1.

A certain compound (x ) shows the following reactions. (i) When KI is added to an aqueous suspension of X containing aceticacid, iodine is liberated. (ii) When CO_(2)is passed through an aqueous suspension of 'X', the turbidity transforms to a ppt. (iii) When a paste of (X ) in water is heated with ethylalcohol, a product of anaesthetic use is obtained.The anaesthetic obtained in the above, treated with silver powder to form the following.

Answer»

`C_(2) H_(2)`
`C_(2)H_(6)`
`CH_(4)`
None of these

Solution :`CaOCl_(2) + H_(2)O rarr Ca(OH)_(2) + Cl_(2)`
`{:(CH_(2)),(CH_(2)):} :)CO +3Clrarr {:(C Cl_(3)),(CH_(3)):}:) CO + 3HCL `
`2 {:(C C l_(3)),(CH_(3)):} :)CO+Ca(OH)_(2)rarr {:(CH_(3)COO),(CH_(3)COO):}:) Ca+2CHCl_(3)`
`UNDERSET("Amoesthetic")(2CHCl_(3)) + 6Ag overset( DELTA)(rarr) underset("gas")(C_(2)H_(2)) + 6AgCl`


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