InterviewSolution
This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
What are Redox Reactions? |
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Answer» Redox reactions are those chemical reactions in which both oxidation as well as reduction occur simultaneously.
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| 2. |
Define Redox reactions. |
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Answer» Reactions which involve change in oxidation number of the interacting species. |
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| 3. |
Which of the following statements regarding redox reactions is incorrect? a. Oxidation is the process of loss of electrons by a chemical species ( atom, ion or molecule). b. Reduction is the process of gain of electrons by an atom, ion or molecule. c. A reducing agent is one that undergo reduction d. A reducing agent gives electrons; |
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Answer» (c) A reducing agent is one that undergo reduction is incorrect. |
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| 4. |
Suggest a scheme of classification of the following redox reactions. N2(g) + O2 (g)----------> 2 NO (g) |
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Answer» The compound nitric oxide is formed by the combination of the elemental substances, nitrogen and oxygen; therefore, this is an example of combination redox reactions. |
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| 5. |
Suggest a scheme of classification of the following redox reactions.2Pb(NO3)2(s)--------> 2PbO(s) + 2 NO2(g) + ½ O2(g) |
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Answer» The reaction involves the breaking down of lead nitrate into three components; Therefore, this is categorized under decomposition redox reaction. |
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| 6. |
Determine the oxidation number of all the atoms in the well known oxidants KClO4. |
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Answer» K = +1, Cl = +7, O = -2 |
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| 7. |
In the reaction MnO2 + 4HCl → MnCl2 + 2H2O +Cl2Which of the following species acts as reducing agent?a) MnO2b) HClc) Cl-d) None of the above |
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Answer» c) Cl- species acts as reducing agent. |
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| 8. |
Give an example of photodecomposition reaction? |
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Answer» Decomposition of silver bromide in the presence of light. |
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| 9. |
What are the minimum and maximum Oxidation Number of Cl in its compounds? |
| Answer» Minimum -0, maximum- +7 | |
| 10. |
What is the oxidation number of an atom in the elemental state? |
| Answer» Zero is the oxidation number of an atom in the elemental state. | |
| 11. |
The half cell reaction with their oxidation potentials arePb(s) → Pb2+(aq) + 2e-; E°cell = + 0.13VAg(s) → Ag(aq) + e-; E°cell = -0.80VWrite the cell reaction and calculate its EMF. |
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Answer» Rewrite the two equations in the reduction form thus. Pb2+(aq) + 2eE– → Pb(s); E° = -0.13V ...(i) Ag+(aq) + e– → Ag(s); E° = + 0.80V …(ii) To obtain the equation for the cell reaction, multiply Eq. (ii) with 2 and subtract Eq. (i) from it, we have, Pb(s) + 2Ag+(aq) → Pb2+(aq) + 2Ag(s); E°cell = + 0.80 - (-0.13) = + 0.93V |
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| 12. |
Is Fe → Fe2+ + 2e- redox reaction is oxidation or reduction? |
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Answer» It is oxidation. |
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| 13. |
Can Fe3+ oxidize Br- to Br2 at 1m concentrations? |
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Answer» E°(Fe3+/Fe2+) is lower than that of E°(Br/B–). Therefore Fe2+ reduce Br2 but Br– cannot reduce Fe3+. Thus Fe3+ cannot oxidize Br– to Br2. |
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| 14. |
What is the oxidation number of Cr in K2CrO4? |
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Answer» Let the Ox. no. of Cr in K2CrO4 be x. 2(+1) + x + 4(-2) = 0 +2 + x - 8 = 0 x = +6 |
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| 15. |
Predict,what would happen if CuSO4 is stored in a zinc vessel? |
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Answer» No, as CuSO4 reacts with Zn. |
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| 16. |
Explain the fallacy in O.N. of KI3? |
| Answer» Three I atoms are present in 0,0& -1 oxidation state. | |
| 17. |
Identify the correct statements with reference to the given reactionP4 + 3OH– + 3H2O → PH3 + 3H2PO2–(i) Phosphorus is undergoing reduction only.(ii) Phosphorus is undergoing oxidation only.(iii) Phosphorus is undergoing oxidation as well as reduction.(iv) Hydrogen is undergoing neither oxidation nor reduction. |
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Answer» (iii) Phosphorus is undergoing oxidation as well as reduction. (iv) Hydrogen is undergoing neither oxidation nor reduction. |
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| 18. |
Which of the following electrodes will act as anodes, when connected to Standard Hydrogen Electrode? |
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Answer» (i ,ii) The electrodes having negative electrode potentials are stronger reducing agents than H2 gas and therefore, will act as anodes. |
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| 19. |
MnO4 2- undergoes disproportionation reaction but MnO4 - does not. Explain. |
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Answer» MnO4 - possessMn in highest oxidation state (+7) But in MnO4 2- ,Mn shows +6 oxidation state Hence MnO4 2- undergoes disproportionation reaction but MnO4 - does not. |
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| 20. |
Show that F cannot undergo Disproportionation reaction? |
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Answer» F is most electronegative element and cannot possess three oxidation states. Hence it cannot undergo disproportionation reactions. |
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| 21. |
Explain the disproportionation nature of decomposition of Hydrogen peroxide? |
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Answer» Decomposition of hydrogen peroxide produces water and oxygen. O.N Increases as well as decreases. |
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| 22. |
Classify the following into double displacement, and decomposition reactions :- CaCO3 ----------> CaO + CO2 AgNO3 + KCl -------> AgCl + KNO3 |
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Answer» (i) Decomposition reaction (ii) Double decomposition reaction |
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| 23. |
Define oxidation in terms of electronic concept? |
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Answer» Loss of electron by an atom is called oxidation. |
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| 24. |
How will you define reductant in terms of oxidation no.? |
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Answer» Reductant: Which increases its own ox. no. and decreases that of other in a chemical reaction. |
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| 25. |
Define by reduction in terms of electronic concept. |
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Answer» Reduction is a process in which gain of electrons takes place. |
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| 26. |
Justify that the reaction:2Na(s) + H2(g) → 2NaH is a redox reaction. |
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Answer» In this reaction, Na is oxidised to Na+ and hydrogen is reduced from H2 and H- ion. Therefore it is a redox reaction. 2NaO + H2O → 2Na+ H-1(s) |
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| 27. |
What is the principle of electrochemical cell? |
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Answer» The cell works on the principle of redox reactions . One of the reactant undergoes oxidation while another undergoes reduction. |
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| 28. |
Define oxidation in terms of oxidation number. |
| Answer» The process which involves increase in oxidation number. | |
| 29. |
In the following questions a statement of assertion (A) followed by a statement of reason (R) is given. Choose the correct option out of the choices given below each questiona) Both A and R are true and R is the correct explanation of A.b) Both A and R are true but R is not the correct explanation of A.c) A is true but R is false.d) Both A and R are false.Assertion: (A) CuO + H2 → Cu + H2O is a redox reaction .Reason(R): Cu is a less reactive metal. |
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Answer» c) A is true but R is false. |
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| 30. |
Can the reaction Cr2O7 2- + H2O 2CrO4 2- + 2H+ beregarded as a redox reaction? |
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Answer» O.N of Cr in Cr2O7 2- = +6 O.N of Cr in Cr2O7 2- = +6 Since the oxidation number of Cr has neither decrease nor increased, the above reaction is not a redox reaction. |
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| 31. |
The more positive the value of EV, the greater is the tendency of the species to get reduced. Using the standard electrode potential of redox couples given below find out which of the following is the strongest oxidising agent.(i) Fe3+(ii) I2(s)(iii) Cu2+(iv) Ag+ |
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Answer» The correct answer is (iv) Ag+ |
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| 32. |
EΘ values of some redox couples are given below. On the basis of these values choose the correct option.(i) Cu will reduce Br–(ii) Cu will reduce Ag(iii) Cu will reduce I–(iv) Cu will reduce Br2 |
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Answer» (iv) Cu will reduce Br2 |
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| 33. |
What is Oxidising Agent. |
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Answer» Oxidising Agent The substance (atom, ions or molecules) that gain electrons and is thereby reduced to a low valency state is called an oxidising agent. |
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| 34. |
What is the Molecular Equations? |
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Answer» When the reactant and products involved in a chemical change are written in molecular form in a chemical equation, it is termed as molecular equation. Example: MnO2 + 4HCl → MnCl2 + 2H2O +Cl2 In above example the reactant and products have been written in molecular forms, thus it is a molecular equation |
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| 35. |
Define Ionic Equation. |
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Answer» When the reactant and products involved in a chemical change are ionic compounds, these will be present in the form of ions in the solution. The chemical change is written in ionic forms in the chemical equation, it is termed as ionic equation. Example: MnO2 + 4H+ + 4Cl- → Mn2++ 2Cl- + 2H2O +Cl2 In the above example, the reactant and products have been written in ionic forms, thus the equation is termed as ionic equation. |
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| 36. |
What is meant by elcectrochemical series? |
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Answer» A series of elements arranged in decreasing order of their standard electrode potential. |
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| 37. |
Calculate the oxidation no.of P in PO4-3 |
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Answer» ON of P in PO43- is x . so x +(-2)x4 = -3; or, x = +5. |
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| 38. |
Why do we need salt bridge? |
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Answer» It maintains the electrical neutrality of the half cells. |
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| 39. |
What is salt bridge? |
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Answer» Salt bridge is inverted U tube like structure that contain strong electrolyte (KCl. NH4NO3) in agar agar gel. |
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| 40. |
Discuss the functions of salt bridge. |
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Answer» (i) To maintain electrical neutrality of the two solutions. (ii) To complete the circuit. (iii) It allows the flow of current. |
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| 41. |
Write short note on working of SHE. |
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Answer» It can behave as anode and cathode depending upon another electrode taken. (a) When it acts as anode reaction will be :- H2 ---> 2H+ + 2e Representation will be :- Pt, H2 (1atm.) / H+ ( 1M) (b) 2H+ + 2e- -----> H2 Representation will be :- / H+ ( 1M) / H2 (1atm.), Pt |
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| 42. |
Give one example of a metal oxide which is reduced by coke. |
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Answer» Fe2O3 .............. |
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| 43. |
Define electrochemical series. |
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Answer» The arrangement of elements in the order of increasing standard reduction potential is known as electrochemical series. |
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| 44. |
Give one example of disproportionation reaction. |
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Answer» P4 + NaOH ------> PH3 + H2PO2- |
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| 45. |
Write down the reaction occurring in Daniel cell . What is the direction of flow of current in it? |
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Answer» (i) At Anode :- Zn ------> Zn+2 + 2e- (ii) At Cathode :- Cu+2 + 2e- ------> Cu The current will flow from Cu electrode to Zn electrode . |
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| 46. |
Which of the following is not an example of redox reaction?(i) CuO + H2 → Cu + H2O(ii) Fe2O3 + 3CO → 2Fe + 3CO2(iii) 2K + F2 → 2KF(iv) BaCl2 + H2SO4 → BaSO4 + 2HCl |
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Answer» (iv) BaCl2 + H2SO4 → BaSO4 + 2HCl |
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| 47. |
In the following reaction write down the redox couples :- Fe + Sn+2 -------> Fe+2 + Sn |
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Answer» Fe+2 / Fe and Sn+2 / Sn |
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| 48. |
Tell how can household bleaching agent be formed? |
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Answer» Cl2(g) + 2 OH– (aq) ---------> ClO– (aq) + Cl– (aq) + H2O (l) So, Household bleaching agent can be formed by dissolving chlorine in the base. |
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| 49. |
Define oxidation in terms of electronic concept. |
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Answer» Oxidation is a process in which loss of electrons take place. |
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| 50. |
Why does fluorine not show disporportionation reaction? |
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Answer» Because F Can show only -1 oxidation state and not +ve O.S. due to highest electronegativity. |
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