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101.

`B_(2)O_(3)` isA. AcidicB. BasicC. AmphotericD. None of these

Answer» Correct Answer - A
`B_(2)O_(3)` is acidic and down the group basic nature of oxides increases.
`underset(("acidic"))(B_(2)O_(3))+6NaOH rarr 2Na_(3)BO_(3)+3H_(2)O_(3)`
102.

Which out of the following compound does not exist?A. `BF_(3)`B. `TlCl_(3)`C. `TlCl_(5)`D. Both (B) and (C)

Answer» Correct Answer - C
`Tl^(5+)` does not exist.
103.

Which specie does not exist?A. `[BF_(6)]^(3-)`B. `[AlF_(6))]^(3-)`C. `[GaF_(6)]^(3-)`D. `[InF_(6)]^(3-)`

Answer» Correct Answer - A
`BF_(3)` cannot more than one `F^(-)` ion due to non availability of vacant d-orbitals. This is because maximum covalency of boron is four
104.

Which is not a mineral of aluminiumA. AnhydriteB. BauxiteC. CorundumD. Diaspore

Answer» Correct Answer - A
Anhydrite `(CaSO_(4))` is not a mineral of aluminium.
105.

Which of the following mineral does not contain Al?A. CryoliteB. MicaC. FeldsparD. Fluorspar

Answer» Correct Answer - D
Fluorspar `(CaF_(2))` does not contain aluminium.
106.

Sapphire is a mineral ofA. BaB. BC. BiD. Al

Answer» Correct Answer - D
Sapphire (blue colour) is a mineral of Al.
107.

A mineral acid used as disinfectant isA. Phosphoric acidB. Sulphuric acidC. Phosphrous acidD. Boric acid

Answer» Correct Answer - D
Boric acid `H_(3)BO_(3)` has antiseptic properties.
108.

Mark the incorrect statement. Pure alumina isA. a bad conductor of electricity.B. a good conductor of electricityC. an electrovalent compound.D. volatile in nature

Answer» Correct Answer - A::C::D
Pure alumina is not an electrovalent compound. It is a bad conductor of electricity and non-volatile in nature with very high melting point.
109.

When bauxite powder is mixed with coke and reacted with nitrogen at 2075 K, carbon monoxide and X are formed. What is the gas formed when X is reacted with water ?A. `NH_(3)`B. `N_(2)`C. `N_(2)O`D. `O_(2)`

Answer» Correct Answer - A
When bauxite mixed with coke is heated in an atmosphere of `N_(2)` at 2075 K. AIN is formed. AIN reacts with water to give `NH_(3)`
`Al_(2)O_(3) + 3C + N_(2) rarr 2AIN + 3CO uarr`
`AIN + 3H_(2)O rarr Al(OH)_(3)+NH_(3)`
110.

Which is true for an element `R` present in `13 th` group of the perodic table?A. It is a gas at room temperatureB. It has oxidation state +4C. It forms `R_(2)O_(3)`D. It forms `RX_(2)`

Answer» Correct Answer - C
Element R belongs to group 13. As such the formula of its oxide is `R_(2)O_(3)`. (Element R shows the group valency i.e., 3 of Group 13).
111.

Elements of group 13 not reacting with water areA. BB. AlC. GaD. In

Answer» Correct Answer - C::D
B, Ga and In do not react with water.
112.

Monovalency of heavier members of group 13 elements can be explained on the basis ofA. their low ionisation energiesB. their low electronegatively valuesC. their larger sizesD. inert pair effect

Answer» Correct Answer - D
Due to inert pair effect, down the group, the stability of lower oxidation state (+1 in group 13) increases.
113.

Which one of the following has the lowest m.p.?A. BB. AlC. GaD. Tl

Answer» Correct Answer - C
In group 13, Ga has the lowest melting point.
114.

A particular element belongs to group 13 and second period of the periodic table, it isA. Gas, slightly metallicB. Liquid, non- metallicC. Solid, non-metallicD. Solid, less metallic

Answer» Correct Answer - C
The element in second period of group 13 is boron. It is solid and non-metallic in nature.
115.

Which of the following atomic numbers represent group 13 elements ?A. 13B. 53C. 31D. 81

Answer» Correct Answer - A::C::D
Group 13 elements have atomic number 5,13 31, 49 and 81.
116.

Of all the Group 13 elements, the element with lowest electronegatively isA. BB. TlC. InD. Al

Answer» Correct Answer - D
Group 13 element with lowest electronegativity is Al.
117.

In the extraction of aluminium the purpose of addition of cryolite to alumina is :A. to obtain more aluminiumB. to dissolve bauxiteC. to product anodesD. to cause reduction

Answer» Correct Answer - B
To dissolve bauxite.
118.

Which of the following elements is the hardest?A. BoronB. AluminiumC. GalliumD. Indium

Answer» Correct Answer - A
Boron is a network solid.
119.

In the electrolytic extraction of aluminium, the solvent isA. waterB. `Fe_(2)O_(3)+Al`C. Molten cryoliteD. Molten `Al_(2)O_(3)`

Answer» Correct Answer - C
Molten cryolite acts as solvent.
120.

`AlCl_(3)` fumes in moist air becauseA. It is very volatileB. It is covalentC. HCl is formed in moist airD. It is highly hygroscopic

Answer» Correct Answer - C
Anhydrous `AlCl_(3)` fumes in moist air because of hydrolysis.
`AlCl_(3)+3H_(2)O rarr Al(OH)_(3)+3HCl`
HCl so produced fumes in moist air.
121.

Which out of the following compounds of Boron is hardest ?A. Boron oxideB. Boron carbideC. Boron nitrideD. Boron hydroxide

Answer» Correct Answer - B
Boron carbide `B_(4)C` (also called Norbia) is the hardest substance.
122.

Which one is not an ore of aluminium ?A. China clayB. MicaC. CryoliteD. Carnallite

Answer» Correct Answer - D
Carnalite, `KCl.MgCl_(2).6H_(2)O`.
123.

When Al is added to hot solution of KOH ?A. No action takes placeB. Oxygen is evolvedC. Water is producedD. Hydrogen is evolved

Answer» Correct Answer - D
`2Al+2KOH+2HOH rarr 2KAlO_(2)+3H_(2)`
124.

Anhydrous aluminium chloride is prepared byA. Dissolving aluminium metal in conc. HClB. By heating a mixture of alumina with chlorineC. By heating a mixture of alumina and carbon with dry chlorineD. By heating alumina with dry HCl

Answer» Correct Answer - C
`Al_(2)O_(3)+3C+3Cl_(2) rarr 2AlCl_(3)+3CO`
125.

Aluminium chloride is a/anA. Bronsted-Lowery acidB. Arrhenius acidC. Lewis acidD. Lewis base

Answer» Correct Answer - C
Anhydrous `AlCl_(3)` is a Lewis acid.
126.

Which of the following statements about anhydrous Aluminium chloride is correct?A. It exists as `AlCl_(3)` moleculeB. It is a strong Lewis BaseC. It is not readily hydrolysedD. It sublimes at `100^(@)C` under vacuum

Answer» Correct Answer - D
It sublimes at `100^(@)C` under vaccum.
127.

Eka-aluminium isA. GalliumB. GermaniumC. IndiumD. Scandium

Answer» Correct Answer - A
Gallium is called Eka-aluminium (means one next to aluminium)
128.

Which of the following statements about aluminium chloride is incorrect?A. It exists as a dimerB. It is a covalent compoundC. It involves back bonding between `Cl` and `Al`D. Its aqueous solution conducts electricity

Answer» Correct Answer - C
Cl donates a lone pair to Al forming a coordinate bond.
129.

Anodized aluminium is aluminiumA. obtained on anodeB. alloy, containing 98% aluminiumC. electrolytically coated with aluminium oxideD. None of these

Answer» Correct Answer - C
Anodized aluminium is aluminium electrolytically coated with `Al_(2)O_(3)`.
130.

Diborane undergo alkylation reaction with `Br_(3)` formingA. `B_(2)HR_(5)`B. `B_(2)R_(6)`C. `B_(2)H_(2)R_(4)`D. `B_(2)H_(3)R_(3)`

Answer» Correct Answer - C
`B_(2)H_(6)+4BR_(3) rarr 3B_(2)H_(2)R_(4)`. Only four terminal hydrogen atoms are replaced by R group whereas bridging hydrogen atoms donot get substituted.
131.

Pick up the wrong statementA. Anhydrous `AlCl_(3)` exists as `Al_(2)Cl_(6)` (dimer)B. Anhydrous `AlCl_(3)` is a trigonal planar moleculeC. Anhydrous `AlCl_(3)` fumes in airD. Anhydrous `AlCl_(3)` is ionic.

Answer» Correct Answer - D
Anhyd. `AlCl_(3)` is covalent compound and not ionic because of high IE required. Instead hydrated `AlCl_(3)` is ionic.
132.

Which of the following statements is wrong about `BCl_(3)` ?A. `BCl_(3)` is a covalent compoundB. `BCl_(3)` acts as a Lewis acidC. `BCl_(3)` does not form a dimerD. In `BCl_(3)`, the `B-Cl` bonds are greater than single bonds.

Answer» Correct Answer - D
All the `B-Cl` bonds are single covalent bonds.
133.

Which of the following statements regarding boric acid is false?A. It acts as a tribasic acidB. It has a planar structureC. It acts as a monobasic acidD. It is soluble is hot water

Answer» Correct Answer - A
Boric acid is a monobasic acid and not tribasic acid.
134.

Pick up the wrong statementA. Borax is used in the manufacture of optical glassesB. Borax is used as a fluxC. Borax is used as a water softenerD. Borax is not used for glazing paper

Answer» Correct Answer - D
It is a wrong statement because borax is used for glazing paper.
135.

In meta-aluminates, co-ordination number of aluminium isA. 3B. 6C. 1D. 4

Answer» Correct Answer - B
In meta-aluminates, co-ordinates number of aluminium is 6.
`underset("Meta-aluminate ion")([Al(OH)_(4)(H_(2)O)_(2)]^(-))`
136.

`BCl_(3)+H_(2)O rarr X` The products fored in the above reaction areA. `B_(2)O_(3)+HOCl`B. `H_(3)BO_(3)+HCl`C. `B_(2)H_(6)+HCl`D. No reaction

Answer» Correct Answer - B
`BCl_(3)+3H_(2)O rarr B (OH)_(3)+3HCl`
Thus the products are `B(OH)_(3)` i.e., `H_(3)BO_(3)` and HCl
137.

Which out of the following compounds will liberate methane upon reaction with water?A. `BeC_(2)`B. `Al_(4)C_(3)`C. `Be_(2)C`D. Both (B) and (C)

Answer» Correct Answer - D
`Al_(4)C_(3)+12H_(2)O rarr 4Al(OH)_(3)+3CH_(4)`
`Be_(2)C+2HOH rarr 2BE(OH)_(2)+CH_(4)`
138.

Which one of the following elements is a non-metal ?A. BoronB. IndiumC. SodiumD. Magnesium

Answer» Correct Answer - A
Boron is a non-metal.
139.

Rubies and sapphires are essentiallyA. `Al_(2)O_(3)+C`B. `Al_(2)O_(3)`C. `Al_(2)O_(3)+Ag_(2)O`D. `Al_(2)O_(3)+Au_(2)O_(2)`

Answer» Correct Answer - B
Rubies and sapphires essentially consist of `Al_(2)O_(3)`.
140.

Aluminium vessels should not be washed with materials containing washing soda because -A. Washing soda is expensiveB. Washing soda is easily decomposedC. Washing soda reacts with Al to form insoluble aluminium oxideD. Washing soda reacts with Al to form soluble aluminate.

Answer» Correct Answer - D
Aluminium vessels should not be washed with materials containing washing soda since washing soda reacts with Al to form soluble aluminare.
141.

Which of the following can be used for the isolation of aluminium ?A. `Al_(2)O_(3) + 3C overset(Delta)rarr 2Al + 3CO uarr`B. `AlCl_(3)+ 3Na rarr 3NaCl + Al`C. `Al_(2)O_(3) + Fe rarr Fe_(2)O_(3)+Al`D. None

Answer» Correct Answer - A
Before 1886, Al was manufactured by chemical reduction of `AlCl_(3)` with Na
`AlCl_(3) + 3Na rarr 3NaCl+Al`.
142.

Aluminium alloy with beautiful golden yellow colour used for making artificial jewellery isA. DuraaluminB. MagnaliumC. AlcladD. Aluminium bronze

Answer» Correct Answer - D
Aluminium bronze has a beautiful golden yellow colour.
143.

When zeolite which is hydrated sodium aluminium silicate is treated with hard water, the sodium ions are exchanged withA. `H^(+)` ionsB. `Ca^(2+)`C. `Mg^(2+)`D. `Ca^(2+)` and `Mg^(2+)`

Answer» Correct Answer - D
Zeolite is hydrated sodium aluminium silicate. It replace the `Ca^(2+)` and `Mg^(2+)` ions present in hard water with `Na^(+)` ions.
144.

In reaction `BF_(3)+3LiBH_(4) rarr 3LiF+X`, X isA. `B_(4)H_(10)`B. `B_(2)H_(6)`C. `BH_(3)`D. `B_(3)H_(8)`

Answer» Correct Answer - B
`BF_(3) + 3LiBH_(4) rarr 3LiF + 2B_(2)H_(6)`
145.

In which of the following minerals, Al is not presentA. CryoliteB. MicaC. FeldsparD. Fluorspar

Answer» Correct Answer - D
Fluorspar `(CaF_(2))` does not contain aluminium. Feldspar `(K_(2)O.Al_(2)O_(3).6H_(2)O)`, mica `(KAl_(3)Si_(3)O_(10)(OH)_(2))` and cryolite `(Na_(3)AlF_(6))` contain aluminium.
146.

The ignition mixture used in alumino-thermy is a mixture ofA. Mg powder `+Na_(2)O_(2)`B. Al powder `+ BaO_(2)`C. Al powder `+ Na_(2)O_(2)`D. Mg powder + `BaO_(2)`

Answer» Correct Answer - B
Ignition mixture used in aluminothermy is a mixture of aluminium powder and barium peroxide `(BaO_(2))`.
147.

Thermite is a mixture of iron oxide andA. zinc powderB. sodium shavingsC. potassium metalD. aluminium powder

Answer» Correct Answer - D
Thermite is a mixture of iron oxide `(Fe_(2)O_(3))` and aluminium powder.
148.

Thermite is a mixture ofA. Fe and AlB. Ferric oxide and aluminium powderC. Barium peroxide and magnesium powderD. Cu and Al

Answer» Correct Answer - B
`Fe_(2)O_(3)+Al` powder is thermite used in alumino thermite process.
149.

In the thermite welding process we useA. Al powderB. Fe powderC. Ca powderD. `Al+Fe_(2)O_(3)` mixture.

Answer» Correct Answer - A
In thermite process a mixture of aluminium powder and `Fe_(2)O_(3)` is used.
150.

Hydrogen will not reduceA. Heated cupric oxideB. Heated ferric oxideC. Heated stannic oxideD. Heated aluminium oxide

Answer» Correct Answer - D
Hydrogen will not reduce heated `Al_(2)O_(3)`.