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A solution of [Co(NH_(3))_(4)I_(4)]Cl when treated with AgNO_(3) gives a white precipitate.What should be the formula of isomer of the dissolved complex that gives yellow precipitate with AgNO_(3). What are the above isomers called ? |
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Answer» Solution :`(i)` A solution of `[Co(NH_(3))_(4)I_(2)]Cl` when treated with `AgNO_(3)` gives a WHITE precipitate, because `Cl^(-)` ion is counter ion. `(ii)` FORMULA of isomer of the dissolved complex that gives yellow precipitate with `AgNO_(3)` is, `[Co(NH_(3))_(4)Cl I]I` BECUASE `I^(OPLUS)` is counter ion `(iii) [Co(NH_(3))_(4)I_(2)]Cl` and `[Co(NH_(3))_(4)Cl I ] I` both are ionisation isomers. |
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