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101.

4-chloro-2-ethyl 1-butene

Answer» `{:(ClCH_(2)CH_(2)C=CH_(2)),(" "|),(" "CH_(2)CH_(3)):}`
102.

`{:(" "CH_(2)CHO),(" "|),(CH_(3)-C-Cl),(" "|),(" "CH_(3)):}`

Answer» 3-chloro-3-methylbutanal
103.

1-chloro-5-methyl-2-hexanone

Answer» `CH_(3)underset(CH_3)underset(|)CHCH_(2)CH_(2)-underset(O)underset(||)C-CH_(2)Cl`
104.

1-chloro-2-propanal

Answer» `CH_(3)-underset(OH)underset(|)CHCH_(2)Cl`
105.

2-methyl-3-phenylpentanoic acid

Answer» `CH_(3)CH_(2)-underset(C_(6)H_(5))underset(|)CHoverset(CH_(3))overset(|)CHCOOH`
106.

`C_(6)H_(5)CH=CH-CO-C_(6)H_(5)`

Answer» 1,3-diphenyl-2-propen-1-one
107.

`CH_(2)=CHCOOH`

Answer» Correct Answer - Propenoic acid
108.

`{:(" "CH_(2)CHO),(" "|),(CH_(3)-C-Cl),(" "|),(" "CH_(3)):}`

Answer» 3-chloro-3-methylbutanal
109.

3-(1-chloroethyl)-4-methyl-4-phenyl-2-pentanone

Answer» `{:(" "C_(6)H_(5)" "O),(" "|" "||),(CH_(3)-C-CH-C-CH_(3)),(" "|" "|),(" "H_(3)C" "CHCl),(" "|),(" "CH_(3)):}`
110.

1,2,3-trichlorobutane

Answer» `CH_(2)Cl-CHCl-CHCl-CH_(3)`
111.

2,2,4-trimethylpentane

Answer» `CH_(3)underset(CH_(3))underset(|)(C)HCH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(3)`
112.

3,3,5-trimethylheptane

Answer» `CH_(3)underset(C_(2)H_(5))underset(|)(CH)-CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)CH_(3)`
113.

1-phenyl-1-paropanol

Answer» `C_(6)H_(5)-underset(OH)underset(|)"C"CH_(2)CH_(3)`
114.

1-bromo-2,2-dimetylpropane

Answer» `CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)Br`
115.

1,2-dibromo-3-hchlorobutane

Answer» `CH_(2)Br-CHBr-CHCl-CH_(3)`
116.

5-ehyl-2,2-dimthylheptane

Answer» `{:(" "CH_(3)),(" "|),(CH_(3)-"CC"H_(2)CH_(2)CHCH_(2)CH_(3)),(" "|" "|),(" "CH_(3)" "CH_(2)CH_(3)):}`
117.

`Cl-underset(Cl)underset(|)overset(Cl)overset(|)(C)-COOH`

Answer» 2,2,2-tricholoroethanoic acid
118.

`{:(CH_(2)=C-CH_(2)CH_(3)),(" "|),(" "HC-CH_(3)),(" "|),(" "CH_(3)):}`

Answer» 2-enthy1-3methly1-1-butene
119.

2-methyl-2-paropanol

Answer» `CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-OH`
120.

`CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-C-=N`

Answer» 2,2-dimethylpropaneitrile
121.

`CH_(2)=CH-CH=CH-CH=CH_(2)`

Answer» Correct Answer - 1,3,5-hexatriene
122.

`CH_(2)=CH-C-=C-underset(CH_(3))underset(|)(C)HCOOH`

Answer» 2-methyl-5-hexen-3-ynoic acid
123.

3-bromo-1,3,5-hexatriene

Answer» `CH_(2)=CH-overset(Br)overset(|)C=CH-CH=CH_(2)`
124.

Which of the following statements `is//are` correct?A. Homologous series can be represented by a general formula.B. The chemical properties of an organic compound depend on the funcitonal group.C. Groups obtained by the removal of one `H` atom from the alkane are called alky1 group.D. Alkynes consist of one doulbe-bond in their molelues.

Answer» Correct Answer - A::B::C
`(a),(b),and (c ) are self-explanatory.
(d) is wrong, alkyne consists of one triplebond.
125.

`(CH_(3))_(2)-overset(OH)overset(|)(C)-CH_(2)-COCH_(3)`

Answer» 4-hydroxy-4-methyl-2-pentanone
126.

`H_(3)overset(4)C-overset(O)overset(||)overset(3" ")(C)-overset(2)CH_(2)-overset(O)overset(||)overset(1" ")(C)-OH`

Answer» Correct Answer - 3-oxobutanoic acid
127.

2-ethyl-1-hexene

Answer» `CH_(3)CH_(2)CH_(2)CH_(2)underset(CH_(2))underset(||)"CC"H_(2)CH_(3)`
128.

3-methyl -2-butenoic acid

Answer» `CH_(3)-underset(CH_(3))underset(|)(C)=CH-COOH`
129.

4-methoxy-2-butenoic acid

Answer» `CH_(3)OCH_(2)CH=CHCOOH`
130.

2-methly-2-butenoic acid

Answer» `CH_(3)-underset(CH_(3))underset(|)(C)=CH-CH_(3)`
131.

1,3-dichloro-2-butenoic acid

Answer» `ClCH_(2)underset(OH)underset(|)(C)HCH_(2)Cl`
132.

1-ethoxypropan

Answer» `CH_(3)CH_(2)CH_(2)OCH_(2)CH_(3)`
133.

pentane-2,4-bione

Answer» `CH_(3)-CO-CH_(2)-CO-CH_(3)`
134.

1-ethoxypropan-1-ol

Answer» `CH_(3)-CH_(2)O-overset(OH)overset(|)(CH)-CH_(2)-CH_(3)`
135.

1-bromo-3-methoxypropane

Answer» `CH_(3)OCH_(2)CH_(2)CH_(2)Br`
136.

3-penten-1-ol

Answer» `CH_(3)-CH=CHCH_(2)CH_(2)OH`
137.

5-amino-3-methylhexanoic acid

Answer» `{:(CH_(3)-CHCH_(2)CHCH_(2)COOH),(" "|" "|),(" "NH_(2)" "CH_(3)):}`
138.

1-penten-3-one

Answer» `CH_(2)=CH-overset(O)overset(||)C-CH_(2)CH_(3)`
139.

4-methyl-3-pentenal

Answer» `CH_(3)-underset(CH_(3))underset(|)C=CHCH_(2)CHO`
140.

In which of the following reactions, the principal group loses its preferences? A. IB. I, IIC. I, II, IIID. I,II

Answer» Correct Answer - B
I. The principal group `(-COOH)` is lost.
II. Same as is `(I)`
III. One `(-COOH)` group is lost, but still one `(- COOH)` group is left in the product.
141.

Draw the formulae for the first five numbers of each homologous series beginnig with the following compounds: a. `H - COOH` b. `CH_(3) COCH_(3)` c. `H - CH = CH_(2)`

Answer» a. `H.COOH` (Methamoic acid)
ii. `CH_(3) COOH` (Ethanoic acid)
iii. `CH_(3) CH_(2) COOH` (Propanoic acid)
iv. `CH_(3) CH_(2) CH_(2) COOH` (Butanoic acid)
v. `CH_(3) CH_(2) CH_(2) CH_(2) CH_(2) COOH` (Pentanic acid)
b. i. `CH_(3) - CO - CH_(3)` (Propanone)
ii. `CH_(3) - CO - CH_(2) CH_(3)` (Bultan-2-one)
iii. `CH_(3) - CO - CH_(2) CH_(2) CH_(3)` (Pentuan-2-one)
iv. `CH_(3) COC_(4) H_(9)` (Hexan-2-one)
v. `CH_(3) = COC_(5) H_(11)` (Heptan-2-one)
c. i. `CH_(2) = CH_(2)` (Ethene)
ii. `CH_(3) CH_(2) CH = CH_(2)` (Propene)
iii. `CH_(3) CH_(3) CH = CH_(2)` (But-1-ene)
iv. `CH_(3) CH_(2) CH_(2) CH = CH_(2)` (Pent-1-ene)
v. `CH_(3) - CH_(2) - CH_(2) - CH_(2) - CH = CH_(2)`
(Hex-1-ene)]
142.

The decreasig order of priority for the following functional groups is: I.`-OH` II gt `-C -= C-` III. IV. `-NH_(2)`A. `(IV) gt(I)gt(II)gt(III)`B. `(IV)gt(I)gt(III)gt(II)`C. `(I)gt(II)gt(IV)gt(III)`D. `(I)gt(III)gt(IV)gt(I)`

Answer» Correct Answer - C
(For priority order, see sectio 1.5.6)
143.

Which of the following statements `is//are` correct?A. The common name of `(HOOC - CH_(2) - COOH)` is malonic acid.B. The common name of is succinic acid.C. The `IUPAC` name of `(CH_(2) = CH - OCOCH_(3))` is viny1 acetate.D. The `IUPAC` name of acrylonitrile is Prop-2-ene-nitrile.

Answer» Correct Answer - A::B::D
(c ) Viny1 ethanoate.
144.

Which of the following statements `is//are` correct?A. The `IUPAC` name of amy1` alcohol is pentanol.B. The `IUPAC` name of isoamy1 alcohol is 3-methy1 butanol.C. Wood spirit is methanol.D. Methy1 acohol is also called carbino1

Answer» Correct Answer - A::B::C::D
All statements are self-explanatory.
145.

Assertion `(A)` : Pentane and 2-methy1 pentane are homolo-gues. Reason `(R )`: Pentane is a straight-chain alkane, while 2-methy1 pentane is a branched-chain alkane.A. If both `(A)` and `(R )` are correct and `(R )` is the correct explanation for `(A)`.B. If both `(A)` and `(R )` are correct and `(R )` is not the correct explanation.C. If `(A)` is correct and `(R )` is incorrect.D. If both `(A)` and `(R )` are incorrect.

Answer» Correct Answer - B
Both `(A)` and `(R )` are correct but `(R )` is not the correct explanation for `(A)`.
146.

Which of the following statements is wrong for homologus series?A. All members have a general formula.B. All members have the same functional group.C. All memberss have the same chemical properties.D. All members have the same physical properties.

Answer» Correct Answer - D
The statement is self explanatory.
147.

2-ethoxy-1-ethoxy-1-ethanol

Answer» `CH_(2)H_(5)OCH_(2)CH_(2)OH`
148.

1-phenyl-2-paropanol

Answer» `C_(6)H_(5)CH_(2)underset(OH)underset(|)"C"HCH_(3)`
149.

`CH_(3)CH_(2)CH=CHCOOH`

Answer» Correct Answer - 2-pentenoic acid
150.

4-chloro-2-pentyne

Answer» `CH_(3)-C-=C-underset(Cl)underset(|)CH-CH_(3)`