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A diatomic molecule is made of two masses m_(1)andm_(2) which are separated by a distance r. If we calculate its rotational energy by applying Bohr's rule of angular momentum quantization, its energy will be given by : |
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Answer» `((m_(1)+m_(2))N^(2)H^(2))/(2m_(1)m_(2)r^(2))` `because r_(1)=(m_(2)r)/(m_(1)+m_(2))""...(1)` and `r_(2)=(m_(1)r)/(m_(1)+m_(2))""...(2)` `E=(1)/(2)Iomega^(2)=(1)/(2)(m_(1)r_(1)^(2)+m_(2)r_(2)^(2))omega^(2)""...(3)` `because mvr=(nh)/(2pi)=omegaIimpliesomega=(nh)/(2piI)""...(4)` (put equations (1), (2) and (4) in (3)) we get `E=((m_(1)+m_(2))n^(2)h^(2))/(2m_(1)m_(2)r^(2))` |
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