A black are [x]on fraiment Na_(2)CO_(3) in the presence of air gives a green compound (a). When Rreen compound (a) died in water it producess dark precipitate (b) and pink solution (e) crystal of (e) when treated with propene produces dark ppr (b) Geometry around central atom in (a) and (c) respectively

A black are [x]on fraiment Na_(2)CO_(3) in the presence of air gives a

1.	A black are [x]on fraiment Na_(2)CO_(3) in the presence of air gives a green compound (a). When Rreen compound (a) died in water it producess dark precipitate (b) and pink solution (e) crystal of (e) when treated with propene produces dark ppr (b) Geometry around central atom in (a) and (c) respectively
Answer» tetrahedral, tetrahedral square planar, tetrahedral octahedral, tetrahedral tetrahedral, octahedral Solution :`underset((x))(2MnO_(2))2K_(2)CO_(3)+O_(2) to 2K_(2)MnO_(4)+2CO_(4)` The dark green `K_(2)MnO_(4)` disproportionates in a NEUTRAL or acidic solution to GIVE permangante. `3MnO_(4)^(-2)+4H^(o+) to underset((C))(2MnO_(4)^(-))+ underset((b))(MnO_(2))+2H_(2)O` `MnO_(2)` is dark precipitate (b) and `KMnO_(4)` solution is PINK solution (c) When `KMnO_(4)` reacts with propene (unsaturated compounds) it is reduced to `MnO_(2)` (b) `CH_(3)-CH-=CH_(3) overset("Cold" KMnO_(4)//OH^(-))toCH_(3)- underset(OH) underset(\|)(CH)- underset(OH) underset(\|)(CH_(2)) underset((b))(MnO_(2))` The geometry of `MnO_(4)^(-2) and MnO_(4)^(-)` ions is tetrhydral