1.

1.94 g of a mixture of KOH (56) and K_(2)CO_(3)(138) is dissolved in water and separated into two equal parts by volume. One part required 50 mL 0.1 M H_(2)SO_(4) to reach the phenolphthalein end point while the other part required 75 mL of the same acid to reach the methyl orange end point. The mass percentage of K_(2)CO_(3) in the mixture is

Answer»

`35.5%`
`71%`
`29%`
`64.5%`

Solution :Let one PART of solution has x mmol KOH and y mmol `K_(2)CO_(3)`.
`implies x + y = 10`
and x + 2y = 15
`implies y = 5, x = 5`
Total mmol of `K_(2)CO_(3)` in the sample = 10
MASS of `K_(2)CO_(3)=(10 XX 138)/(1000)= 1.38 g`
`implies` Mass % of `K_(2)CO_(3)= (1.38)/(1.94) xx 100 = 71%`


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