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A chemical reaction `2A rarr 4B+C`, in gaseous phase shows an increase in concentration of `B` by `5xx10^(-3) M` in `10` second. Calculate: (a) rate of appearance of `B`, (b) rate of the reaction, (c ) rate of disappearance of `A`. |
Answer» (a) Rate of appearance of `B=("increase in[B]")/("time")=(5xx10^(-3))/10` `=5xx10^(-4) M s^(-1)` (`M` is mol `litre^(-1))` (b) Also, rate of reaction `=-1/2(d[A])/(dt)=1/4(d[B])/(dt)` `:. -1/2(d[A])/(dt)=1/4xx5xx10^(-4)` `:. -1/2(d[A])/(dt)=1.25xx10^(-4) M sec^(-1)` (c ) Rate of disappearance of `A=1.25xx2xx10^(-4)` `= 2.5xx10^(-4) M sec^(-1)` |
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