1.

A crystalline solid (A) reacts with hydrogen gas to form a monoatomic gas (B) and a highly associated liquid ( C).(A) is soluble in water and undergoes hydroloysis slowly to form (B),(C ) and a diatomic gas (D).When pure and dry(D) is subjected to a silent electric discharge an another pale blue gas (E) is produced which like (A) also acts a strong oxidising agent.(E) dissolves in potassium hydroxide forming an orange coloured solid which is paramagnetic in nature. (A) reacts with IF_5, SbF_5, PF_5 etc to form the addition compounds. (C ) forms an addition compound (F) with KF with when electrolysed in molten state forms a most reactive gas (G).(B) and (G) (taken in 2:1) ratio when heated in nickel tube at 400^@ C and 6 atm pressure forms (A).The first ionization energy (IE_1) of (B) is fairly close to (D). Whichof the correct choice for (D) and (E) ?

Answer»

(E) reacts with dry iodine to FORM `I_2O_5`
A filter paper soaked in alcoholic benzidine BECOMES brown when brought in contact with (E)
(D) is prepared by Brin's process
(B) and (C ) both

SOLUTION :(B)test of ozone (not GIVEN by `H_2O_2`)
( C)`2BaO+O_2`(air)`overset(500^@C)to2BaO_2, 2BaO_2 overset(800^@C)toBaO + O_2`
(A)`O_3` forms `I_4O_9` with dry iodine (correct statement )


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