1.

(a) Arrange the following compounds in the increasing order of their acid strength: p-cresol, p-nitrophenol, phenol (b) Write the mechanism (using curved arrow notation) of the following reaction: CH_(2)=CH_(2)overset(H_(3)O^(+))toCH_(3)-CH_(2)^(+)+H_(2)O or Write the structures of the products when butan-2-ol reacts with following: (a) CrO_(3) (b) SOCl_(2)

Answer»

Solution :(a) p-cresol `LT` PHENOL `lt` p-nitrophenol
(b)
(a) `CH_(3)CH_(2)underset("Butan-2-ol")(CHCH_(3))underset(O)OVERSET(CrO_(2))toCH_(3)CH_(2)underset("Butan-2-one")underset(O)underset(||)C-CH_(3)`
(b) `CH_(3)CH_(2)underset("Butan-2-ol")underset(OH)underset(|)(CH)CHCH_(3)overset(SOCl_(2))toCH_(3)CH_(2)underset("2-Chlorobutane")underset(|)(CHCH_(3))`


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