1.

2-Chlorobutane was treated with alc. KOH and the product formed was reacted with dil. KMnO_(4) to give the product B. The structure of B is :

Answer»

`CH_(3) - underset(OH)underset(|)(CH) - CH_(2) - CH_(3)`
`CH_(3) - CH = CH - CH_(2)OH`
`CH_(3) - underset(OH)underset(|)(CH) - underset(OH)underset(|)(CH)CH_(3)`
`underset(OH)underset(|)(CH_(2)) - underset(OH)underset(|)(CH)CH_(2)CH_(3)`

Solution :`CH_(3) - CH_(2) underset(CL)(CH)CH_(3) OVERSET(alk.KOH)rarr CH_(3)CH = CHCH_(3) overset(alk.KMnO_(4))rarr CH_(3) - underset(OH)underset(|)(CH)-underset(OH)underset(|)(CH) - CH_(3)`


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