1.

A solution of silver nitrate is electrolysed for 20 minutes with a current of 2 ameres. Calculate the mass of silver deposited at the cathode.

Answer»

Solution :Electrochemical reaction at cathode is `AG^(+) + e^(-) to Ag` (reduction)
`m = ZI t`
`m - (108 g mol^(-1))/(96500 C mol^(-1))xx 2400 C`
`m = 2.68 g`
`Z = ("molarmass of Ag")/((96500)) = (108)/(1 xx 96500)`
`I = 2A`
`t = 20 xx 60S = 1200S`
`It = 2A xx 1200 S = 2400C`.


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