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1.

A large number of fishes are suddenly found floating dead on a lake. There is no evidence of toxic dumping but you find an abundance of phytoplankton. Suggest a reason for the fish killing.

Answer»

Excessive phytoplankton (organic pollutants such as leaves, grass trash etc.) growth which is present in water is biodegradable. Bacteria decomposes this organic matter in water. During this process when large number of bacteria decomposes the organic matter, they consume the dissolved oxygen in water. When the level of dissolved oxygen falls below 6 ppm then the fishes cannot survive and they die.

2.

What is effect of excess of SO42- ion in drinking water?

Answer»

Excess of SO42- in drinking water (500 ppm) may cause a laxative effect.

3.

What are fungicides?

Answer»

Those chemicals which check the growth of fungi are called fungicides.

4.

What are primary and secondary pollutants of the air?

Answer»

Primary pollutants are those which after their formation remain as such, e.g., NO. Secondary pollutants are those which are formed as a result of reaction between primary pollutants, e.g., PAN (peroxyacylnirates).

5.

(a) Oxidation of sulphur trioxide in the absence of a catalyst is a slow process but this oxidation occurs easily in the atmosphere. Explain how does this happen. Give chemical reactions for the conversion of SO2 into SO3.(b) How is ozone produced in stratosphere?(c) What is the compound formed when CO combines with blood?

Answer»

(a) The presence of particulate matter in polluted air catalyses the oxidation of SO2 to SO3. The reaction is also promoted by ozone and hydrogen peroxide.

2SO2 + O2 \(\overset{Dust\,or\,soot\,particles}{\rightarrow}\) 2SO3

SO2 + O\(\overset{hv}{\rightarrow}\) SO3 + O2

SO+ H2O2 → H2O + SO3

(b) The formation of ozone in the stratosphere takes place in two steps. In the first step, ultraviolet radiation coming from the sun has sufficient energy to split dioxygen into two oxygen atoms. In the second step, the oxygen atoms react with more of dioxygen to form ozone.

O\(\overset{hv}{\rightarrow}\) O + O, O + O2 → O3

(c) Carboxyhaemoglobin (COHb).

6.

Name the different regions of the atmosphere along with their attitudes and temperature ranges.

Answer»

Troposphere (0-11 km), Stratosphere (11 – 50), Mesosphere (50 – 85 km), Thermosphere (85 – 500 km).

7.

What do you mean by "inversion temperature" in different regions of the atmosphere?

Answer»

When we go from one region of the atmosphere to the next adjoining region, the trend of temperature changes from increase to decrease or vice-versa. This is called inversion temperature.

8.

How NO2 pollution can be controlled? Explain.

Answer»

(i) The catalytic converters are used in the automobile exhaust which in the first stage converts the oxides of nitrogen to free N2 or to small amount of NH3.

(ii) The fuel gases coming from power plants or industrial units and containing NO2 and SO2 are freed from these gases by scrubbing them with sulphuric acid.

9.

In the following questions more than one option of Column I and Column II may match.Match the activity given in Column I with the type of pollution created by it given in Column II.Column I (ActivityColumn II (Effect)(i) Releasing gases to the atmosphere after burning waste material containing sulphur(a) Water pollution(ii) Using carbamates as pesticides(b) Photochemical smog, damage to plant life, corrosion to building  material, induce breathing problems, water pollution(iii) Using synthetic detergents for washing clothes(c) Damaging ozone layer(iv) Releasing gases produced by automobiles and factories in the atmosphere.(d) May cause nerve diseases in human.(v) Using chlorofluorocarbon compounds for cleaning computer parts(e) Classical smog, acid rain, water pollution, induce breathing problems, damage to buildings, corrosion of metals.

Answer» (i) → (e) (ii) → (d) (iii) → (a) (iv) → (b) (v) → (c)
10.

In the following questions more than one option of Column I and Column II may match.Match the pollutant(s) in Column I with the effect(s) in Column II.Column IColumn II(i) Oxides of sulphur(a) Global warming(ii) Nitrogen dioxide(b) Damage to kidney(iii) Carbon dioxide(c) ‘Blue baby’ syndrome(iv) Nitrate in drinking water(d) Respiratory diseases(v) Lead(e) Red haze in traffic and congested areas

Answer» (i) → (d) (ii) → (e) (iii) → (a) (iv) → (c) (v) → (b)
11.

Carbon monoxide gas is more dangerous than carbon dioxide gas. Why? Explain.

Answer»

It is highly poisonous to living beings because of its ability to block the delivery of oxygen to the organs and tissues. It binds to haemoglobin complex to form carboxyl haemoglobin (COHb) which is about 300 times more stable than oxy‐hemoglobin complex. In the blood when the concentration of carbon haemoglobin reaches about 3‐4 percent, the oxygen carrying capacity blood is greatly reduced. This oxygen deficiency, results in to headache, weak eyesight, nervousness and cardiovascular disorder CO2 does not combine with haemoglobin and hence is less harmful as pollutant but it is the main contributor forwards green house effect & global warming.

12.

What are pathogens? Mention its harmful effect?

Answer»

Pathogens are disease causing microorganisms include bacteria, Virus etc. They enter into water from animal excreta and domestic sewage.

13.

Name two herbicides used to kill weeds.

Answer»

(i) Sodium chlorate (NaClO3), (ii) Sodium arsenite (Na3AsO3).

14.

Name two herbicides? 

Answer»

NaClO3 (sodium chlorate) and Na3AsO3 (Sodium Arsenite). 

15.

Write any two achievements of green chemistry?

Answer»

1.Development of polystyrene foam sheet packaging material this Technology allows eliminations CFCs which contribute to ozone depletion, global warming and ground level smog.

2. Catalytic hydrogenation of diethanolamine in which environmental friendly herbicide is produced in less dangerous ways.

16.

Name two herbicides?

Answer»

NaClO3 (sodium chlorate) and Na3AsO3 (Sodium Arsenite)

17.

What are harmful effects as depletion of ozone layer?

Answer»

(1) The ozone layer protects the earth from the harmful UV radiation of the sun, with the depletion of the layer, more radiation will enter the earth’s atmosphere. UV radiations are harmful because they lead to the skin cancer and sun burns. 

(2) They cause death of many phytoplankton’s which lead to a decrease of fish productivity. 

(3) Increase in UV radiation, decreases the moisture content of the soil and damages both plants and fibres.

18.

Write the methods for management of waste material?

Answer»

1. Recycling:‐materials are recycled which saves the cast of raw material and waste disposal.

2. Sewage treatment

3. Burning and Incineration

4. Digesting

5. Dumping

19.

What do you mean by ozone hole? What are its Consequences

Answer»

Ozone hole implies distribution of the ozone layer by the Harmful UV radiations the depletion will virtually result in creating some sort of holes in the blanket of ozone which surround us. As a result, the harmful radiations cause skin cancer, loss of sight and also affect our immune system

20.

What do you mean by ozone hole? What are its consequences?

Answer»

Ozone hole: There is depletion of ozone over Antarctica region commonly known as a ozone hole. Its consequences are that UV light can reach the earth which can lead to ageing of skin, cataract, sunburn, skin cancer, killing of many phytoplankton, damage to fish productivity etc. It has also been observered that plant protein get easily affected by UV radiation which leads to the harmful mutation of cells.

21.

Write the methods for management of waste material?

Answer»

1. Recycling:‐materials are recycled which saves the cast of raw material and waste disposal. 

2. Sewage treatment

3. Burning and Incineration 

4. Digesting 

5. Dumping

22.

What do you mean by ozone hole? What are its Consequences .

Answer»

Ozone hole implies depletion of the ozone layer by the Harmful UV radiations .This depletion will virtually result in creating some sort of holes in the blanket of ozone which surround us. As a result, the harmful radiations cause skin cancer, loss of sight and also affect our immune system

23.

What do you mean by Biochemical oxygen demand?

Answer»

Biochemical oxygen demand is the amount of oxygen required by bacteria to decompose organic matter in a certain volume of sample of water. Clean water would have BOD value of less than 5 ppm, where as highly polluted water has a BOD of 17 ppm or more.

24.

What do you mean by Biochemical oxygen demand?

Answer»

Biochemical oxygen demand is the amount of oxygen required by bacteria to decompose organic matter in a certain volume of sample of water. Clean water would have BOD value of less than 5ppm, where as highly polluted water has a BOD of 17ppm or more

25.

Write the chemical reaction take place during acid rain in the atmosphere?

Answer»

1. H2O + CO2 ‐‐‐‐‐‐‐ > H2CO3

2. H2CO3 ‐‐‐‐‐‐ > H+ + HCO3

3. 2SO2 + O2 + 2H2O ‐‐‐‐‐‐ > 2H2SO4

26.

On the basis of chemical reactions involved, explain how do chloroflouorocarbons cause thinning of ozone layer in stratosphere.

Answer»

Chlorofluorocarbons are stable compounds. They move to stratosphere by random diffusion. These undergo decomposition in the presence of sunlight to release Cl atoms. 

These Cl atoms cause catalytic chemical reactions and cause significant depletion of ozone layer as shown below:

Cl2CF2 → Cl  + C ClF2

Cl + O3 → ClO ∙ + O2

ClO + O → Cl∙ + O2

Since the free radicals use ozone and convert it to oxygen, they cause thinning of ozone layer in stratosphere.

27.

What are harmful effects of acid rain? 

Answer»

1. It is harmful for crops 

2. It damages buildings made up of marble.

28.

What are harmful effects of acid rain?

Answer»

(i) harmful to animals.

(ii) Harmful to plants.

(iii) Harmful to material life.

29.

Write the chemical reactions for the formation of oxides of sulphur? Mention its sources?

Answer»

1. 2SO2 + O2 ‐‐‐‐‐‐ > 2SO3

2. SO2 + O3 ‐‐‐‐‐‐‐ > SO3 + O2

3. SO2 + H2O2 ‐‐‐‐‐‐ > 2H2SO4

Sources: Burning of fossil fuels containing sulphur

30.

What is acid rain? How is it harmful to the environment?

Answer»

When the PH of the rain water below 5.6 due to the presence of oxides of sulphur & nitrogen and carbon dioxide in the atmosphere is called acid rain. Harmful effects of acid rain 

1. It is toxic to vegetation and aquatic life 

2. It damages building and states and dissolves heavy metals from soils, rocks and sediments. Taj Mahal has been damaged by acid rain. 

3. The heavy metal ions such as copper, lead and aluminium, leached from the soil, enter well water and produced variety of toxic effects. 

4. Acid rain also corrodes water pipes resulting in the leaching as heavy metals such as iron, lead and copper into drinking water.

31.

CFC’s are used in :(a) Refrigerants(b) Plastic formation(c) In electrical appliances(d) All of the above

Answer»

(a) Refrigerants

32.

Particulate air pollutant is :(a) Chlorine(b) Coal(c) Ammonia(d) All of the above

Answer»

Particulate air pollutant is Coal.

33.

PAN means :(a) Peroxy Aldehyde Nitrate(b) Peroxy Ammonium Nitrate(c) Peroxy acetyl Nitrate(d) None of the above

Answer»

(c) Peroxy acetyl Nitrate

34.

Find the incorrect statement(a) BOD value of clean water is less than 5 ppm.(b) Drinking water pH should be between 5.5 - 9.5.(c) Carbon, sulphur and nitrogen oxides are the most widespread air pollutants.(d) Dissolved oxygen concentration below 5 ppm is ideal for the growth of fish.

Answer»

(d) Dissolved oxygen concentration below 5 ppm is ideal for the growth of fish.

35.

Statues and monuments in India are affected by acid rain, how?

Answer»

The air around the statues and monuments in India contains fairly high levels of the oxides of sulphur and nitrogen. This is due to a large number of industries and power plants in the nearby areas. The problem has been further aggravated due to use of poor quality of coal, kerosene and fire wood as fuel for domestic purposes. The states acid rain affects for marble of these statues and monuments. 

CaCO3+H2SO4 ‐> CaSO4+H2O+CO

As a result, this away and marble is getting discoloured and lusterless.

36.

Match the following:List - IList - IIA. Freons1. Acid rainB. Photochemical smog2. Ozone deplectionC. Classical smog3. Stone leprosyD. Acid rain4. Corrosion of painted surfacesCode :ABCD(a)2413(b)3241(c)1324(d)4132

Answer»
ABCD
(a)2143

37.

Distinguish between photochemical smog and classical smog.

Answer»
Photochemical smogClassical smog
1. it is formed by oxides of nitrogen, hydrocarbons,etc.,1. It is formed by oxides of sulphur carbon and particulate matter from combustion
2. It is oxidizing in nature2. It is reducing in nature
3. Photochemical smog occurs in cities having large numbers of vehicles. It is not harmful3. It occurs in both urban and rural areas. It is harmful
38.

Define green chemistry? Explain with one example.

Answer»

Chemistry and chemical process involving the minimum use and generation of harmful substances is called green chemistry

Ex:‐ Earlier tetrachloroethene themes was used as solvents for dry cleaning. This compound is carcinogenic; therefore it has been replaced by liquefied CO2 along with a suitable detergent, which is less harmful.

39.

Write short note on :- ( a) BOD ( b) Photo chemical smog (c).Ozone hole.

Answer»

(a) BOD: Biochemical oxygen demand is defined as the amount of oxygen required microorganisms to oxidise the organic pollutants presents in water. Water having BOD less than 5ppm is clean water and greater than 17ppm is polluted water 

(b) Photo chemical smog: It consists of oxides of nitrogen which absorb light and form free radicals. It is extremely harmful and is oxidizing in nature. 

(c) Ozone hole: ozone layer is depleted near Antarctica and it is called ozone hole.

40.

A person was using water supplied by Municipality. Due to shortage of water he started using underground water. He felt laxative effect. What could be the cause?

Answer»

The laxative effect is observed only when the concentration of sulphates in water is greater than 500 ppm. Sulphate is harmless at moderate concentration but concentration above 500 ppm produces laxative effects and hypertension.

41.

Freons are ………

Answer»

Freons are Chiorofluoroalkanes.

42.

Ozone layer is depicted by the reactive ………

Answer»

Ozone layer is depicted by the reactive Chlorine atom.

43.

Assertion(A):-Excessive use of chlorinated synthetic pesticides causes soil and water pollution.Reason (R) :-Such pesticides are non- biodegradable.(a) Both A and R are correct and R is the correct explanation of A.(b) Both A and R are correct and R is not the correct explanation of A.(c) Both A and R are not correct.(d) A is not correct but R is correct.

Answer»

(a) Both A and R are correct and R is the correct explanation of A.

44.

Define primary pollutant of the air.

Answer»

Those pollutants which are directly emitted from the sources and pollute the air are called primary pollutants of the air.

45.

What is marine pollution?

Answer»

Pollution of sea water due to discharge of wastes into it is called marine pollution.

46.

Which disease is caused due to hole in the ozone layer and why?

Answer»

Ultra violet rays will reach the earth after passing through the hole and cause skin cancer.

47.

Give one main reason of ozone depletion.

Answer»

Chlorofluorocarbon causes depletion of ozone layer.

48.

Assertion(A):- Classical smog is reducing in nature.Reason(R):- It is a mixture of smoke, fog and sulphur dioxide(a) Both A and R are correct and R is the correct explanation of A.(b) Both A and R are correct and R is not the correct explanation of A.(c) Both A and R are not correct.(d) A is not correct but R is correct.

Answer»

(a) Both A and R are correct and R is the correct explanation of A.

49.

Give one main reason of ozone depletion? 

Answer»

The main reason of ozone depletion is the release of chlorofluoro compounds (CFC’s) in the atmosphere also known as Freon.

50.

What is the nature of classical smog?

Answer»

Reducing is the nature of classical smog.