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101.

One mole of `PCl_(3)` is dissolved in excess of water. No. of moles of NaOH required to neutralise this solution completely is

Answer» Correct Answer - 5
`PCl_(3) + 3H_(2)O rarr ubrace(H_(3)PO_(3))_("(dibasic)") + 3HCl " " :.` Total 5 moles of NaOH required
102.

Which is greater for `P_(4)` (white) tan `P_(4)` (red)A. Molar entropyB. Melting pointC. Solubility in `CS_(2)`D. Ignition temperature

Answer» Correct Answer - A::C
Factual
103.

Dinitrogen gas is evolved when sodium nitrite is heated below `500^(º)C`A. aloneB. with ammonium chlorideC. with sodium chlorideD. with potassium nitrate

Answer» Correct Answer - B
104.

Which statement is not correct for nitrogen?A. It is obtained by heating `(NH_(4))_(2) Cr_(2)O_(7)`B. It does not readily react with `O_(2)`C. It is a typical non-metalD. d-orbitals are available for bonding

Answer» Correct Answer - D
105.

Which of the following have `Delta H_(f)^(º) lt 0`A. OzoneB. O(g)C. P(red)D. `S_(8)` (monoclinic)

Answer» Correct Answer - C
106.

The anhydride of nitric acid isA. nitric oxideB. nitrous oxideC. dinitrogen trioxideD. dinitrogen pentoxide

Answer» Correct Answer - D
107.

Which of the following is a mixed acid anhydride ?A. NOB. `NO_(2)`C. `N_(2)O_(5)`D. `N_(2)O`

Answer» Correct Answer - B
108.

When ammonia is oxidsed by oxygen in the presence of platinum at `800^(@)C`, the gas obtained is :A. `N_(2)O`B. NOC. `NO_(2)`D. `N_(2)O_(5)`

Answer» Correct Answer - B
109.

Substances burn more readily in `N_(2)O` than in air because `N_(2)O`:A. is reactive at high temperatureB. dissociates to give more nitrogen than in airC. the activation energy is increased on increasing temperatureD. dissociates more readily than `O_(2)`

Answer» Correct Answer - D
110.

Sulphur on boiling with `NaOH` solution givesA. `Na_(2)S_(2)O(3) + NaSO_(3)`B. `Na_(2)S_(2)O_(3) + Na_(2)S`C. `Na_(2)SO_(3) + H_(2)S`D. `Na_(2)SO_(3) + SO_(2)`

Answer» Correct Answer - B
`3S + 6NaOH rarr 3H_(2)O + 2Na_(2)S + Na_(2)SO_(3)`
111.

Nitrolim is obtained by passing nitrogen over:A. heated mixture of `Al_(2)O_(3)` and carbonB. oleumC. calcium carbideD. heated calcium carbide

Answer» Correct Answer - D
112.

Which among the following is/are peroxo acid (s) ?A. `H_(2)S_(2)O_(3)`B. `H_(2)SO_(3)`C. `H_(2)S_(2)O_(7)`D. `H_(2)S_(2)O_(8)`

Answer» Correct Answer - B::D
113.

Which of the following cannot dissociated as `PX_(5) hArr PX_(3) + X_(2)`A. `PF_(5)`B. `PCl_(5)`C. `PBr_(5)`D. `PI_(5)`

Answer» Correct Answer - A
114.

The aqeous solution of hydrogen peroxide:A. converts blue litmus pinkB. converts blue litumus whiteC. converts red litumus blueD. None of these

Answer» Correct Answer - B
115.

What happens when: ltbr (a) `NH_(4) Cl " & " NaNO_(3)` is heated strongly (b) `(NH_(4))_(2) CO_(3)` is heated. (c) `NH_(4) NO_(2)` is heated.

Answer» (a) `NH_(4)Cl + NaNO_(3) rarr NH_(4) NO_(3) + NaCl , NH_(4) NO_(3) overset(Delta)rarr N_(2)O + 2H_(2)O`
(b) `(NH_(4))_(2) CO_(3) overset(Delta)rarr 2NH_(3) + CO_(2) + H_(2)O` (c) `NH_(4) NO_(2) overset(Delta)rarr N_(2) + 2H_(2)O`
116.

Sulphuric acid reacts with `PCl_5` to giveA. Thionyl chlorideB. Sulphur monochlorideC. Sulphuryl chlorideD. Sulphur tetrachloride

Answer» Correct Answer - C
`2PCl_(5) + H_(2)SO_(4) rarr SO_(2)Cl_(2) + 2POCl_(3) + 2HCl`
117.

Thermodynamically most stable allotrope of phosphorus is :A. RedB. WhiteC. BlackD. Yellow

Answer» Correct Answer - C
118.

Phosphorus trichloride, `PCl_(3)` undergoes, hydrolysis at room temperature to produce an oxoacid. It has the formula :A. `HPO_(3)`B. `H_(3)PO_(3)`C. `H_(3)PO_(4)`D. `H_(3)PO_(2)`

Answer» Correct Answer - B