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51.

Rewrite the following statements by selecting the correct options:i. ………… is a metal. (a) Mg (b) S (c) P (d) Brii. ………. is a nonmetal. (a) Au (b) Hg (c) Br (d) Cuiii. ………… is a metalloid. (a) Aluminium (b) Antimony (c) Zinc (d) Mercuryiv. Metalloids have properties of ……….. (a) metals (b) nonmetals (c) both metals and nonmetals (d) neither metals nor nonmetalsv. …………. is a good conductor of electricity. (a) Bromine (b) Iodine (c) Graphite (d) Sulphur

Answer»

i. Mg is a metal.

ii. Br is a nonmetal.

iii. Antimony is a metalloid.

iv. Metalloids have properties of both metals and nonmetals.

v. Graphite is a good conductor of electricity.

52.

Cations are formed by _____ (loss / gain) of electrons and anions are formed by _____ (loss / gain) of electrons.

Answer»

Cations are formed by loss of electrons and anions are formed by gain of electrons.

53.

In construction work, state why the alloy duralumin is used rather than pure aluminium.

Answer»

Duralumin is light, strong and corrosion resistant.

54.

Which of the following statements is correct for roastingA. convert sulphide to oxideB. Convert sulphide to sulphateC. Remove aresnic and sulphur impuritiesD. All

Answer» Correct Answer - D
55.

A metal ‘X’ has a valency 2 and a non-metal ‘Y’ has a valency 3. Write an equation to show how ‘Y’ forms an ion.

Answer»

3X - 6e→ 3X2+

2Y + 6e→ 2Y3-

56.

Element X is a metal with a valency 2. Element Y is a nonmetal with a valency 3. Write equations to show how X and Y form ions.

Answer»

Y + 3e → Y3 (cations formed).

57.

Aluminium is extracted from alumina (Al2O3) by electrolysis of a molten mixture of …………… (a) (Al2O3) + KF + Na3AlF6 (b) (Al2O3) + HF + NaAlF4 (c) (Al2O3) + CaF2 + NaAlF4(d) (Al2O3) + Na3AlF6 + CaF2 

Answer»

(d) (Al2O3) + Na3AlF6 + CaF2

58.

 Loss of electrons from an element ‘X’ is represented by : X – 3e– → X3+ (X → X3+ + 3e–) X3+ formed is a _____ (cation / anion) and element ‘X’ has a valency of _____ [+2 /+3 / -3].

Answer»

X3+ formed is a cation and element ‘X’ has a valency of +3.

59.

 In the electrolysis of molten alumina, the carbon anode is gradually burnt away. Why ?

Answer»

In the electrolysis of molten aluminium oxide, oxygen gas is liberated which gradually bums away carbon anode at a higher temperature to form carbon dioxide. 

C + O2 ⟶ CO2.

60.

Loss of electrons from an element ‘X’ is represented by : X – 3e– → X3+ (X → X3+ + 3e–) If X3+ combines with oxygen the formula of the product is _____ (X2O3 / XO / X3O2 ),

Answer»

 If X3+ combines with oxygen the formula of the product is X2O3 .

61.

Loss of electrons from an element ‘X’ is represented by : X – 3e– → X3+ (X → X3+ + 3e–).The ion X3+ _____ (accepts / loses) electrons and gets _____ (oxidised / reduced) to neutral _____ (ions / atoms / molecules).

Answer»

 The ion X3+ loses electrons and gets reduced to neutral atoms.

62.

Loss of electrons from an element ‘X’ is represented by : X – 3e– → X3+ (X → X3+ + 3e–)If the above product in the _____ (solid/molten) state is electrolysed the ion X3+ will get discharged at the _____ (anode / cathode).

Answer»

If the above product in the molten state is electrolysed the ion X3+ will get discharged at the cathode. 

63.

The slag obtained during the extraction of copper pyrites is composed mainlt of `feSiO_(3)`

Answer» Correct Answer - T
64.

Redraw the given and label it correctly. Answer the questions given below : Explain the law on which this method is based.

Answer» This method is a based on the laow of gravitation, where in particles of the same size are seperated, by their weight with the help of water.
65.

Redraw the given diagram and label it correctly . Answer the question given below : In the abvoe process, name the two compoounds along with their molecular formula which are added in the mixture to lower its melting point.

Answer» The two compounds cryolite `(Na_(3)AlF_(6))` and Fluorspar `(CaF_(2))` are added in the mixture to lower its metling point up to `1000^(@)C`
66.

Redraw the diagram and label it correctly . Answer the question given below : What does the abvoe diatgram indicates

Answer» The above diagram indicates the process of Froth floatation method of conctrated by this method.
67.

What is concentration of ore ?

Answer» The process of separating gangue from the ore is called concetration of ore.
68.

___________ is the hardest natural substance.

Answer» Correct Answer - Diamond
69.

Metals react with Nitric acids to form _____________

Answer» Nitrate salts
70.

Non-metals combine with oxygen to form _____________

Answer» acidic oxides
71.

Describe some general method for the concentration of ore.

Answer» (i) Magnetic Seperation method :
(a) This method requires an electromagnetic machine.
(b) The main parts of this machine are two types of iron rollers and the converyor belt moving continously around them.
(c) One of the rollers in nonmagnetic while the other is electromagnetic.
(d) The conveyor belt movin around the rollers is (non magnetic) made up of leather or brass.
(e) the powdered ore is poured on the converyour belt near the nonmagnetic roller.
(f) Two collector vessles are placed below the magnetic roller.
(g) The particels of the nonmagnetic part in the ore are not attracted towards the magnetic roller.
(h) Therefore, they are carried further along the belt and fall in the collector vesslel near the magnetic roller.
(j) In this way the magnetic and nonmagnetic ingredients in the ore can be separated depending on their magnetic nature.
(k) It contains mainly the nonmagnetic ingredient stannic oxide `(SnO_(2))` and the magnetic ingredient ferrous tungstate `(FeWO_(4))`
(I) These are separated by the electromagnetic method.
(ii) Froth foatation method :
(a) The froth floatation, method is based on the two opposite properties, hydrophilic and hydrophobic, of the particles.
(b) Here the particles of the metal sulphides, due to their hydrophobic property, get wetteed mainly with oil, while due to the hydrophilic propery the gangue particles get wetted with water.
(c) By using these properties certian ores are concentrated by froth floatation method.
(d) In this, method, the finely gorund ore is put into a big tank containing ample amount of water.
(e) Certain vegetable oil such as pine oil, eucalyptus oil, is added in the water for the formation of froth.
(f) Pressurised air is blown through the water.
(g) There is an agitator rotating around its aixs in the centre of the floatation tank. the agitator is used as per the requrement. Bubbles are formed due to the blown air.
(h) Due to agitation, a foam is formed from oil, waterand air bubbles together. Dut to the agitating. thsi foam rises to the surface of water and floats. That is why thsi method is called froth floatation process.
(I) Particles of certain sulphide ore float with the foam on water as they preferentially get wetted by the oil. For Example thsi method is used for the concentration of zinc blend (ZnS) and copper pyrite `(CuFeS_(2))`.
(iii) Leaching :
(a) The first step in the extraction of the metals like aluminium, gold silver from their ores is the method of leaching.
(b) In this method the of leaching.
(b) In this method the ore is soaked in a certain solution for long time.
(c) The ore dissolves in that solution due to a specific chemical reaction
(d) The gandues does not react and therefore does not dissolve in that solution.
(e) So it can be separated. For example, concentration of bauxite, the aluminium ore is done by leaching method.
(f) Here, bauxite is soaked in aqueous `NaOH` ore aqueous `Na_(2)CO_(3)` whcih dissolves the main ingredient alumina in it.
72.

Gold and silver are used to make jewellery.

Answer» (i) Gold and silver are precious metals with attactive lustre.
(ii) They have low reactivity. They do react with atmospheric oxygen, moisture, carbon dioxie.
(iii) They do not react with dilute acids.
(iv) These metals are malleable and ductile.
(v) Diu to these properties gold and silver are used to make jewellery.
73.

Metals react with oxygen to form _____________

Answer» metal oxides
74.

A freshly prepared mixutre of concentrated HCl and concentrated `HNO_(3)` in the ratio of `3:1` is known is _____________

Answer» Correct Answer - Aqua Regia
75.

State the function of 1. NaOH 2. cryolite 3. fluorspar in the metallurgy of aluminium.

Answer»

Functions of : 

(i) NaOH : Crushed and powdered bauxite is heated with a cone, solution of NaOH at 150-200°C for 2 hours under pressure. The main impurities present in bauxite (Fe2O3 and SiO2) remain unaffected with cone. NaOH since these are not amphoteric. Bauxite, being amphoteric reacts with the base to form sodium aluminate, which is soluble in water. Thus NaOH helps in the purification of the ore. 

(ii) Cryolite : 

(a) To increase the mobility of the fused mixture. 

(b) To lower the fusion point of the mixture. 

(c) To increase the electrical conductivity of the mixture. 

(iii) Fluorspar : 

(a) To increase the mobility of the fused mixture

(b) To lower the fusion point of the mixture.

76.

Andizing is prcess of forming a thick layer of _____________

Answer» Aluminium oxide
77.

Redraw the given diagram and label it correctily. Answer the questions given below. : What is the result of ganue particles and ore particles in this process.

Answer» The result of this process is that the lighter gangue particles are carried away along with the flowing water, while the heavier particles of ore blocked by the wooden riffles and get collected on the slits between them.
78.

Give reasons for the following – pertaining to Hall Herault’s process.The fusion temperature of the electrolyte has to be lowered before conducting the electrolytic reduction.

Answer»

The liberated A1 metal [m.p. 660°C] may also tend to volatize out and get wasted. Hence the fusion temperature of the electrolytic mixture has to be – lowered.

79.

Redraw given diagram and label the parts. Completer the paragraph with the words given in the bracket : ( Heavier, ball mil, lighter slits,inclined, stream of water, vibrating)

Answer» In the method of seperation, Wilfley table is made by fixing narrow and thin wooden riffles on inclined surface. The table is kept vibrating continuously. Powdered ore obtained form lumps of the ore using abll mill is poured on the table, a strea of water is also realsed from the upper side. Ass a results, the lighter gangue particels are carried away along with the following water while the heavier particles in which particles in which proportion of minierals is more and proportion of gangue is less, are blocked by the wooden riffles and get collected on the slits between them.
80.

Ionic compounds are _____________ in nature.

Answer» Correct Answer - cystalline
81.

In spite of the addition of cryolite and fluorspar to alumina only `Al^(+3)andO^(-2)` ions are discharged at their respective electrodes. Justify.

Answer» Cryolite `(Na_(3)AlF_(6))` and fluorspar `(CaF_(2))` are added to alumina to reduce its melting point. `Al^(+3)` discharges preferentially over `Na^(+)andCa^(+3)` at cathode, because of lower discharge potential of `Al^(+3)` than `Na^(+)andCa^(+)` and at anode, `O^(-2)` gets discharged due to its lower discharge potential than `F^(-)` and is evolved as `O_(2)`, which reacts with carbon anode forming `CO_(2)` gas.
82.

Redraw the given diagram and label the parts. Complete the paragraph with the words given in the bracket : (gangue particles hydrophobic, oilwater, metal sulphides, hydrolphillic).

Answer» The froth floatation method is based on the two opposite propertis, hydrophilic and hydrophobic of the particles. Here the particles of metal sulphide due to their hydrophobic property, get wetted mainly with oil, while due to the hydrophilic property the gangue particles get wetted with water. By using theses properties certain ores are concentrated by forth floatation method.
83.

Give reasons for the following – pertaining to Hall Herault’s process.The constituents of the electrolyte in addition to one part of fused alumina contains three parts of cryolite and one part of fluorspar.

Answer»

 The reasons for addition of mainly cryolite [in a higher ratio] and fluorspar to the electrolytic mixture are : 

(a) They lowers the fusion point of the mixture i. e. the mixture fuses [melts] around 950°C instead of 2050°C. 

(b) They enhances the mobility of the fused mixture by acting as a solvent for the electrolytic mixture. Thus cryolite in the molten state of subdivision dissolves aluminium oxide. 

(c) Addition of cryolite enhances the conductivity of the mixture. Since pure alumina is almost a non-conductor of electricity.

84.

Redraw the given diagram and label the parts. Complete the paragraph with the words given in the bracket : ( heavy particles, Gangue particles, bottom lower, highter upper)

Answer» In hydraulic separation method, the finely ground ore is released in the tank.A forcefuly jet of water is introduced in the tankfrom the lower side. Gangue particles are lighter and thereofore they flow out along with the water jet from the outlet on the upper side of tank and get collected separately. at the same time the bottom from the lower side of the tank.
85.

Blister copper isA. pure copperB. ore of copperC. alloy of copperD. impure copper

Answer» Correct Answer - 4
Impure copper.
86.

The element which is recovered from electrolyte process is `:`A. ironB. leadC. aluminiumD. zinc

Answer» Correct Answer - 3
Al recovered by electrolytic process.
87.

What are the different methods used for removing gangue from ores? (OR) Write the five methods of concentration of ores.

Answer»

1. Wilfley table method 

2. Hydraulic separation method 

3. Magnetic separation method 

4. Froth floatation method 

5. Leaching method.

88.

State two methods of concentration of ores in which the heavy particles of ores can be separated from the light gangue particles by the gravitational method.

Answer»

1. Wilfley table method

2. Hydraulic separation method are two methods of concentration of ores in which the heavy particles of ores can be separated from the light, gangue particles by the gravitational method.

89.

Distinguish between:Roasting and Calcination.

Answer»

Roasting:

1. In this process, the ore is heated strongly in the presence of air. 

2. In this process, sulphide ore is converted into metal oxide. 

3. During this process SO2 is given out.

Calcination:

1. In this process, the ore is heated strongly in the limited supply of air. 

2. In this process, carbonate ore is converted into metal oxide. 

3. During this process CO2 is given out.

90.

Difference between calcination and roasting?

Answer»

Roasting : 

1. Ore is heated in the presence of air. 

2. Used generally for sulphide ores. SO2 gas is given off. 2ZnS+ 3O2 → 2ZnO + 2SO2 

3. Volatile impurities are removed as oxides. 

Calcination : 

1. Ore is heated in the absence of air. 

2. Hence Used generally for carbonate ores. Hence, CO2 gas is given off. ZnCO3 → ZnO + CO2

3. Moisture, organic impurities and volatile impurities are removed.

91.

The reactions given below represent the processes of reduction to obtain metals from their respective ores. Arrange them in the following order. Sodium, aluminium, zinc, chromium, iron, copper and mercry (1) Metal oxide + metal sulphide `to` Metal + `SO_(2)` (2) Metal oxide + CO `to` Metal + `CO_(2)` (3) Metal oxide + C `to` CO (4) Metal oxide `to` Metal + `O_(2)` (5) Meta oxide `overset(Delta)to` Metal + `O_(2)` (6) `"Metal oxide"+"Aluminium"to"Aluminium oxide"+"Metal"` (7) Metal chloride `to` Metal + ChlorinceA. 7 4 3 6 2 1 5B. 7 4 3 6 2 5 1C. 1 3 2 4 6 7 5D. 7 4 5 2 6 1 5

Answer» (i) Metal chloride `to` Metal + Chlorine
(ii) Metal oxide `to` Metal + `O_(2)`
(iii) Metal oxide + C `to` Metal + CO
(iv) `"Metal oxide"+"alumininm"to"aluminium oxide" +"metal"`
(v) `"Meta oxide"+COto"Metal"+CO_(2)`
(vi) `"Metal oxide"+"Metal suphide"to"Metal"+SO_(2)` (vii) `"Metal oxide"overset(Delta)to"Metal"+O_(2)`
92.

Metals can be recovered from their ores by chemical methods.

Answer» Correct Answer - T
93.

Which measures would you suggest to stop the corriosion of metallic articles or not to allow the corrosion to start ?

Answer» Various methods are used to protect metals from corrosion. To stop the corrosion of metallic articles , they should be kept isolated from a direct contact with air.
94.

Write three methods of preventing rusting of iron.

Answer»

1. The rusting of iron can be prevented by painting, oiling, greasing or varnishing its surface. 

2. Galvanisation is another method of protecting iron from rusting by coating iron with a thin layer of zinc. 

3. Corrosion of iron is prevented by coating iron with noncorrosive substance like carbon. This process is termed as alloying.

95.

The method chiefly used for the extraction of lead and tin from there oras are respectrively .A. self reduction and carbon reductionB. self reduction and elecyrolyic reductionC. carbon reduction and self reductionD. cyanide process and carbon reduction

Answer» Correct Answer - A
96.

What is the electronic definition of Oxidation and Reduction ?

Answer» Definition in terms of electrons transfer.
Oxidation means loss of electrons.
Reduction means gain of electrons.
97.

Explain the different methods to prevent corrosion of metals.

Answer»

(1) Corrosion of a metal can be prevented if the contact between metal and air is cut off. 

(2) Corrosion of a metal is prevented by coating with something which does not allow moisture and oxygen to react with it. 

(3) A layer of oil or paint or grease is applied on the surface of a metal to prevent corrosion. The rusting or corrosion of iron can be prevented by this method. 

(4) Corrosion is also prevented by coating a corrosive metal with a noncorrosive metal. Galvanising, tinning, electroplating, anodising and alloying are the different methods in which a metal is coated with a noncorrosive metal to prevent corrosion.

98.

What is meant by corrosion?

Answer»

Corrosion is degradation of a material due toreaction with its environment.

99.

State whether the following statements are True or False.i. Corrosion of metals can be stopped by detaching the air from metals.ii. Due to corrosion a greenish layer forms on the surface of copper or brass vessel.iii. Ionic compounds are soluble in kerosene.iv. Ionic compounds in the solid state conduct electricity.v. Mercury, silver and gold are very reactive metals.

Answer»

i. True.

ii. True.

iii. False. 

(Ionic compounds are soluble in water and insoluble in kerosene.)

iv. False. 

(Ionic compounds in the solid state do not conduct electricity.)

v. False. 

(Mercury, silver and gold are least reactive metals.)

100.

Chemical seqaration is one of the methods employed inA. dressing of oreB. concentration of oreC. extraction of metal from its oxideD. conversion ore to oxide

Answer» Chemical separation is one of the methods employed in concentration of ore.