1.

A compound (A) having molecular formula C_(7)H_(11) Br is optically acitve. A react with HBr in the absence of peroxide to give isomeric products (B) and (C). Tretting (A)with potassium-tutoxide give (D). (D) on reductive ozonolysis gives two moles of formaldehyde and one mole of 1,3 cyclopentanedione.(A) in the presence of peroxide reacts with HBr to given (E).

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