1.

A doubly ionised lithium atom is H_2 -like with atomic no. 3. It is excited to produce radiations, Wavelength of radiations required to excite the electron in Li^(++) from the Ist to Illrd Bohr orbit is

Answer»

101.21Å
202.42Å
303.63Å
113.71Å

Solution :For 1st ORBIT, `Z=3, n=1," then "`
`W_(1)=(-13.6)/(12) xx 9=-122.4eV`
`=-195.84 xx 10^(-10)J`
Energy NEEDED for exciting an electron from Ist to IIIrd orbit is `W_(3)-W_(1)=HV`
then `hv=174.08 xx 10^(-19)J=(hc)/(lambda)`
`lambda=(hc)/(174.08 xx 10^(-19) )m=113.74Å`


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