1.

A sample of drinking water was found to be serverly contaminated with chloroform, CHCl_(3), supposed to be carcinogen. The level of contamination was 15 ppm (by mass). (i) Express this in percent by mass. (ii) Determine the molality of chloroform in the water sample.

Answer»

SOLUTION :15 ppm means 15 PARTS in million `(10^(6))` parts by mass in the solution
`therefore"% bymass "=(15)/(10^(6))xx100=15xx10^(-4)`
Taking 15 g chloroform in `10^(6)g` of the solution, mass of solvent `~=10^(6)g`
Molar mass of `CHCl_(3)=12+1+3xx35.5="119.5 g mol"^(-1)`
`therefore"Molality"=(15//119.5")/(10^(6))xx1000=1.25xx10^(-4)m.`


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