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301.

Write scientific reason.Pine oil is used in the froth floatation process.

Answer»
  • In the concentration of an ore by froth floatation process, the ore is mixed with water and pine oil. When air is bubbled through the mixture a froth is formed.
  • The mineral particles in the ore are preferentially wetted by the oil and float on the top in the froth.
  • The gangue particles are wetted by water and settle down. Thus the mineral can be separated from the gangue and the ore is concentrated.
302.

Write scientific reason.Anodes need to be replaced from time to time during the electrolysis of alumina.

Answer»
  • During electrolysis of alumina, the oxygen liberated at the carbon anode reacts with graphite rods (carbon anode) and forms carbon dioxide.
  • As the anodes get oxidised during electrolysis of alumina, they are continuously eroded. Hence, it is necessary to replace anodes from time to time.
303.

When a copper coin is dipped in silver nitrate solution, a glitter appears on the coin after some time. Why does this happen? Write the chemical equation.

Answer»

When a copper coin is dipped in a silver nitrate solution, more reactive copper displaces silver from silver nitrate solution. The silver so liberated deposits on the copper coin. As a result, a shiny coat of silver is formed on the coin.

Cu(s) + 2AgNO3(aq) → Cu(NO3)2(aq) + 2Ag(s)

304.

Extraction of aluminium can be understood by : Electrolytric reduction of `Al_(2) O_(3)` : Electrolysis : `Al_(2) O_(3) + Cryolite + CaF_(2)` Cathode : Carbon inside the `Fe` container Anode : Graphite rods. The purpose of adding cryolite is.A. to decrease the electrical conductivity of pure aluminiumB. to lower the melting point of `AI_(2)O_(3)`C. to remove the impurities as slagD. to increase the `Al%` in the yield

Answer» Correct Answer - B
305.

Extraction of aluminium can be understood by : Electrolytric reduction of `Al_(2) O_(3)` : Electrolysis : `Al_(2) O_(3) + Cryolite + CaF_(2)` Cathode : Carbon inside the `Fe` container Anode : Graphite rods. The motion electrolytes contain `Na^(oplus),Al^(3+)` and `Ca^(2+)` but only `Al` gets deposited at cathode because,A. Standard reduction potential of `Al` is more than those of `Na & Ca`B. Standard oxidation potential of `Al` is more than those of `Na & Ca`C. Graphite reacts only with `Al^(3+)` and not with `Na^(+) & Ca^(2+)`D. Discharge potential of `Al^(3+)` is higher than `Na^(+) & Ca^(2+)`

Answer» Correct Answer - A
306.

Extraction of aluminium can be understood by : Electrolytric reduction of `Al_(2) O_(3)` : Electrolysis : `Al_(2) O_(3) + Cryolite + CaF_(2)` Cathode : Carbon inside the `Fe` container Anode : Graphite rods. The function of fluorspar `(CaF_(2))` is.A. to increase the melting point of electrolyteB. to increase electrolytic conductivity powerC. to remove the impurities as slagD. all of the above

Answer» Correct Answer - B
307.

(viii) Amongest the following groups of oxides, the group containing oxides that cannot be reducing by carbon to give the respective metals is.A. `Fe_(2)O_(3),ZnO`B. `PbO,Fe_(3)O_(4)`C. `Cu_(2)O,SnO_(2)`D. `CaO,K_(2)O`

Answer» (d) potassium and calcium are strong reductant hence their oxides cannot be reduced by carbon.
308.

The reactivity of metals with dil HCl in decreasing order is ___________A. `Mg gt Zn gt Al gt Fe`B. ` Mg gt al gt Zn gt Fe`C. `Fe gt Zn gt Al gt Mg`D. `Fe gt Al gt Zn gt Mg`

Answer» `Mg gt al gt Zn gt Fe`
309.

What is the nature of the oxides of metals ?

Answer» Oxides of metals are basic in nature.
310.

In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.(a) A and R are correct, R explains A (b) A and R are correct, R does not explains A (c) A is correct but R is wrong (d) A is wrong but R is correctAssertion(A) – Clay is an ore of aluminium while bauxite is not. Reason (R) – Aluminium can be economically extracted from bauxite not from clay.

Answer»

(d) A is wrong but R is correct

311.

Find out the incorrect pair:(a) Copper – Least reactive (b) Clay – Mineral of Al (c) Bauxite – Mineral of Al (d) Gangue – Impurity

Answer»

(c) Bauxite – Mineral of Al

312.

Sequence the following steps involved generally in the extraction of a metal in pure form from its ore, the extraction of a metal in pure form from its ore. (1) The metal obtained from its oxide requires further purification for end use. (2) The ore shoud be converted to its oxide form. (3) The ore is beneficial to us if it is hand-picked then metal crushed and ground, and later subjected to Pulverisation as per the requirement. (4) The ore in the form of oxide is required to be reduced. (5) Dressed ore is required for it to be concentrated.A. 5 3 2 4 1B. 3 5 2 4 1C. 3 5 2 1 4D. 3 5 4 2 1

Answer» (i) The ore is beneficial to us if it is hand-picked and then ore is crushed and grounded, and later subjected to Pulverisation as per the requirement.
(ii) Dressed ore is required to be concetrated.
(iii) Ore is required to be converted to its oxide form.
(iv) Ore in the form of oxide its oxide requires reduced.
(v) The metal obtained from its oxide requires further purification for end use.
313.

Bauxite has the composition ……………… (a) Al2O3(b) Al2O3 .nH3O (c) Fe2O3 .2H2O (d) None of these

Answer»

(b) Al2O3 .nH3

314.

Aluminium oxide is called an amphoteric oxide.

Answer» (i) An oxide which shows both acidic as well as basic properties is called and amphoteric oxide.
(ii) Metal oxides are usually basic in nature.
(iii) But some metal oxides like aluminium oxide, zinc oxide, etc, react both with acid as well as bases to produce salt and water.
(iv) Aluminium oxide shows both acidic as well as basic peroperties.
(v) Hence, aluminium oxide is called an amphoteric oxide
315.

___________ is an oxide which is amphoteric.A. Cooper oxideB. Magneiusm dioxideC. Zinc oxideD. Calcium oxide

Answer» Correct Answer - Zinc oxide
316.

State the chemical composition of Bauxite.

Answer» In Bauxite, Aluminium oxide `(Al_(2)O_(3). nH_(2)O)` is 30% to 70% while the reamaining portion is gangue made of silica, sand, iron oxide etc.
317.

`NaCN` is sometimes added in the froth flotation process as a depressant when `ZnS` and `PbS` minerals are expected because `:`A. `Pb(CN)_(2)` is precipitated whhile no effect on `ZnS`.B. `ZnS` forms solubel complex `Na_(2)[Zn(CN)_(4)]` while `PbS` forms froth.C. `PbS` froms soluble complex `Na_(2)[Pb(CN)_(4)]` while `ZnS` forms froth.D. `NaCN` is never added in froth floatation process.

Answer» Correct Answer - 2
`ZnS+4NaCNrarrNa_(2)[Zn(CN)_(4)]+Na_(2)S`
`PbS+NaCNrarr`No such complex formation
318.

In the extraction of copper, metal is formed in the Bessemer converter due to reactionA. `Cu_(2)S +2Cu_(2)O rarr 6Cu +SO_(2)`B. `Cu_(2)S rarr 2Cu +S`C. `Fe + Cu_(2)O rarr 2Cu +FeO`D. `2Cu_(2)O rarr 4Cu +O_(2)`

Answer» Correct Answer - A
319.

Select the stepe requried for the extraction of aluminium and sequence them. (1) froth flotation (2) chemical separation (3) electrolytic reduction (4) smelting (5) distillation under low pressure (6) electrolytic refining (7) Pulverisation (8) conversion of concentrated ore into oxide (9) crushing and grindingA. 9 5 7 2 3 8 6 1B. 3 2 1 4 5 6 7 8C. 9 7 2 8 3 6D. 9 7 2 3 8 6

Answer» (i) Crushing and grinding
(ii) Pulverisation
(iii) Chemical separation
(iv) Conversion of concentrated ore into oxide
(v) Electrolytic reduction
(vi) Electrolytic refining
320.

Why is it necessary to replace carbon anode from time to time in the electrolytic extraction of aluminium ?

Answer» (i) Reactions taking place at anode.
(ii) Electrolyte used in the extraction of alumininum.
(iii) Ions obtained.
(iv) Products obtained at the anode.
(v) Reaction between the product obtained and the anode.
321.

 The given sketch of an electrolytic cell used in the extraction of aluminium:(i) What is the substance of which the electrode A and B are made ? (ii) At which electrode (A ro B) is the aluminium formed ? (iii) What are the two aluminium compound in the electrolyte C ? (iv) Why is it necessary for electrode B to be continuously replaced ?

Answer»

 (i) Carbon (Graphite) 

(ii) A 

(iii) Aluminium oxide / Alumina / cryolite (sodium aluminium fluoride). 

(iv) Burns away in the presence of oxygen produced or consumed. 

322.

The given figure illustrates the refining of aluminium by Hoope’s process. (i) Which of A and B is the cathode and which one is the anode ? (ii) What is the electrolyte in the tank ? (iii) What material is used for the cathode ?

Answer»

(i) A—Cathode, B—Anode. 

(ii) Mixture of fluorides. 

(iii) Graphite

323.

Write the reactions occuring at cathode and anode.

Answer» The electrons reaction are as follows :
Anode reaction `-Ag to Ag^(+) +e^(-)`
Cathode reaction `-Ag^(+)+w^(-) to Ag`
324.

What can you say about the reactivity of metals at anode and cathode.

Answer» The reactivity of metal at anode is less thant the reactivitiy of metal at cathode.
325.

Silver is purified by distillation process

Answer» Correct Answer - F
326.

Impure nickel can be purified byA. electrolytic refiningB. Mond-carbonyl processC. zone-refining processD. van-arkel process

Answer» (b) Mond-carbony! Process is used to purify impure Ni.
327.

The reagent that dissolves noble metals.

Answer» Correct Answer - Aqura regia
328.

In _____________ process sulphide ores are strongly heated.

Answer» Correct Answer - Roasting
329.

Explain the following reactions with the help of balanced equation:Chlorine is treated with hydrobromic acid.

Answer»

When chlorine is treated with hydrobromic acid, chlorine displaces bromine from hydrobromic acid.

Cl2(g) + 2HBr(aq) → 2HCl(aq) + Br2(aq)

330.

Extraction of copper from its sulphide ore.

Answer» `{:(2Cu_(2)S,+,3O_(2),to, 2Cu_(2)O, +, 2SO_(2) uarr),("Copper",,"Oxygen",,"Copper",,"Sulphur"),("Sulphide",,,,"oxide",,"dioxide"),(2Cu_(2)O,+, Cu_(2)S, to, 6Cu,+,SO_(2) uarr),("Copper",, "Copper",,"Copper",,"Sulphur"),("oxide",,"sulphide",,,,"dioxide"):}`
331.

Zinc oxide is dissolved in diute hydrochloric acid.

Answer» When zinc oxide dissolves in dilute hydrochoric acid, zinc chloride and water is formed.
`underset("Oxide")underset("Zinc")(ZnO)+underset("Acid")underset("Hydrochloric")(2HCl)to underset("Chloride")underset("Zinc")(ZnCl_(2))+underset("Water")(H_(2)O)`
332.

State two metals which can be cut easily with a knife.

Answer»

Sodium and potassium are soft metals and can be cut easily with a knife.

333.

The process employed for the purification of copper with cuprous oxide as the impurity isA. pollingB. liquationC. electrolytic processD. oxidation

Answer» Correct Answer - A
334.

The reaction that is not asscoiated with the middle region of blast furnace during smelting is ______.A. `CO_(2)+Cto2CO`B. `CaCO_(3)toCaO+CO_(2)`C. `CaO+SiO_(2)toCaSiO_(3)`D. `C+O_(2)toCO_(2)`

Answer» `C+O_(2)toCO_(2)`. This reaction takes plance in the lower region of blast furnace.
335.

Which of the following process involves smeltingA. `2PbS +3O_(2) rarr 2PbO + 2SO_(2) uarr`B. `AI_(2) O_(3).2H_(2)O rarr AI_(2)O_(3) + 2H_(2)O`C. `Fe_(2)O_(3) +CO rarr 2Fe +2CO_(2)`D. `Cr_(2)O_(3) + 2AI + AI_(2) O_(3) +2Cr +Heat`

Answer» Correct Answer - C
336.

Fill in the blanks: 1. Magnesite is calcined to give …………… 2. …………… a chemical substance that forms an easily fusible slag with gangue. 3. Flux + Gangue → …………… 4. In the extraction of iron …………… is removed as slag. 5. In the extraction of copper …………… is removed as slag. 6. Cr O can be reduced by …………… an process. 7. …………… is used as a reducing agent for the reduction of chromic oxide. 8. …………… is purified by zone refining. 9. In the mond process, impure nickel is heated with …………… compound. 10. …………… filament is used to decompose.

Answer»

1. Magnesia 

2. Flux 

3. slag 

4. Calcium silicate (CaSiO3

5. Ferrous silicate (FeSiO3

6. Aluminothermic process 

7. Aluminium 

8. semi-conductior 

9. carbon monoxide 

10. Tungsten

337.

Fill in the Blanks:1. …………… is the most abundant metal. 2. …………… is used in packing materials for food items.3. …………… is used in the manufacture of paints, rubber and cosmetics. 4. …………… is the first metal used by the humans. 5. …………… is one of the expensive and precious metals. 6. …………… is used for increasing the efficiency of solar cells and also used as catalysts. 7. …………… ore is concentrated by froth floatation process. 8. Zinc blende is concentrated by …………… process. 9. Gold ore is leached by adding of ……………

Answer»

1. Aluminium 

2. Aluminium foils 

3. Zinc oxide 

4. Copper 

5. Gold 

6. Gold nanoparticle  

7. Sulphide

8. Froth floatation

9. NaCN

338.

Match the following:(i) Haematite (a) Fe3O4(ii) Siderite(b) Fe3O3(iii) Iron pyrite(c) Fe3O3(iv) Magnetite(d) FeS2

Answer»

(i) – (b) 

(ii) – (c) 

(iii) – (d) 

(iv) – (a)

339.

Match the following:(i) Copper glance(a) CuCO3 . Cu(OH)2(ii) Malachite(b) Cu2S(iii) Copper pyrite(c) 2CuCO3. Cu(OH)2(iv) Azurite(d) CuFeS2

Answer»

(i) – (b) 

(ii) – (a) 

(iii) – (d) 

(iv) – (c)

340.

Match the following :(i) Copper glance(a) CuCO3 . Cu(OH)2(ii) Malachite(b) Cu2S(iii) Copper pyrite(c) 2CuCO3 . Cu(OH)2(iv) Azurite(d) CuFeS2

Answer»

(i) – (b) 

(ii) – (a) 

(iii) – (d) 

(iv) – (c)

341.

Copper glance is...........type of ore-A. CarbonateB. SulphidesC. OxideD. Sulphate

Answer» Correct Answer - B
Copper glance, chemical formula is `Cu_(2)S`.
342.

What is meant by amalgam?

Answer»

The amalgam is an alloy in which one of the metals is mercury.

343.

High purity copper is obtained byA. Zone refiningB. PolingC. Electrolytic refiningD. Cupelling

Answer» Correct Answer - C
After electrlytic refining. Purity of copper is `99.99%` which is enough for electrical applications.
344.

State the term used to express the purity of gold.

Answer»

The purity of gold is expressed in carat.

345.

What are the constituents of bronze?

Answer»

Copper and tin are the constituents of bronze.

346.

Select the correct answer from A, B, C and D. The two main metals in Bronze are : (A) Copper and zinc (B) Copper and lead (C) Copper and nickel (D) Copper and tin

Answer»

The two main metals in Bronze are Copper and tin.

347.

ldentify the term in the following : “The method used to separate ore from gangue by preferential wetting.” 

Answer»

Froth flotation process.

348.

A strip of copper is placed in four different colourless salt solutions. They are KNO3 , AgNO3 , Zn(NO3 )2 , Ca(NO3)2 . Which one of the solutions will finaky turn blue. 

Answer»

Silver Nitrate (AgNO3).

349.

Sulfide ores are common for the metals.A. `Ag,Cu` and `Pb`B. `Ag,Cu` and `Zn`C. `Ag,Mg` and `Pb`D. `Al,Cu` and `Pb`

Answer» Correct Answer - A
350.

Statement I Nitrate ores are very rar. statement II Bond dissociation energy of `N_(2)` is very high Which of these statement (s) is`//`are true ?A. Only IB. Only IIC. Neither (a) nor (b)D. Both (a) and (b)

Answer» Correct Answer - (d)