1.

1,1,2,2- tetrachloropropane was heated with zinc dust and the product was bubbled through ammonical AgNO_3. What is the weight of precipitate obtained?

Answer»

30.0g
29.4g
28.0g
25.7g

Solution :The dehalogenation of vicinal tetrahaloalkane gives alkynes. It is done by heating the compound with ZN dust.

`:'` 182 g of tetrachloro ALKANE gives 147 gives 147 g of PPT.
`:.` 36.4g of tetrachloro alkane gives `(147xx 36.4)/182`
= 29.4 g of precipitate


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