1.

(a) Give reasons for the following : Phenol does not undergo protonation readily. (b) Give chemical test to distinguish between the followings pairs of compounds -2- butanol and 2-methyl -2- propanol.

Answer»

Solution :(a) In phenol, there is `+ve` charge on oxygen in its RESONATING structures, THEREFORE, it does not undergo protonation easily.
(b) Add `I_(2)` and `NaOH` to the compound, 2- BUTANOL will give yellow PRECIPITATE DUE to formation of iodoform whereas 2-methyl-2- propanol will not react.


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