and as(4,−3)(4,−3)diameter,

(x−1)(x−4)+y+2)(y+3)=0(1)(1)(x−1)(x−4)+y+2)(y+3)=0

Equation of line joining(1,−2)(1,−2)and as(4,−3)(4,−3)

(4–1)(y+2)−(−3+2)(x−1)=0⟹(4–1)(y+2)−(−3+2)(x−1)=0⟹

3y+x+5=0(2)(2)3y+x+5=0

equation of family of circles passing through the 2 points is

(x−1)(x−4)+(y+2)(y+3)−2K(3y+x+5)=0⟹(x−1)(x−4)+(y+2)(y+3)−2K(3y+x+5)=0⟹

x2+y2–2(K+52)x−2(3K−52)y+10–10K=0(3)(3)x2+y2–2(K+52)x−2(3K−52)y+10–10K=0

The center is(K+52,3K−52)(K+52,3K−52)

This should lie on3x+2y=7⟹3x+2y=7⟹

3(K+52)+2(3K−52)=7⟹2K=13(K+52)+2(3K−52)=7⟹2K=1

(3) now becomes

x2+y2–6x+2y+5=0x2+y2–6x+2y+5=0

7547.

Jouing Coaldinahion Compoundlll chlasidlmicka

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7548.

15.How many moles of calcium carbonate (CaCO3) are present in 10 g of the substance ? (C40 uut16 u

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7549.

Define exchange energy.

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Theexchange energyis theenergyreleased when two or more electrons with the same spinexchangetheir positions in the degenerate orbitals of a subshell.

7550.

D. Long answer questions1. What is the difference between H, and H,0?

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H2 is Hydrogen, a gas. When it combines with oxygen(O2), it becomes H2O (water). H2 is An Element whereas H2O is a Compound. H2 exists in gaseous state because of its extremely low melting point easily and H2O exists in all three states easily.