1.

(A), (B) and (C) are thrce non-cyclic fuactional isomsers of a carbonyl compound with molecular formula C4H8O Isomery (A) and (C) give positive. Tollens’ test whereas isomer (B) does not give Tollens’ test but gives positive Iodoform test. Isomers (A) and (B) on reduction withZn/Hg – Conc. HCl give the same product (D). Write the structuress of (A), (B), (C) and (D).

Answer»

Solution :`A=CH_3CH_2 CH_2 CHO`
`B=CH_2 CO CH_2 CH`
`C=(CH_3)_2 CHCHO`
`D=CH_3CH_2CH_2CH_2`


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