1.

 A cationic complex has two isomers A & B. Each has one Co3+, five NH3 , one Br- and one SO4 2-. A gives a white precipitate with BaCl2 solution while B gives a yellow precipitate with AgNO3 solution. (a) What are the possible structures of the complexes A and B? (b) Will the two complexes have same colour?

Answer»

(a) A= [Co(NH3)5Br]SOB= [Co(NH3)5SO4]Br

(b)No



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