1.

(a) Draw the structures of the following molecules : (i) H_(3)PO_(2) (ii) CIF_(3) (b) Explain the following observations : (i) Nitrogen is much less reactive than phosphorus. (ii) Despite having greater polarity, hydrogen fluoride boils at a lower temperature than water . (iii) Sulphur has greater tendency for catenation than oxygen in the same group.

Answer»

Solution :(i) `H_(3)PO_(2)`

(ii) `CIF_(3)` : Structure of `ClF_(3)`(g)

(B) (ii)Water molecules has twice as many Hydrogen bonding does HF and therefore more INTERMOLECULAR ATTRACTION and HIGHER boiling point than HF.


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