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A dilute solution contains m mole of solute A in 1 kg of a solvent with molal elevation constant K_(b). The solute A undergoes dimerization as 2 A hArr A_(2). Show that equilibrium constant for dimer formation is given by: K_(c ) = (K_(b)(K_(b)m-Delta T_(b)))/((2DeltaT_(b)-K_(b)m)^(2) where Delta T_(b) is elevation in boiling point for given solution. Assume molarity = molality. |
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