1.

A reacton is first order in A and second order in B. (i)Wite the differential rate equation. (ii)How is the rate affected on increasing the concentration of B three times? (iii)How Is the rate affected when the concentration of both A and B are doubled?

Answer»

Solution :Reaction:`A+BtoP`
Order with respect to A=1
Order with respect to B=2
Total order of reaction =1+2=3
(i)Rate law of REACTON is as follow:
`(d[R])/(DT)=k[A]^(1)[B]^(2)`
In short r=`k[A]^(1)[B]^(2)`
(ii)Effect on rate if the concentration increase by three times:
`r_(2)=k[A]^(1)[3B]^(2)` `r_(2)=9 r_(1)`
Rate increases by 9 times.
(iii)If concentration A and B both double then the rate:
Concentration of A=2A
Concentration of B=2B
So,`r_(3)=k[2A]^(1)[2B]^(2)`
`=k2[A]^(2)xx4[B]^(2)` `therefore` The rate becomes 8 times
(Note:If only concentration of B is double then rate become double)


Discussion

No Comment Found