1.

A certain volume of dry air at NTP is allowed to expand 4 times of its original volume under (a) isothermal conditions, (b) adiabatic conditions. Calculate the final pressure and temperature in each case if γ = 1.4.

Answer»

Given :

Suppose V1 = V

V2 = 4V

P1 = 76 cm of Hg

P2 = ?

γ = 1.4

T1 = 273K

T2 = ?

(a) For isothermal expansion :

P1V1 = P2V2

or,  P2\(P_1\frac{V_1}{V_2}\)

= 19 cm of Hg.

As the process is isothermal, therefore the final temperature will be the same as the initial temperature,

i.e., T2 = 273 K

(b) Adiabatic expansion : From the relation

P1V1γ = P2V2γ

∴ P2 = P1\((\frac{V_1}{V_2})^γ\)

\(= 76\times(\frac{1}{4})^{0.04}\)

\(= 76\times(0.25)^{1.4}\)

= 10.91 cm of Hg

From the relation,

T1V1γ−1 = T2V2γ−1

⇒ T2 = T1\((\frac{V_1}{V_2})^{γ-1}\)

⇒ T2 = 273\((\frac{1}{4})^{0.04}\)

\(\frac{273}{(4)^{0.04}}\)

= 156.8 K



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