1.

A reaction takes place in a several sequential steps A,B,C and D. the vlaue of enthalpy change for sequential steps are p,q,r and s respectively. If A and C have equal values of enthalpy change with total enthalpy change is t, then choose the incorrect statement among the following.

Answer»

`q=r`
`q+r=t-(s+p)`
`2q=t-(s+p)`
`q+r=p+s`

SOLUTION :According to the question, the diagramatic representation of given reaction can be drawn as

As given, q=r[Hence, (a) is correct]
USING concept of Hess's law
`t=p+q+r+s`
`therefore q+r=t-(s+p)`[hence (b) is correct]
`2q=t-(s+p)`[hence (C) is correct]
`[becauseq=r]`
but q+r=p+s is INCORRECT because EXACT amount of enthalpy change for each step is not given.


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