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1.

What are the problems of hydrogen concentration?

Answer»

If the concentration of hydrogen more than 4% and less than 74% explosion problems will be there. Therefore the concentration of hydrogen is restricted to less than 1% by air changer ventilation system. 

2.

Write chemical equation for lead acid cell. 

Answer»

PbO2 + H2 SO4  PbSO4 +2 H2 (during discharge) 

Pb + SO4  PbSO4 (during charge)

3.

What are the advantages of plante type batteries? 

Answer»

Plante plate type batteries have longer life and can with stand rapid discharge. 

4.

How H2 O2 generated in lead acid battery? 

Answer»

At end of charge, when most of the Pb is converted. H2 O2 generated from H2O. O2 appears as gas at positive plate. H2 at negative plate, i.e. gassing starts.

5.

Why lead acid battery requires so much large initial charging? 

Answer»

Initially for a new battery, negative plate will be PbO instead of Pb. To convert all of them back to Pb, we need so much prolonged initial charging. 

6.

Is the chemical reaction of plante cells same as tubular lead acid cells? 

Answer»

No. Plante cells having both electrodes are lead (Pb) only. 

During charging, H2 H2 + O2 

O2 reacts with Pb to form PbO2 + (+ve plate) 

During discharge, Pb + c PbSO4 (on -ve plate)

While PbO2  Pb + O2 (on +ve plate).  

That is converted back to lead. 

Therefore PbSO4 formed only on -ve plate. That is sulphation problem are reduced by 50%