1.

A heterogeneous catalyst system follows

Answer»

order kinetics in beginning and after some time it BECOMES a zero order REACTION
only zero order kinetics
only `I^(ST)` order kinetics
`LI^(nd)` order kinetics.

Solution : When surface of the catalyst is fully covered and any further increase of the REACTANT does not change the situation then the reaction rate becomes independent of concentration and it becomes a zero order reaction.


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