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51.

Which of the following relation is correct ? (where `T_(i)` = Inversion temperature, `T_(c)` = Critical temperature)A. `T_(c) = 6.75 T_(i)`B. `T_(i) = 6.75 T_(c)`C. `T_(i) gt 6.75 T_(c)`D. `T_(c) gt 6.75 T_(i)`

Answer» Correct Answer - B
52.

Which of the following curves represents the chemical adsorption ?A. B. C. D.

Answer» Correct Answer - C
53.

Select the wrong statement among the following:A. Orbital angular momentum `= sqrt(l(l+1))(h)/(2pi)`B. Resultant angular momentum and resultant magnetic moment are in same directionC. Resultant angular momentum and resultant magnetic moment are in opposite directionD. Orbital angular momentum has (2l+1) orientations

Answer» Correct Answer - B
54.

Which of the following is not correctly matched ?A. `{:("Molecule",("d-orbital present in the hybrid orbitals"),),(SF_(4),sp^(3)d" " (d_(z^(2))),):}`B. `{:("Molecule",("d-orbital present in the hybrid orbitals"),),(IF_(5),sp^(3)d^(2)" " (d_(x^(2)-y^(2)), d_(z^(2))),):}`C. `{:("Molecule",("d-orbital present in the hybrid orbitals"),),(XeF_(6),sp^(3)d^(3)" " (d_(xy),d_(yz),d_(zx)),):}`D. `{:("Molecule",("d-orbital present in the hybrid orbitals"),),(XeF_(2),sp^(3)d" " (d_(x^(2))-d_(y^(2))),):}`

Answer» Correct Answer - D
55.

Which of the following is most soluble in water ?A. LiIB. NaIC. KID. RbI

Answer» Correct Answer - A
56.

Which of the following sulphates will be insoluble in water due to high lattice energy?A. `BaSO_(4)`B. `BeSO_(4)`C. `Na_(2)SO_(4)`D. `K_(2)SO_(4)`

Answer» Correct Answer - A
57.

Match the following: `{:(" Set I",," Set II"),("A. 10 Vol " H_(2)O_(2),,"1. per hydrol"),("B. 20 Vol " H_(2)O_(2),,"2. 5.358 N"),("C. 30 Vol " H_(2)O_(2),,"3. 1.785 M"),("D 100 Vol " H_(2)O_(2),,"4. 3.03%):}` The correct match is :A. A-4, B-3, C-2, D-1B. A-1, B-2, C-3, D-4C. A-1, B-3, C-2, D-4D. A-4, B-2, C-3, D-1

Answer» Correct Answer - A
58.

Which of the following will weigh less in presence of external magnetic field ?A. `Cr_(24)`B. `Mn_(29)`C. `Co_(27)`D. `Zn_(30)`

Answer» Correct Answer - D
59.

The volume strength of `10 N H_(2)O_(2)` is :A. 112B. `11.2`C. `0.112`D. 56

Answer» Correct Answer - D
60.

The rms speed at NTP of a gas can be calculated from the expression:A. `sqrt(3P//d)`B. `sqrt(3PV//M)`C. `sqrt(3RT//M)`D. `sqrt(3d//P)`

Answer» Correct Answer - A::B::C
61.

What will be the volume strength of molar solution of `H_(2)O_(2)` ?A. `5.6`B. `22.4`C. `11.2`D. `10.4`

Answer» Correct Answer - C
62.

For diatomic molecules, the correct relation is/areA. `C_(P) = 7//2R`B. `C_(V) = 5//2 R`C. `gamma = 1.4`D. `C_(P) = 3//2 R`

Answer» Correct Answer - A::B::C
63.

`BrCl_(3)` molecule involves `(sp^(3)d)` hybridization, the d-orbital contributing this hybridization will be :A. `d_(xy)`B. `d_(yz)`C. `d_(x^(2)-y^(2))`D. `d_(z^(2))`

Answer» Correct Answer - C
64.

All these molecules have `sp^(3)` hybridization, select the molecule in which all the bond do not have same percentage (s) character:A. `CH_(4)`B. `C Cl_(4)`C. `NH_(3)`D. `C Cl_(2)F_(2)`

Answer» Correct Answer - D
65.

In `PCl_(3)F_(2)` molecules, select the correct statement about two (P-F) bonds:A. Both (P-F) bonds are equatorialB. Both (P-F) bonds are axialC. One (P-F) bond is axial and one (P-F) bond is equatorialD. can not be predicted

Answer» Correct Answer - B
66.

`PCl_(5)` molecule involves `(sp^(3)d)` hybridization, the d-orbital contributing this hybridization will be :A. `d_(xy)`B. `d_(yz)`C. `d_(zx)`D. `d_(z^(2))`

Answer» Correct Answer - D
67.

An ideal gas is taken from the state A (pressure P, volume V) to the state B (pressure P/2, volume 2V) along a straight line path in the P-V diagram. Select the wrong statement from the following: A. The work done by the gas in the process A to B exceeds the work that would be done by if the system were taken from A to B along the isotherm.B. In the T-V diagram, the path AB becomes a part of parabola.C. In the P-T diagram, the path AB becomes a part of hyperbola.D. In going from A to B, the temperature T of the gas first increases to a maximum value and then decreases.

Answer» Correct Answer - C
68.

A sample of `2kg` of helium (assumed ideal) is taken through the process `ABC` and another sample of `2kg` of the same gas is taken through the process `ADC`. Then the temperature of the states `A` and `B` are (given `R = 8.3J mol^(-1)K^(-1))` A. `T_(A) = 120.5K, T_(B) =120.5K`B. `T_(A) = 241K, T_(B) =241K`C. `T_(A) = 120.5K, T_(B) = 241 K`D. `T_(A) = 241K, T_(B) = 482K`

Answer» Correct Answer - C
69.

A solid is formed by three elements X,Y and Z, X atoms form a fcc lattice with Y atoms occupying all tetrahedral voids. Z atoms occupying half the octahedral voids. The formula of the solids is :A. `X_(2)Y_(4)Z`B. `XY_(2)Z_(4)`C. `X_(4)Y_(2)Z`D. `X_(4)YZ_(2)`

Answer» Correct Answer - A
70.

Which of the following pairs is correctly matched ?A. `{:("Experimental","Phenomenon"),("X-ray spectra","Charge on the nucleus"):}`B. `{:("Experimental","Phenomenon"),(alpha-"particle scattering","Quantized electron orbit"):}`C. `{:("Experimental","Phenomenon"),("Emission spectra","Qunatization of energy"):}`D. `{:("Experimental","Phenomenon"),("The photoelectric effect","The nuclear atom"):}`

Answer» Correct Answer - C
71.

Which of the following represents zero order reaction ?A. B. C. D.

Answer» Correct Answer - A
72.

Which of the gas can displace remaining all the gases from the surface of adsorbent ?A. COB. `H_(2)`C. `O_(2)`D. `N_(2)`

Answer» Correct Answer - A
73.

Which of the following is an example of associated colloid ?A. Protein + WaterB. Soap + WaterC. Rubber + BenzeneD. `As_(2)O_(3)+Fe(OH)_(3)`

Answer» Correct Answer - B
74.

Which of the following figure represents the variation of particle momentum and the associated de - Broglie wavelength ?A. B. C. D.

Answer» Correct Answer - D
75.

The plot of log V against log P at constant temperature for a fixed mass of gas is :A. B. C. D.

Answer» Correct Answer - B
76.

In the sequence of reaction, `L overset(k_(1))rarr M overset(k_(2))rarr N overset(k_(3))rarrO` `k_(3) gt k_(2) gt k_(1)` The rate determining step of the reaction is :A. `L rarr M`B. `M rarr N`C. `N rarr O`D. `L rarr O`

Answer» Correct Answer - A
77.

`pH` of a `0.1 M` monobasic acid is found to be `2`. Hence, its osmotic pressure at a given temperature T K isA. 0.1 RTB. 0.11 RTC. 1.1 RTD. 0.01 RT

Answer» Correct Answer - B