1.

A compound (X) gives Observation - I: +ve Todoform test Observation - II : One mole of organic compound gives one mole of Agl by Zeisel's method Observation - III : One mole gives 2 moles of CH_(4) with excess of methyl magnesium bromide. Observation - IV: Gives no test for 2,4- DNP and no ppt. with AgNO_(3) From observations - I and II it can be predicted that the compound (X) contains

Answer»

`-UNDERSET(O)underset(||)C-CH_(3)` group
`-underset(OH)underset(|)CH-CH_(3)` group
`-underset(NH_(2))underset(|)CH-CH_(3)` group
`-underset(O)underset(||)C-Cl_(3)` group

Solution :It gives +ve IODOFORM test the organic compound CONTAINS `CH_(3) -overset(OH)overset(|)CH-` group. It does not contain `CH_(3)-overset(O)overset(||)C-` group because No reaction with 2-4-DNP


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