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1.

Why are Grignard reagents soluble in ether but not in benzene? 

Answer»

Grignard reagents from co-ordination complexes with ether but not benzene since the former has lone pair of electrons but the later does not. 

2.

Di-tert butyl ether cannot be made by Williamson’s synthesis. Explain why ? 

Answer»

To prepare di tert-butyl ether by Williamson’s synthesis, we need tert-butyl bromide and Sodium tertiary butoxide. Since tert-butyl bromide being 3°-alkyl halide prefers to undergo elimination rather than substitution, therefore the product obtained is isobutylene rather than ditertiary butyl ether. 

3.

Give a chemical test to distinguish between (i) Ether and an Alcohol (ii) Ether and Phenol

Answer»

(i) Alcohols give positive Lucas Test but ethers are not or any other. 

(ii) Phenol gives positive neutral FeCl3 Test but ethers not or any other.