1.

A student try to prepare p-nitroaniline by nitrating aniline with con. HNO_3-con.H_2SO_4 mixture but he got m-nitroaniline from aniline. Why?

Answer»

SOLUTION :Aniline reacts with ACID to form anilium ION `(C_6H_5-N^+H_3)`. In this ion `NH_3` GROUP is META directing.


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