1.

A closed vessel of known volume containing known amount of ideal gaseous substance 'A'was observed for variation of pressure with temperature .The expected graph was to be like as in ( i) However actual observations revealed the graph to be like. (ii) The deviation was attributed to polymerisation of gas molecules as nA(g) 1 A_(n) (g).If it is known that the above reactiongives only 50% yield. (a) Calculate the ratio of ( n_("experiment"))/( n_("theoritical")) ( where n_("exp.")= Total no. of gaseous mole actually present n_("theoretical") = Total no. of mole origianl taken ) ( b) Find the value of n to which the gas A is being polymerised into

Answer»


ANSWER :(a) 0.625 (B) 4


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