1.

2-Methylpropane on monochlorination under photochemical conditions give

Answer»

2-chloro-2-methylpropane as major PRODUCT
(1:1) mixture of 1-chloro-2-methylpropane and 2-chloro-2-methylpropane
1-chloro-2-methylpropane as a major product
(1:9) mixture of 1-chloro-2-methylpropane and 2-chloro-2-methylpropane

Solution :`CH-UNDERSET(CH_(3))underset(|)overset(H)overset(|)(C)-CH_(3)-underset((A))(CH_(3)-underset(CH_(3))underset(|)overset(Cl)overset(|)(C)-CH_(3))+underset((B))(CH_(3)-underset(CH_(3))underset(|)(C)H-CH_(2)-Cl`
RATIO of (A): (B) is 5:9


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